• 제목/요약/키워드: gadolinium

검색결과 325건 처리시간 0.025초

영구자석 배열을 이용한 능동형 자기재생 냉동기에 대한 실험적 연구 (Experimental investigation on the room temperature active magnetic regenerator with permanent magnet array)

  • 김영권;정상권
    • 대한설비공학회:학술대회논문집
    • /
    • 대한설비공학회 2008년도 동계학술발표대회 논문집
    • /
    • pp.186-191
    • /
    • 2008
  • In this study, a room temperature AMRR (Active magnetic regenerative refrigerator) was fabricated, and experimentally investigated. Gadolinium (Gd) was selected as a magnetic refrigerant with Curie temperature of 293 K. Permanent magnet was utilized to magnetize and demagnetize the AMR. To produce large magnetic field above 1 T in the magnetic refrigeration space, a special arrangement of permanent magnets, so called Halbach array, is employed. Sixteen segments of the permanent magnets magnetized different direction, constitute a hollow cylindrical shaped permanent magnet. The AMR is reciprocated along the bore of the magnet array and produces cooling power. Helium is selected as the working fluid and a helium compressor is utilized to supply helium flow to the regenerator. The fabricated AMRR has different structure and compared to a convectional AMRR since it has an additional volume after the regenerator. Therefore, the cooling ability is generated not only by magnetocaloric effect of magnetic refrigerant but also by the pulse tube effect. It is verified that the cooling ability of AMR is increased due to the magnetocalric effect by the fact that the temperature span becomes $16^{\circ}C$ while the temperature span is only $8^{\circ}C$ when the magnetic field is not applied to the regenerator.

  • PDF

Dual Functional Gd(III)-DOTA Liposomes for Cancer Therapy and Diagnosis as a Theragnostic Carrier

  • Han, Hee Dong;Jung, Suk Hyun;Seong, Hasoo;Cho, Sun Hang;Shin, Byung Cheol
    • Bulletin of the Korean Chemical Society
    • /
    • 제34권1호
    • /
    • pp.154-158
    • /
    • 2013
  • Development of dual functional liposome has been studied for cancer theragnostics. Therefore, we focused on ultrasound-sensitive liposomes with doxorubicin (DOX) and gadolinium (Gd) as a theragnostic carrier having a potential for cancer therapy and diagnosis. In this study, Gd(III)-DOTA-modified sonosensitive liposomes (GL) was developed using chemically synthesized Gd(III)-DOTA-DPPE lipid. Sonosensitivity of GL to 1 MHz ultrasound induced 25% of DOX release. The relaxivities ($r_1$) of GL were $7.33-10.34\;mM^{-1}s^{-1}$, which was higher than that of MR-bester$^{(R)}$. Intracellular delivery of DOX from GL by ultrasound irradiation was evaluated according to ultrasound intensity, resulting in increase of uptake of DOX released from ultrasound-triggered GLs compared to GL3 or Doxil$^{(R)}$ without ultrasound. Taken together, this study shows that the paramagnetic and sonosensitive liposomes, GL, is a novel and highly effective delivery system for drug with the potential for broad applications in human disease.

Symmetrical Solid Oxide Electrolyzer Cells (SOECs) with La0.6Sr0.4Co0.2Fe0.8O3 (LSCF)-Gadolinium Doped Ceria (GDC) Composite Electrodes

  • Lee, Kyoung-Jin;Lee, Min-Jin;Park, Seok-hoon;Hwang, Hae-Jin
    • 한국세라믹학회지
    • /
    • 제53권5호
    • /
    • pp.489-493
    • /
    • 2016
  • Scandia ($Sc2O_3$)-stabilized zirconia (ScSZ) electrolyte-supported symmetrical solid oxide electrolyzer cells (SOECs), in which lanthanum strontium cobalt ferrite (LSCF)-gadolinia ($Gd_2O_3$)-doped ceria (GDC) composite materials are used as both the cathode and anode, were fabricated and their high temperature steam electrolysis (HTSE) performance was investigated. Current density-voltage curves were obtained for cells operated in 10% $H_2O$/90% Ar at 750, 800, and $850^{\circ}C$. It was possible to determine the ohmic, cathodic, and anodic contributions to the total overpotential using the three-electrode technique. The HTSE performance was significantly improved in the symmetrical cell with LSCF-GDC electrodes compared to the cell consisting of an Ni-YSZ cathode and LSCF-GDC anode. It was found that the overpotential due to the LSCF-GDC cathode largely decreased and, at a given current density, the total cell voltage decreased, which resulted in the enhanced hydrogen production rate in the symmetrical cell.

