• Title/Summary/Keyword: fuel-film

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Dependence of Nanoparticle and Combustion Characteristics of Gasoline Direct Injection Engines on Coolant Temperature (GDI 엔진의 냉각수온에 따른 연소성능 및 입자상 물질 배출 특성)

  • Lee, Hyo-Keun;Choi, Kwan-Hee;Myung, Cha-Lee;Park, Sim-Soo;Park, Jong-Il;Han, Seung-Kook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.131-136
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    • 2012
  • This paper investigated the combustion and exhaust gas characteristics of gasoline direct injection engines for various cooling water temperature. The engine-out nanoparticle emission number and size distribution were measured by a DMS-500 equipped upstream of the catalyst. A CLD-400 and an HFR-400 were equipped at the exhaust port to analyze the cyclic NOx and total hydrocarbon emission characteristics. The results showed that the nanoparticle emission number greatly increased at low coolant temperatures and that the exhaust mainly contained particulate matter of 5.10 nm. THC also increased under low temperature conditions because of fuel film on the combustion chamber. NOx emissions decreased under high temperature conditions because of the increase in internal exhaust gas recirculation. In conclusion, an engine management system control strategy for driving coolant temperature up rapidly is needed to reduce not only THC and NOx but also nanoparticle emissions.

Performance of Air Electrodes with a Surface-Polished Yttria-Stabilized Zircona Electrolyte for Thin-Film Solid Oxide Fuel Cells (박막 고체산화물 연료전지용 이트리아 안정화 지르코니아 전해질 연마표면상의 공기극 성능)

  • Lee, Yu-Gi
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.283-289
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    • 2001
  • Composite cathodes of 50/50 vol% LSM- YSZ (La$_{1-x}$Sr$_{x}$MnO$_3$-yttria stabilized zirconia) were deposited onto surface- Polished YSZ electrolytes by colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD) and studied by ac impedance spectroscopy (IS). The typical impedance spectra measured for an air/LSM- YSZ/YSZ/Pt/air cell at $700^{\circ}C$ were composed of two depressed arcs. Addition of YSZ to the LSM electrode significantly enlarged the triple-phase boundaries (TPB) length inside the electrode, which led to a pronounced decrease in cathodic resistivity of LSM-YSZ composite electrodes. Polishing the electrolyte surface to eliminate the influences of surface impurities and to enlarge the TPB length can further reduce cathode resistivity. The cathodic resistivity of the LSM- YSZ electrodes was a strong function of operation temperature, composition and particle size of cathode materials, applied current, and electrolyte surface roughness.

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Preparation of SDC electrolyte film for IT-SOFCs by electrophoretic deposition (EPD를 이용한 IT-SOFC용 SDC 전해질 필름의 제조)

  • Lee, Kyeong-Seop;Jo, Chul-Gi;Kim, Young-Soon;Shin, Hyung-Shik
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.158-158
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    • 2009
  • The electrophoretic deposition(EPD) technique with a wide range of novel applications in the processing of advanced ceramic materials and coatings, has recently gained increasing interest both in academic and industrial sector not only because of the high versatility of its use with different materials and their combinations but also because of its cost-effectiveness requiring simple apparatus. Compared to other advanced shaping techniques, the EPD process is very versatile since it can be modified easily for a specific application. For example, deposition can be made on flat, cylinderical or any other shaped substrate with only minor charge in electrode design and positioning[1]. The synthesis of the nano-sized Ce0.2Sm0.8O1.9(SDC)particles prepared by aurea based low temperature hydrothermal process was investigated in this study[2].When we made the SDC nanoparticles, changed the time of synthesis of the SDC. The SDC nanoparticles were characterized with field-emission scanning electron microscope(FESEM), energy dispersive X-ray analysis(EDX), and X-ray diffraction(XRD). And also we researched the results of our investigation on electrophoretic deposition(EPD) of the SDC particles from its suspension in acetone solution onto a non-conducting NiO-SDC substrate. In principle, it is possible to carry out electrophoretic deposition on non-conducting substrates. In this case, the EPD of SDC particles on a NiO-SDC substrate was made possible through the use of a adequately porous substrate. The continuous pores in the substrates, when saturated with the solvent, helped in establishing a "conductive path" between the electrode and the particles in suspension[3-4]. Deposition rate was found to increase its increasing deposition time and voltage. After annealing the samples $1400^{\circ}C$, we observed that deposited substrate.

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Extinguishing Characteristics of Liquid Pool Eire by Water Mist Containing Sodium Salt (나트륨 염이 첨가된 미분무수의 액체 pool fire소화특성)

  • Park Jae-Man;Shin Chang-Sub
    • Fire Science and Engineering
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    • v.19 no.3 s.59
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    • pp.13-19
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    • 2005
  • An experimental study is presented for extinguishing characteristics of liquid fuel fire by water mist containing sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing an additive, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space to measure flame temperature variation. The average evaporation rate of a water droplet containing an additive was lower than that of a pure water droplet at a given surface temperature due to the precipitation of salt in the liquid-film and change of surface tension. In case of using an additive, the flame temperature was lower than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing an additive was increased reducing flame size. And also dissociated metal atoms, sodium, were reacted as a scavenger of the major radical species OH^-,\;H^+$ which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Performance Prediction of Liquid Rocket Thrust Chambers with Nonuniform Propellant Mixing (추진제의 비균일 혼합분포를 고려한 액체로켓 추력실의 성능 예측기법 개발)

  • 김성구;최환석;한영민;이광진
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.9
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    • pp.82-88
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    • 2006
  • In order to effectively reduce thermal loads on regenerative cooled walls, fuel cooling injectors and film cooling devices have often been employed. The present study has established a numerical methodology for prediction of performance and near-wall temperature distribution taking into account the nonuniform mixing due to these additional cooling devices. A correction procedure for main propulsive parameters has also been proposed based on comparison between prediction and experimental data. Under the computational framework of this study, the predicted results were in good agreement with hot-firing test data for a 30 tonf-class full-scale combustor at the design and off-design conditions. As a consequence, the present numerical method is expected to be useful for design and evaluation of regenerative cooled liquid rocket thrust chambers.

