• Title/Summary/Keyword: functional additives

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Characterization and ACE Inhibitory Activity of Fermented Milk with Probiotic Lactobacillus plantarum K25 as Analyzed by GC-MS-Based Metabolomics Approach

  • Zhang, Min;Jiang, Yunyun;Cai, Miao;Yang, Zhennai
    • Journal of Microbiology and Biotechnology
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    • v.30 no.6
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    • pp.903-911
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    • 2020
  • Addition of probiotics to yogurt with desired health benefits is gaining increasing attention. To further understand the effect of probiotic Lactobacillus plantarum on the quality and function of fermented milk, probiotic fermented milk (PFM) made with probiotic L. plantarum K25 and yogurt starter (L. delbrueckii ssp. bulgaricus and Streptococcus thermophilus) was compared with the control fermented milk (FM) made with only the yogurt starter. The probiotic strain was shown to survive well with a viable count of 7.1 ± 0.1 log CFU/g in the PFM sample after 21 days of storage at 4℃. The strain was shown to promote formation of volatiles such as acetoin and 2,3-butanediol with milk fragrance, and it did not cause post-acidification during refrigerated storage. Metabolomics analysis by GC-MS datasets coupled with multivariate statistical analysis showed that addition of L. plantarum K25 increased formation of over 20 metabolites detected in fermented milk, among which γ-aminobutyric acid was the most prominent. Together with several other metabolites with relatively high levels in fermented milk such as glyceric acid, malic acid, succinic acid, glycine, alanine, ribose, and 1,3-dihydroxyacetone, they might play important roles in the probiotic function of L. plantarum K25. Further assay of the bioactivity of the PFM sample showed significant (p < 0.05) increase of ACE inhibitory activity from 22.3% at day 1 to 49.3% at day 21 of the refrigerated storage. Therefore, probiotic L. plantarum K25 could be explored for potential application in functional dairy products.

Through-Silicon-Via Filling Process Using Cu Electrodeposition (구리 전해 도금을 이용한 실리콘 관통 비아 채움 공정)

  • Kim, Hoe Chul;Kim, Jae Jeong
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.723-733
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    • 2016
  • Intensive researches have been focused on the 3-dimensional packaging technology using through silicon via (TSV) to overcome the limitation in Cu interconnection scaling. Void-free filling of TSV by the Cu electrodeposition is required for the fabrication of reliable electronic devices. It is generally known that sufficient inhibition on the top and the sidewall of TSV, accompanying the selective Cu deposition on the bottom, enables the void-free bottom-up filling. Organic additives contained in the electrolyte locally determine the deposition rate of Cu inside the TSV. Investigation on the additive chemistry is essential for understanding the filling mechanisms of TSV based on the effects of additives in the Cu electrodeposition process. In this review, we introduce various filling mechanisms suggested by analyzing the additives effect, research on the three-additive system containing new levelers synthesized to increase efficiency of the filling process, and methods to improve the filling performance by modifying the functional groups of the additives or deposition mode.

The Effect of Ice Adhesion according to Functional Group and Chemical Structure of Additive (화합물 작용기와 화학구조에 따른 수용액의 빙부착 억제 효과)

  • Chung, Dong-Yeol;Peck, Jong-Hyeon;Kang, Chae-Dong;Hong, Hi-Ki
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.8
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    • pp.607-614
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    • 2007
  • This paper investigated that the functional group and chemical structure of additives affect ice adhesion in aqueous solutions cooling with stirring. In order to compare the effect on the ice adhesion in aqueous solutions, the functional group like carboxyl (-COOH), hydroxyl(-OH) or amine($-NH_{2}$) one were compared each other. Among the functional group, the strength of the hydrogen bonding force order is amine, hydroxyl and carboxyl one. It supports that ethylene diamine 7 mass% solution including amine group was effective to suppress the ice adhesion, though it is corrosive. Also, the ice adhesion were effectively resisted and formed lots of ice slurries in cooling experiment of 7 mass% solution of 1, 2-and 1, 3-propanediol which is different molecular structure but equal molecular weight each other.

Combinatorial Methods for Characterization and Optimization of Polymer Formulations

  • Amis Eric J.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.110-111
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    • 2006
  • Most applications of polymers involve blends and mixtures of components including solvents, surfactants, copolymers, fillers, organic or inorganic functional additives, and various processing aids. These components provide unique properties of polymeric materials even beyond those tailored into the basic chemical structures. In addition, skillful processing extends the properties for even greater applications. The perennial challenge of polymer science is to understand and exploit the structure-processing-property interplay relationship. We are developing and demonstrating combinatorial methods and high throughput analysis as tools to provide this fundamental understanding.

