• Title/Summary/Keyword: gamma mixture

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Pore Size Control of Silica-Coated Alumina Membrane for $CO_2$ Separation ($CO_2$ 선택투과 분리를 위한 Silica 코팅 Alumina 막의 세공 제어)

  • 서봉국;김성수;김태옥
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.263-269
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    • 1999
  • For effective $CO_2$ separation using pore size controlled membrane, silica was deposited in the mesopores of a $\gamma$-alumina film by chemical vapor deposition of tetraethoxysilane (TEOS) and phenyl-substituted ethoxysilanes at 773-873K. The membranes prepared with phenyl-substituted ethoxysilanes were calcined to remove the phenyl group and control the pore size. The gas permaselectivity of prepared membranes was evaluated by using $H_2$, $CO_2$ $N_2$, $CH_2$ and $C_3H_8$ single component and a mixture of $CO_2$ and $N_2$. The membranes produced using TEOS contained micropores having permselectivity only to hydrogen, but the phenyl-subsitituted ethoxysilane derived membranes possessed micorpores which are recognizable molecules of $CO_2$, $N_2$ and $CH_4$. In the diphenyl-diethoxysilane-derived membrane, the $CO_2$ permeance and selectivity of $CO_2$/$CH_4$ were $10^{-6} m^3(STP) \cdot m^{-2} \cdot s^{-1} \cdot kPa^{-1}$ and 11, respectively. Therefore, the use of phenyl-substituted ethoxysilane was effective in controlling micropore size for $CO_2$ separation.

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Volatile Flavor Components in Bogyojosaeng and Suhong Cultivars of Strawberry (Fragaria ananassa Duch.)

  • Park, Eun-Ryong;Lee, Hae-Jung;Kim, Kyong-Su
    • Preventive Nutrition and Food Science
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    • v.5 no.3
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    • pp.119-125
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    • 2000
  • Volatile flavor components of two strawberry (Fragaria ananassa Duch.) varieties, Bogyojosaeng and Suhong, ere extracted by SDE(Simultaneous steam distillation and extraction) using a mixture of n-pentane and diethylether (1:1, v/v) as an extract solvent. Analysis of the concentrate by capillary gas chromatography and gas chromatography-mass spectrometry led to the identification of 146 and 153 components in Bogyojosaengand Suhong respectively. There were 49 esters, 25 alcohols, 20 ketones, 24 aldehyds, 6 acids, 9 terpenes and terpene derivatives, 2ethers, 11 unknowns and miscelaneous in Bogyojosaeng and 67 ethers, 9 unknowns and miscellaneous in Suhong. Among these, (E)-2-hexenyl acetae (4.56%) in Bogyojosaeng and (E)-nerolidol (12.38%) in Suhong were major compounds and aceticacid, (E)-2-hexenal, hexyl acetate, ethyl acetate, ethyl butanoate, methyl butanoate, ethyl hexanoate and ${\gamma}$-dodecalactone were the main components in each sample, though there were several differences in composition and threshold of volatile compounds. Total contents of volatile components isolated and identified in Bogyojosaeng an Suhong were 9.010 and 12.527 mg/kg, respectively.

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Radiation-Induced Graft Copolymerization of Methacrylic Acid and Methyl methacrylate onto Polyester.

  • Kang, Young-Kun;Chang, Hoon-Seun;Lee, Chong-Kwang;Park, Jae-Ho
    • Nuclear Engineering and Technology
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    • v.10 no.4
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    • pp.195-201
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    • 1978
  • The radiation-induced graft polymerization of methacrlic acid and methyl methacrylate onto a polyester fabric was investigated with ${\gamma}$-ray as the radiation source, and the rate of grafting was examined. When acrylic acid, methacrylic acid, and methyl methacrylate were grafted onto a polyester fabric, grafting efficiency was depened upon the dielectric constant of the solvent in the monomer mixture. The yield of the graft polymerization was related to the total dose, the concentration of the monomer, and the concentration of the swelling agent. The melting point and the glass transition temperature of MA and MMA grafted copolymers were analysed by means of DTA. Physical properties, such as the moisture regain, the antistatic property, and the wicking time were measured.