Silicon surface texturing for enhanced nanocrystalline diamond seeding efficiency (나노결정질 다이아몬드 seeding 효율 향상을 위한 silicon 표면 texturing)

  • Park, Jong Cheon;Jeong, Ok Geun;Kim, Sang Youn;Park, Se Jin;Yun, Young-Hoon;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.86-92
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    • 2013
  • $SF_6/O_2$ inductively coupled plasmas were employed to texture Si surface as a pretreatment for nanocrystalline diamond film growth. It was found that the $SF_6/O_2$ plasma texturing provided a very wide process window where normalized roughness values in the range of 2~16 could be obtained. Significantly improved nucleation densities of ${\sim}6.5{\times}10^{10}cm^{-2}$ compared to conventional mechanical abrasion were achieved after seeding for the textured Si substrate.

Hydrophilization of a Porous Polytetrafluoroethylene Supporter by Radiation Grafting Poly(Acrylonitrile-co-Sodium Allylsulfonate) (Acrylonitrile/Sodium Allylsulfonate 공중합체 방사선 접목을 이용한 다공성 Polytetrafluoroethylene 지지체의 친수화)

  • Park, Byeong-Hee;Sohn, Joon-Yong;Yoon, Ki-Suk;Shin, Junhwa
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.293-298
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    • 2014
  • We prepared hydrophilic porous supporters for the reinforced composite fuel cell membrane by radiation grafting of acrylonitrile (AN) and hydrophilic sodium allylsulfonate (SAS) into a porous polytetrafluoroethylene (PTFE) supporter. The physicochemical properties of the supporters prepared under various reaction conditions such as molar ratio of SAS/AN, monomer concentration, and irradiation dose were evaluated. FTIR was utilized to confirm the successful introduction of SAS/AN copolymer chains into the porous PTFE. The pores of the porous PTFE film were found to be decreased with an increase in the degree of grafting by using FE-SEM and gurley number. Furthermore, by analyzing the degree of grafting, contact angle, and TBO (toluidine blue O) uptake, the hydrophilicity of the prepared supporters was found to increase with an increase in the degree of grafting.

A Study on Generalized Output Capacitor Ripple Current Equation of Interleaved Boost Converter (인터리브드 부스트 컨버터에 대한 일반화된 출력 커패시터 리플전류 수식에 관한 연구)

  • Jung, Yong-Chae
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.6
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    • pp.1429-1435
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    • 2012
  • DC-DC converter commonly used in photovoltaic systems, fuel cell systems and electric vehicles is a boost converter. The interleaved boost converter, connected in parallel by several boost converters and operated by the phase difference to reduce the input and output current ripple, has been widely used in recent years. Because of small input and output current ripples, the circuit can reduce the size of the input and output capacitors. Thus, instead of conventional electrolytic capacitor, the film capacitor with high reliability can be used and this is the life and reliability of the entire system can be improved. In this paper, the output current ripple formulas of the multi-stage interleaved boost converter are derived, and the characteristics in accordance with duty are found out. In order to verify the abovementioned contents, the derived results will make a comparison with the calculated values by using PSIM tool.

Research Activities of Transpiration Cooling for Liquid Rocket and Air-breathing Propulsions (액체로켓과 공기흡입식 추진기관을 위한 분출냉각의 연구동향)

  • Hwang, Ki-Young;Kim, You-Il;Song, In-Hyuck
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.235-240
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    • 2010
  • Transpiration cooling is the most effective cooling technique for liquid rocket and air-breathing engines operating in aggressive environments with higher pressures and temperatures. Combustor liners and turbine vanes are cooled by the coolant(air or fuel) passing through their porous walls and also the exit coolant acting as an insulating film. However, its practical implementation has been hampered by the limitations of available porous materials. The search for more practical methods of increasing the internal heat transfer within the walls has led to the development of multi-laminate porous structures, such as Lamilloy$^{(R)}$ and Transply$^{(R)}$. This paper reviews recent research activities of transpiration cooling for the propulsions of liquid rocket, gas turbine, and scramjet.

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A Study on Polarization of the Molten Carvonate Fuel Cell (용융탄산염 연료전지의 분극현상 연구)

  • Nam, S.W.;Suh, S.H.;Lim, T.H.;Oh, LH.;Hong, S.A.;Lim, H.C.
    • Transactions of the Korean hydrogen and new energy society
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    • v.3 no.2
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    • pp.55-62
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    • 1992
  • To improve the MCFC performance it is important to distingush between polarization losses occuring in the individual electrodes and other components. In this study a current interruption technique has been applied to a MCFC unit cell having a reference electrode to separately study the contributions of IR loss and other polarization losses. At a current density of $150mA/cm^2$ the IR-free polarization of a Ni anode was about 60mV while that of a NiO cathode was 130mV and the Ohmic loss of the cell was as large as 170mV suggesting that both the cathode and the cell structure need further improvement. The thin-film electrode model was used to simulate the performance of the electrodes. Both andoe data and cathode data were successfully fitted.

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