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Living cationic polymerization of poly (isobutyl vinyl ether) and PVA derived therefrom

  • Mah, Soukil
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.1-2
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    • 2003
  • Some new synthetic routes for the preparation of poly (isobutyl vinyl ether) (P(IBVE)) having a controllable molar mass with narrow distribution via catalytic or photoinduced living cationic polymerization and their conversion to corresponding PVA have been developed. It was found that the combination of iodomethyl methyl ether (IMME)-zinc iodide is effective in the initiation of the catalytic and the various combinations of diphenyliodonium halides, well known photocationic initiators (DPIX) with zinc halides (ZnX$_2$) are also useful in photoinduced living cationic polymerization of isobutyl vinyl ether (IBVE). Polymerization both in the catalytic and photoinduced systems precede until the full consumption of the monomer and the rate of polymerization increases as the concentration of the catalyst or photoinitiator. The number average molar mass of the resulting polymer is proportional with % conversion, which is determined by the ratio of monomer consumed and the initial values of the catalyst or initiator. The living nature was also confirmed by subsequent monomer addition technique.

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Performance Improvement of Power Control System for Driving MGT

  • Lee Sung-Geun
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.7
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    • pp.744-749
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    • 2005
  • This paper describes the performance improvement of power control system of magnetron (MGT) for microwave oven. The MGT is used extensively in household microwave oven and industrial microwave heating devices, and is operated by 3.0[kV] $\∼$5.0[kV] dc high voltage. The proposed power supply is consisted of a bridge rectifier, step-up converter(SUC) and its controller, half bridge inverter(HBI) and its controller, and full wave double voltage rectifier(DVR). In the proposed system, a good power factor can be obtained by the SUC' switching method that the inductor current waveforms follows that of the rectified voltage, and a line input power can be controlled to a range of 17.5[$\%$] by duty ratio (DR) adjustment of the HBI.

Evaluation of Thermal Fluid Characteristics for EGR Cooler with Spiral Type (Spiral 구조 EGR Cooler의 열유동 특성 평가)

  • 허형석;원종필;박경석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.44-50
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    • 2003
  • Cooled EGR is an effective method for the reduction of NOx from a diesel engine and an EGR Cooler is the key component of the system. High efficiency, low pressure loss and compactness are required for the EGR Cooler. To meet these requirements, new geometric tube must be developed. In this paper, a full size EGR cooler test bench has been developed to validate the CFD flow and heat transfer models. Fluid temperature and pressure drop measurements are provided. fillet temperature is $200^{\circ}C$ and $300^{\circ}C$, and flow rates vary from 0.008 kg/sec to 0.019 kg/sec. The gas flow and heat transfer in a single tube cooler have been studied using computational fluid dynamics(CFD). Analysis has been carried out in a single tube with a plain tube and six spirally enhanced tubes of varying pitch to depth ratio(p/e).

Multi-stage Finite Element Inverse Analysis of Elliptic Cup Drawing Processes with the Large Aspect Ratio (세장비가 큰 타원형 컵 성형 공정의 다단계 유한요소 역해석)

  • Kim, S.H.;Kim, S.H.;Huh, H.
    • Transactions of Materials Processing
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    • v.9 no.3
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    • pp.304-312
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    • 2000
  • An inverse finite element approach is employed to efficiently design the optimum blank shape and intermediate shapes from the desired final shape in multi-stage elliptic cup drawing processes. The multi-stage deep-drawing process is difficult to design with the conventional finite element analysis since the process is very complicate with the conventional finite element analysis since the process is very complicated with intermediate shapes and the numerical analysis undergoes the convergence problem even with tremendous computing time. The elliptic cup drawing process needs much effort to design sine it requires full three-dimensional analysis. The inverse analysis is able to omit all complicated and tedious analysis procedures for the optimum process design. In this paper, the finite element inverse analysis provides the thickness strain distribution of each intermediate shape through the multi-stage analysis. The multi-stage analysis deals with the convergence among intermediate shapes and the corresponding sliding constraint surfaces that are described by the analytic function of merged-arc type surfaces.

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Adaptive Pattern Search for Fast Block-Matching Motion Estimation (고속 블록 정합 움직임 추정을 위한 적응적 패턴 탐색)

  • Kwak, Sung-Keun
    • Journal of the Korea Computer Industry Society
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    • v.5 no.9
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    • pp.987-992
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    • 2004
  • There is the temporal correlation of the video sequence between the motion vector of current block and the motion vector of previous block. In this paper, we propose the improved diamond search pattern using an motion vector prediction candidate search point by the predicted motion information from the same block of the previous frame. Simulation results show that PSNR(Peak-to-Signal Noise Ratio) values are improves as high as high as 14~24% in terms of average number of search point per motion vector estimation and improved about 0.02~0.37dB on an average except the full search(FS) algorithm.