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A Study on the Thermal Properties of Epoxy/Micro-Nano Alumina Composites, as Mixture of Surface Modified Nano Alumina (표면개질된 나노알루미나를 혼합한, 에폭시/마이크로-나노알루미나 콤포지트의 열적특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1504-1510
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    • 2016
  • The aim of this study is to improve properties both glass transition temperature($T_g$) and coefficient of thermal expansion(CTE) using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40, 50, 60wt%)+surface modified nano alumina(1_phr) composites. 20 kinds specimen were prepared with containing micro, nano alumina and GDE as a micro composites(10, 20, 30, 40, 50, 60, 70wt%) or a nano/micro alumina composites(1phr/40, 50, 60wt%). Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The glass transition temperature and coefficients of thermal expansion was evaluated by DSC and TMA. The glass transition temperature decreased and coefficients of thermal expansion become smaller with filled contents of epoxy/micro alumina composites. On the other hand, $T_g$ and CTE as GDE addition variation(1,2,3,5g) of epoxy/micro-nano alumina composites decreased and increased respectively.

The AC Insulation Breakdown Properties of Epoxy/Multi-Alumina Composites for Adding Surface Modified Nano Alumina (표면처리된 나노알루미나가 첨가된 에폭시/멀티-알루미나 콤포지트의 교류절연파괴 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1511-1517
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    • 2016
  • The aim of this study is to improve of properties for electrical AC insulation breakdown strength using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40,50,60wt%)+surface modified nano alumina(1_phr) composites. 14 kinds specimen were prepared with containing epoxy resins, epoxy micro composites and epoxy nano-micro alumina mixture composites. Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The electrical AC insulation breakdown strength was evaluated by sphere to sphere electrode system and raising velocity 1kV/s. The AC breakdown strength decreased insulation properties of multi-composites according to increasing micro alumina and GDE addition contents.

Gastric Emptying Time (GET) Test Using Radioisotope (방사성동위원소를 이용한 Gastric Emptying Time의 연구)

  • Koo, Bon-Hwan;Ha, Sung-Woo;Son, Sang-Kyun;Lee, Jae-Tae;Lee, Kyu-Bo;Whang, Kee-Suk
    • The Korean Journal of Nuclear Medicine
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    • v.22 no.2
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    • pp.187-192
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    • 1988
  • A gamma camera coupled to a computer was used in 20 normal volunteers after ingestion of the mixture of $^{99m}Tc-DTPA$ and milk in order to determine gastric emptyng time (GET) and to evaluate the effect of metoclopramide, a dopamine antagonist that stimulates gastric motility, to gastric emptying. The normal value for biological gastric emptying half time was found to be $63{\pm}7$ minutes, and the gastric emptying was monoexponential fashion, at least for the first 60 minutes. Among the 20 volunteers, nine were repeated the test after injection of metoclopramide, which has significantly reduced the value of GET to $31{\pm}3$ minutes (p<0.01). GET test using $^{99m}Tc-DTPA$ is very useful in gastric function evaluation, especially in follow-up check of the functional change.

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Inhibition of Adipocyte Differentiation by MeOH Extract from Carduus crispus through ERK and p38 MAPK Pathways

  • Lee, Eun-Jeong;Joo, Eun-Ji;Hong, Yoo-Na;Kim, Yeong-Shik
    • Natural Product Sciences
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    • v.17 no.4
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    • pp.273-278
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    • 2011
  • In this study, the effects of a methanol (MeOH) extract of Carduus crispus L. (Asteraceae) on adipogenesis was investigated in 3T3-L1 cells. To differentiate preadipocytes to adipocytes, confluent 3T3-L1 preadipocytes were treated with a hormone mixture, which included isobutylmethylxanthine, dexamethasone, and insulin (MDI). The methanol extract of C. crispus significantly decreased fat accumulation by inhibiting adipogenic signal transcriptional factors in MDI-induced 3T3-L1 cells in a dose-dependent manner. In MTT assays and on PI-staining, methanol extract of C. crispus inhibited the proliferation of 3T3-L1 cells during mitotic clonal expansion (MCE). The anti-adipogenic effect of the Carduus extract seemed to be associated with the upregulation of extracellular signal-regulated kinase (ERK) and p38 mitogen-activated protein kinase (MAPK) pathways within the first 2 days after MDI treatment. These results suggest that methanol extract of C. crispus might be beneficial for the treatment of obesity.