Synthesis and Luminescence Characterization of En3+ Doped Gd2O3 Phosphors by Combustion Method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Kim, Jung-Duk;Han, Sang-Do;Park, Jin-Won;Singh, K.C.
    • Transactions on Electrical and Electronic Materials
    • /
    • 제4권5호
    • /
    • pp.28-32
    • /
    • 2003
  • Europium-doped gadolinium oxide ($Gd_2O_3;Eu^{3+}$) phosphors have been prepared by combustion method using urea[H$_2$NCONH$_2$] or carbohydrazide[H$_2$NNHCONHNH$_2$] as fuel materials in a preheated furnace at 500$^{\circ}C$. The phosphors obtained were fired at 1200$^{\circ}C$ for 3 hours to get better luminescent properties. The combustion method used was found to be a simple and fast method for the preparation of fine-sized particles. The influence of the fuel/oxidant (urea or carbohydrazide/nitrate) mole ratio on the phosphor has been investigated and the optimum values for various parameters have been determined. By this method, phosphor that has better brightness and smaller size particles than that obtained by conventional method has been prepared.d has been prepared.

반도체형 열중성자 선량 측정센서 개발 (The development of a thermal neutron dosimetry using a semiconductor)

  • 이남호;김양모
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2003년도 학술회의 논문집 정보 및 제어부문 B
    • /
    • pp.789-792
    • /
    • 2003
  • pMOSFET having 10 ${\mu}um$ thickness Gd layer has been tested to be used as a slow neutron sensor. The total thermal neutron cross section for the Gd is 47,000 barns and the cross section value drops rapidly with increasing neutron energy. When slow neutrons are incident to the Gd layer, the conversion electrons are emitted by the neutron absorption process. The conversion electrons generate electron-hole pairs in the $SiO_2$ layer of the pMOSFET. The holes are easily trapped in Oxide and act as positive charge centers in the $SiO_2$ layer. Due to the induced positive charges, the threshold turn-on voltage of the pMOSFET is changed. We have found that the voltage change is proportional to the accumulated slow neutron dose, therefore the pMOSFET having a Gd nuclear reaction layer can be used for a slow neutron dosimeter. The Gd-pMOSFET were tested at HANARO neutron beam port and $^{60}CO$ irradiation facility to investigate slow neutron response and gamma response respectively. Also the pMOSFET without Gd layer were tested at same conditions to compare the characteristics to the Gd-pMOSFET. From the result, we have concluded that the Gd-pMOSFET is very sensitive to the slow neutron and can be used as a slow neutron dosimeter. It can also be used in a mixed radiation field by subtracting the voltage change value of a pMOSFET without Gd from the value of the Gd-pMOSFET.

  • PDF

T2 이완시간의 정량적 평가에 있어서 Maximum TE의 설정 범위에 대한 연구 : 팬텀연구 (Maximum TE Setting Range for Quantitatively Evaluating T2 Relaxation Time : Phantom Study)

  • 박진서;김성호
    • 대한방사선기술학회지:방사선기술과학
    • /
    • 제41권1호
    • /
    • pp.25-31
    • /
    • 2018
  • This study aimed to evaluate the range of maximum TE that could measure T2 relaxation time accurately by setting diverse maximum TE with using contrast medium phantoms. Contrast medium phantoms ranging from low to high concentrations were made by using Gadoteridol. The relaxation time and relaxation rate were compared and evaluated by conducting T2 mapping by using reference data based on various TEs and data obtained from different maximum TEs. It was found that accurate T2 relaxation time could be expressed only when the maximum TE over a certain range was used in the section with long T2 relaxation time, such as the low concentration section of saline or gadolinium contrast medium. Therefore, the maximum TE shall be longer than the T2 relation time for accurately maturing the T2 relaxation of a certain tissue or a substance.

Midline Glioblastoma Multiforme With Bilateral Symmetric Cysts

  • Lee, Hai-Ong;Koh, Eun-Jeong;Oh, Young-Min;Choi, Ha-Young
    • Journal of Korean Neurosurgical Society
    • /
    • 제43권2호
    • /
    • pp.105-108
    • /
    • 2008
  • Cystic glioblastoma multiforme (GBM) is a rare disease. Its exact prevalence has not yet been reported. Also, the mechanism of cyst formation remains to be elucidated. We report a case of GBM with a large peripheral cyst. A 43-year-old woman visited our clinic with a 3-month history of severe headache, memory impairment and general weakness. T1-weighted gadolinium-enhanced magnetic resonance (MR) image revealed a midline enhanced solid mass and bilateral symmetric banana-shaped peripheral cysts. A centrally enhanced mass was measured $2{\times}4$ cm in size and both mass and cysts as $7{\times}7$ cm. Both the frontal lobe and the frontal horn were severely compressed inferiorly and posteriorly. We resected a midline solid tumor and cysts via the bilateral interhemispheric transcortical approach. Histopathologic examination revealed GBM. The patient was subsequently treated with fractionated conventional brain radiation therapy, followed by temozolomide chemotherapy. Eighteen months later, there was no tumor recurrence and no neurological deficits were noted. Our patient showed no tumor recurrence and a long survival at a long follow-up.