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Analysis on Aerodynamic Characteristics of the CRW Air-Vehicle (CRW 비행체의 공력특성 해석)

  • Choi Seong Wook;Kim Jai Moo
    • Journal of computational fluids engineering
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    • v.8 no.4
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    • pp.26-33
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    • 2003
  • Smart UAV Development Program, one of the 21c Frontier R&D Program sponsored by MOST(Ministry of Science and Technology), was launched in 2002 As an air vehicle for the Smart UAV, CRW(Canard Rotor/wing) concept was one of the candidates compared in trade-off study. The CRW concept has not only been proven completely but its aerodynamic characteristics not known in detail yet. Two calculation methods were adopted in this study to obtain aerodynamic data for the CRW First method was the superpose DATCOM method which is capable of three lifting sufaces, and second one is the full Navier-Stokes computation around CRW configuration using overset grid method. Basic aerodynamic characteristics of the CRW configuration was analyzed and the minimum drag level with lift to drag ratio is presented. The peculiar flow characteristics around rotor/wing and hub were also examined and considered in the configuration design.

Development of 132 kV Standard Potential Transformer and Stability Test (132 kV 초정밀 전압변성기(PT) 개발 및 안정도 평가)

  • Kwon, Sung-Won;Lee, Sang-Hwa;Jung, Jae-Kap;Kim, Mun-Seog;Kim, Jae-Young;Lee, Sung-Ha
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1387_1388
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    • 2009
  • High accurate and stable 132 kV potential transformers (PTs) including 66 kV & 22 kV PT with stability of less than 0.0033 % for 13 month and with ratio error within $\pm$ 0.024 % at full rated voltage have been developed. The PTs are useful as the reference PT of the PT comparator system in the voltage range of 11 kV to 132 kV PT.

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Radiation Characteristics of a Probe-Fed Microstrip Patch Antenna on a Finite Grounded High Permittivity Substrate

  • Kwak, Eun-Hyuk;Yoon, Young-Min;Kim, Boo-Gyoun
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1738-1745
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    • 2015
  • Radiation characteristics of a probe-fed rectangular microstrip patch antenna printed on a finite grounded high permittivity substrate are investigated systematically for various square grounded dielectric substrate sizes with several thicknesses and dielectric constants by experiment and full wave simulation. The effect of the substrate size on the radiation characteristics of a rectangular patch antenna is mainly determined by the effective dielectric constant of surface waves on a grounded dielectric substrate. As the effective dielectric constant of surface waves increases, the substrate sizes for the maximum broadside gain and the required onset for a large magnitude of squint angle decrease, while the variations of the broadside gain, the front-to-back ratio, and the magnitude of squint angle versus the substrate size increase due to the increase of the power of the surface wave.

On the Method for Hot-Fire Modeling of High-Frequency Combustion Instability in Liquid Rocket Engines

  • Sohn, Chae-Hoon;Seol, Woo-Seok;Valery P. Pikalov
    • Journal of Mechanical Science and Technology
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    • v.18 no.6
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    • pp.1010-1018
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    • 2004
  • This study presents the methodological aspects of combustion instability modeling and provides the numerical results of the model (sub-scale) combustion chamber, regarding geometrical dimensions and operating conditions, which are for determining the combustion stability boundaries using the model chamber. An approach to determine the stability limits and acoustic characteristics of injectors is described intensively. Procedures for extrapolation of the model operating parameters to the actual conditions are presented, which allow the hot-fire test data to be presented by parameters of the combustion chamber pressure and mixture (oxidizer/fuel) ratio, which are customary for designers. Tests with the model chamber, based on the suggested scaling method, are far more cost-effective than with the actual (full-scale) chamber and useful for injector screening at the initial stage of the combustor development in a viewpoint of combustion instabilities.

Clinical evaluation of thoracic empyema: review of 59 cases (농흉의 임상적 고찰: 59례 보)

  • 김현순
    • Journal of Chest Surgery
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    • v.15 no.3
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    • pp.274-277
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    • 1982
  • A Clinical analysis of 59 patients of thoracic empyema was done who were received surgical intervention at dept. of thoracic surgery of the C.A.F.G.H. in the period of 2.5 years from January 1979 to June 1982. Occurrence ratio of Left and Right side pleural cavity of empyema was 1: 1.4. The predisposing factors of empyema were pulmonary Tbc. [49%], Chest pain [25%], Cough [8%], in order. B.P.F. was associated with empyema in 5 cases. The pleural cavity empyema was treated with several surgical procedures and conservative measures. Among of the 59 cases, the 30 cases [50%] were treated with decortication, 12 cases [20%] with closed thoractomy drainage, 9 cases with frequent thoracenteses, 5 cases with partial decortication and thoracoplasty and 3 cases with open thoracostomy tube drainage. Among of the 59 cases thoracic empyema, the full recovery were in 32 cases [54%], partial recovery in 20 cases [34%], not improved in 3 cases [5%] and 3 cases were died. The mortality rate was 5% and the recovery rate was 89%.

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