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Analysis of Biurea Decomposed from Azodicarbonamide in Food Products by High Performance Liquid Chromatography Mass/Mass Spectrometry (LC/MS/MS를 이용한 식품 중 아조디카르본아미드 분해산물인 Biurea 함량 분석)

  • Lim, Ho-Soo;Pahn, Kyeong-Nyeo;Kim, Jun-Hyun;Jang, Gui-Hyeon;Moon, Gui-Im;Yang, Hyo-Jin;Park, Sung-Kwan;Park, Hae-Kyong;Kim, So-Hee
    • Korean Journal of Food Science and Technology
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    • v.42 no.4
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    • pp.377-382
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    • 2010
  • This study was conducted to establish a method to analyze biurea decomposed from azodicarbonamide in processed foods such as wheat flour and bread. New method was developed using high performance liquid chromatography mass/mass spectrometry to determine biurea in wheat flour and bakery products. The recovery rate was 94.3-112.5%. The limit of detection for biurea was 0.003 mg/kg, and the limit of quantification was 0.01 mg/kg. The monitoring results for biurea content using established methods showed that biurea was detected at 2.76 mg/kg in the azodicarbonamide-detected flour (detection rate, 2%). The detection rate in processed foods such as baked goods was 27% (16/59). The detection range was 0.19-18.01 mg/kg (average, 3.79 mg/kg). However, it was thought that the detection level was safe due to much lower values than the standard (45 mg/kg). As a result, the newly established biurea analytical method will contribute to the management of azodicarbonamide in processed foods such as wheat flour and bakery products.

Analysis of Azodicarbonamide in Food Products by High Performance Liquid Chromatography (HPLC를 이용한 식품 중 아조디카르본아미드 분석)

  • Lim, Ho-Soo;Bahn, Kyeong-Nyeo;Kim, Jun-Hyun;Jang, Gui-Hyeon;Moon, Gui-Im;Park, Sung-Kwan;Yang, Hyo-Jin;Park, Hae-Kyong;Kim, So-Hee
    • Journal of Food Hygiene and Safety
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    • v.25 no.2
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    • pp.100-105
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    • 2010
  • This study was conducted to establish a method to analyze azodicarbonamide (ADA) in wheat flour. A new method using high performance liquid chromatography (HPLC) was developed for the determination of ADA in wheat flour. The recovery rate was 91.93~97.54%. The limit of detection for ADA was 0.02 mg/kg and the limit of quantification was 0.05 mg/kg. The monitoring results for ADA contents using the established methods showed that it was detected as the low value of 0.95 mg/kg in one of 51 flour samples (detection rate : 2%), but not detected in 59 bakery samples. The detected ADA level was suitable to its usage standard, compared to the standard (45 mg/kg). Although the detection rate was very low, the established analytical method of ADA will contribute to the management of ADA in processed foods such as wheat flour and bakery.

Processing of Vermiculite-Silica Composites with Prefer-Oriented Rod-Like Pores

  • Eom, Jung-Hye;Kim, Young-Wook;Lee, Seung-Seok;Jeong, Doo-Hoa
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.347-351
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    • 2012
  • Vermiculite-silica composites with a layered structure were fabricated by adding cellulose fibers as a pore former and by a simple uniaxial pressing and subsequent sintering process. Three different combinations of additives were used and their effects on the compressive strength and thermal conductivity of the composites were investigated. Both compressive strengths (42-128 MPa) and thermal conductivities (0.75-1.48 $W/m{\cdot}K$) in the direction perpendicular to the pressing direction (T) were higher than those (19-81 MPa and 0.32-1.04 $W/m{\cdot}K$) in the direction parallel to the pressing direction (S) in all samples. The anisotropy in both properties was attributed to the microstructural anisotropy, which was caused by the layered structure developed in the composites.

Preparation and Properties of Silicone Hydrogel Material Containing Silane Group with Cobalt Oxide Nanoparticles through Thermal Polymerization

  • Lee, Min-Jae;Kong, Ki-Oh;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.273-278
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    • 2020
  • This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

Chemical Properties of Semiconductive Shield (반도전 재료의 화학적 특성)

  • Ahn, Jong-Hyun;Kim, Hyang-Kon
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.203-206
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    • 2008
  • To improve mean-life and reliability of power cable in this study, we have investigated chemical properties showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Chemical properties of specimens was measured by FT-ATR (Fourier Transform Attenuated Total Reflectance). The condition of specimens was a solid sheet. We could observe functional group (C=O, carbonyl group) of specimens through FT-ATR. From these experimental result, the concentration of functional group (C=O) was high according to increasing the content of carbon black. We could know EEA was excellent more than other specimens from above experimental results.

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The Performance Stability of Ophthalmic Material with UV-Block Effect Containing Hydroxyl Benzophenone Group and Tungsten Nanoparticles

  • Kim, Duck-Hyun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.61 no.3
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    • pp.97-103
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    • 2017
  • In this study, the functional hydrogel ophthalmic lens containing tungsten oxide nanoparticles, 2,4-dihydroxy benzophenone and 2-hydroxy-4-(methacryloyloxy) benzophenone were manufactured. HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), AA(acrylic acid), the cross-linker EGDMA (ethylene glycol dimethacrylate), the initiator AIBN (azobisisobutyronitrile) and the functional additives including tungsten oxide nanoparticles, 2,4-dihydroxy benzophenone, and 2-hydroxy-4-(methacryloyloxy) benzophenone were used respectively. The measurements of water content and refractive index of the sample was decreased and increased, respectively. And also, the UV transmittance of produced lens containing 2,4-dihydroxy benzophenone, 2-hydroxy-4-(methacryloyloxy) benzophenone and tungsten oxide nanoparticles was measured. Based on the results of this study, it is judged that the performance improvement increased over time when 2-hydroxy-4-(methacryloyloxy) benzophenone was used as an additive, while the use of tungsten oxide nanoparticles influenced on blue-ray-blocking effect of the hydrophilic lens.