Behavior of Radioactive Metal Surrogates Under Various Waste Combustion Conditions

  • Yang, Hee-Chul;Lee, Jae-Hee;Kim, Jung-Guk;Yoo, Jae-Hyung;Kim, Joo-Hyung
    • Nuclear Engineering and Technology
    • /
    • 제34권1호
    • /
    • pp.80-89
    • /
    • 2002
  • A laboratory investigation of the behavior of radioactive metals under the various waste combustion atmospheres was conducted to predict the parameters that influence their partitioning behavior during waste incineration. Neodymium, samarium, cerium, gadolinium, cesium and cobalt were used as non-radioactive surrogate metals that are representative of uranium, plutonium, americium, curium, radioactive cesium, and radioactive cobalt, respectively. Except for cesium, all of the investigated surrogate metal compounds converted into each of their stable oxides at medium temperatures from 400 to 90$0^{\circ}C$, under oxygen- deficient and oxygen-sufficient atmospheres (0.001-atm and 0.21-atm $O_2$). At high temperatures above 1,40$0^{\circ}C$, cerium, neodymium and samarium in the form of their oxides started to vaporize but the vaporization rates were very slow up to 150$0^{\circ}C$ . Inorganic chlorine (NaCl) as well as organic chlorine (PVC) did not impact the volatility of investigated Nd$_2$O$_3$, CoO and Cs$_2$O. The results of laboratory investigations suggested that the combustion chamber operating parameters affecting the entrainment of particulate and filtration equipment operating parameters affecting particle collection efficiency be the governing parameters of alpha radionuclides partitioning during waste incineration.

Use of americium as a burnable absorber for VVER-1200 reactor

  • Shelley, Afroza;Ovi, Mahmud Hasan
    • Nuclear Engineering and Technology
    • /
    • 제53권8호
    • /
    • pp.2454-2463
    • /
    • 2021
  • The objective of this research is to the use of americium (AmO2) as a burnable absorber effectively instead of conventional gadolinium (Gd2O3) for VVER-1200 reactor by analyzing its impacts on reactivity, power peaking factor (PPF), safety factor, and quality of the spent fuel. The assembly is burned to 60 GWd/t by using SRAC-2006 code and JENDL-4.0 data library for finding the optimum amount and effective way of using AmO2 as a burnable absorber. From these studies, it is found that AmO2 can decrease the excess reactivity like Gd2O3 without changing the criticality life span and enrichment of 235U. A homogeneous mixture of the 0.20% AmO2+ 4.95% enriched UO2 fuel rod (model MF-4) decreases the PPF than the reference assembly. The use of AmO2+UO2 in the integral burnable absorber (IBA) rod or the outer layer could also decrease the PPF up to 10 GWd/t but increases rapidly after 30 GWd/t, which could be a safety threat. The fuel temperature coefficient and void coefficient of the model MF-4 are the same as the reference assembly. In addition, 22% of initially loaded Am are burning effectively and contributing to the power production.

Monte Carlo burnup and its uncertainty propagation analyses for VERA depletion benchmarks by McCARD

  • Park, Ho Jin;Lee, Dong Hyuk;Jeon, Byoung Kyu;Shim, Hyung Jin
    • Nuclear Engineering and Technology
    • /
    • 제50권7호
    • /
    • pp.1043-1050
    • /
    • 2018
  • For an efficient Monte Carlo (MC) burnup analysis, an accurate high-order depletion scheme to consider the nonlinear flux variation in a coarse burnup-step interval is crucial accompanied with an accurate depletion equation solver. In a Seoul National University MC code, McCARD, the high-order depletion schemes of the quadratic depletion method (QDM) and the linear extrapolation/quadratic interpolation (LEQI) method and a depletion equation solver by the Chebyshev rational approximation method (CRAM) have been newly implemented in addition to the existing constant extrapolation/backward extrapolation (CEBE) method using the matrix exponential method (MEM) solver with substeps. In this paper, the quadratic extrapolation/quadratic interpolation (QEQI) method is proposed as a new high-order depletion scheme. In order to examine the effectiveness of the newly-implemented depletion modules in McCARD, four problems in the VERA depletion benchmarks are solved by CEBE/MEM, CEBE/CRAM, LEQI/MEM, QEQI/MEM, and QDM for gadolinium isotopes. From the comparisons, it is shown that the QEQI/MEM predicts ${k_{inf}}^{\prime}s$ most accurately among the test cases. In addition, statistical uncertainty propagation analyses for a VERA pin cell problem are conducted by the sensitivity and uncertainty and the stochastic sampling methods.