Silymarin Inhibits Cytokine-Stimulated Pancreatic Beta Cells by Blocking the ERK1/2 Pathway

  • Kim, Eun Jeong;Kim, Jeeho;Lee, Min Young;Sudhanva, Muddenahalli Srinivasa;Devakumar, Sundaravinayagam;Jeon, Young Jin
    • Biomolecules & Therapeutics
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    • v.22 no.4
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    • pp.282-287
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    • 2014
  • We show that silymarin, a polyphenolic flavonoid isolated from milk thistle (Silybum marianum), inhibits cytokine mixture (CM: TNF-${\alpha}$, IFN-${\gamma}$, and IL-$1{\beta}$)-induced production of nitric oxide (NO) in the pancreatic beta cell line MIN6N8a. Immunostaining and Western blot analysis showed that silymarin inhibits iNOS gene expression. RT-PCR showed that silymarin inhibits iNOS gene expression in a dose-dependent manner. We also showed that silymarin inhibits extracellular signal-regulated protein kinase-1 and 2 (ERK1/2) phosphorylation. A MEK1 inhibitor abrogated CM-induced nitrite production, similar to silymarin. Treatment of MIN6N8a cells with silymarin also inhibited CM-stimulated activation of NF-${\kappa}B$, which is important for iNOS transcription. Collectively, we demonstrate that silymarin inhibits NO production in pancreatic beta cells, and silymarin may represent a useful anti-diabetic agent.

Decomposition Mechanism of Waste Hard Metals using by ZDP (Zinc Decomposition Process) (ZDP(Zinc Decomposition Process)를 이용한 폐 초경합금의 분해기구)

  • Pee, Jae-Hwan;Kim, Yoo-Jin;Sung, Nam-Eui;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.173-177
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    • 2011
  • Decomposition promoting factors and decomposition mechanism in the zinc decomposition process of waste hard metals which are composed mostly of tungsten carbide and cobalt were evaluated. Zinc volatility amount was suppressed and zinc valatilization pressure was produced in the reaction graphite crucible inside an electric furnace for ZDP. Reaction was done for 2 h at $650^{\circ}C$, which 100 % decomposed the waste hard metals that were over 30 mm thick. As for the separation-decomposition of waste hard metals, zinc melted alloy formed a liquid composed of a mixture of ${\gamma}-{\beta}1$ phase from the cobalt binder layer (reaction interface). The volume of reacted zone was expanded and the waste hard metal layer was decomposed-separated horizontally from the hard metal. Zinc used in the ZDP process was almost completely removed-collected by decantation and volatilization-collection process at $1000^{\circ}C$.

An Experimental Study on the Lift-off Behavior of Tone-Excited Propane Non-premixed Jet Flames (음향 가진된 프로판 비예혼합 제트 화염의 부상 거동에 대한 실험적 연구)

  • Kim, Seung-Gon;Kim, Kang-Tae;Park, Jeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.5
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    • pp.569-579
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    • 2004
  • The lift-off characteristics of lifted laminar propane jet flames highly diluted with nitrogen are investigated introducing acoustic forcing with a fuel tube resonance frequency. A flame stability curve is obtained according to forcing strength and the nozzle exit velocity for N2 diluted flames. Flame lift-off behavior is globally classified into three regimes; 1) a weakly varying partially premixed behavior caused by a collapsible mixing for large forcing strength, 2) a coexistent behavior of the edge flame and a weakly varying partially premixed behavior for moderate forcing strength, and 3) edge flame or triple flame behavior for small forcing. It is shown that the laminar lifted flame with forcing affects flame lift-off behavior considerably, and is also clarified that the flame characteristic of flame base is well described with the penetration depth of the degree of mixing, ${\gamma}$$\_$$\delta$/. It is also confirmed that the weakly varying partially premixed flame caused by a collapsible mixing fur large forcing strength behaves as that just near flame blow-out in turbulent lift-off flame.