• Clean Technology
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• v.28 no.4
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• pp.331-338
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• 2022

The objective of this study is to prepare bead-type and pellet-type Pt (1 wt%)/Kieselguhr catalysts as hydrogenation catalysts for the polycyclic aromatic hydrocarbons (PAHs) included in pyrolysis fuel oil (PFO). The optimal reaction temperature to maximize the yield of saturated cyclic hydrocarbons during the PFO-cut hydrogenation reaction in a trickle bed reactor was determined to be 250 ℃. A hydrogen/PFO-cut flow rate ratio of 1800 was found to maximize 1-ring saturated cyclic compounds. The yield of saturated cyclic compound increased as the space velocity (LHSV) of PFO-cut decreased. The difference in hydrogenation reaction performance between the pellet catalyst and the bead catalyst was negligible. However, the catalyst impregnated by Pt after molding the Kieselguhr support (AI catalyst) showed higher hydrogenation activity than the catalyst molded after Pt impregnation on the Kieselguhr powder (BI catalyst), which was a common phenomenon in both the pellet catalysts and bead catalysts. This may be due to a higher number of active sites over the AI catalyst compared to the BI catalyst. It was confirmed that the pellet catalyst prepared by the AI method had the best reaction activity of the prepared catalysts in this study. The majority of the PFO-cut hydrogenation products were cyclic hydrocarbons ranging from C₈ to C₁₅, and C₁₁ cyclic hydrocarbons had the highest distribution. It was confirmed that both a cracking reaction and hydrogenation occurred, which shifted the carbon number distribution towards light hydrocarbons.

• Resources Recycling
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• v.17 no.6
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• pp.50-56
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• 2008

A polypropylene fraction collected from the stream of post-consumer plastics was pyrolyzed. The aim of this study is to observe the dependence of yield of BTEX-aromatics normally used as solvent on the reaction temperature. To reach the goal, three experiments were carried out at different temperature between 650 and $700^{\circ}C$, using a fluidized bed reactor that shows an excellent heat transfer. In the experiments, product gases were used as a fluidizing medium to maximize the amount of BTEX-aromatics at fixed flow rate and feed rate during the pyrolysis. Oil, gas and char were obtained as product fractions. Product gases were analyzed with GCs(TCD, FID) and with a GC-MS system for qualitative analysis. For an accurate analysis of product oil, the product oil was distilled under vacuum, and separated the distillation residues from oil fractions that were actually analyzed with a GC-MS system. As the reaction temperature went higher, the content of BTEX-aromatics increased. The maximal yield of BTEX-aromatics was obtained at $695^{\circ}C$ with a value of about 30%. The main compounds of product gas were $CH_4$, $C_2H_4$, $C_2H_6$, $C_3H_6$, $C_4H_{10}$ and the product gas had an higher heating value about 45MJ/kg. It could be used as a heat source for a pyrolysis plant or for other fuel applications.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.7
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• pp.1123-1130
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• 2004

Numerical simulations have been carried out to investigate the effect of nozzle hole geometry on the combustion characteristics of the large diesel engine. 6S90MC-C. Spray and combustion phenomena were examined numerically using FIRE code. Wane breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation processes. Predictions on the cylinder peak pressure and NOx emission were first verified with the experimental data to confirm the reliability of numerical calculations. The comparison results showed good agreements within the range of 0.64% and 4.6% respectively. Finally, the effects of fuel spray angle and diameter on the engine performance were investigated numerically to find the optimum nozzle hole geometry considering fuel consumption, NOx emission and heat flux of the combustion chamber wall. It was concluded that the combustion gas recirculation in cylinder by changing fuel injection direction is an effective method to reduce NOx emission by about 10% with increasing fuel oil consumption, 1.4% in a large diesel engine.

• Carbon letters
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• v.19
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• pp.72-78
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• 2016

Spinnable pitches and carbon fibers were successfully prepared from petroleum or coal pyrolysis residues. After pyrolysis fuel oil (PFO), slurry oil, and coal tar were simply filtered to eliminate the solid impurities, the characteristics of the raw materials were evaluated by elemental analysis, ¹³C nuclear magnetic resonance spectrometer, matrix-assisted laser desorption/ionization time-of-flight mass spectrometer (MALDI-TOF-MS), and so on. Spinnable pitches were prepared for melt-spinning carbon fiber through a simple distillation under strong nitrogen flow, and further vacuum distillation to obtain a high softening point. Carbon fibers were produced from the above pitches by single-hole melt spinning and additional heat treatment, for oxidization and carbonization. Even though spinnable pitches and carbon fibers were processed under the same conditions, the melt-spinning and properties of the carbon fiber were different depending on the raw materials. A fine carbon fiber could not be prepared from slurry oil, and the different diameter carbon fibers were produced from the PFO and coal tar pitch. These results seem to be closely correlated with the initial characteristics of the raw materials, under this simple processing condition.

• Journal of Power System Engineering
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• v.20 no.4
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• pp.52-62
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• 2016

Nowadays, emissions of a vehicle are been getting by testing on a chassis dynamometer and a test modes. Also, fuel efficiency is calculated by carbon-balance method that is applying the emissions(CO, THC and $CO_2$) to the fuel calculation formular. In Korea, before 2014, the formular did not include the fuel factors (density, net heat value and carbon weight fraction), but the constants were based on the fuel properties of 2000s. So, this formular did not consider a characteristic of test fuel property that was changed when progressing fuel efficiency test. The characteristics of test fuel property which was distributed in domestic have a difference of quality depending on production regions and oil-refining facilities. Because the fuel properties are variable value during refineries, crude oils and blending contents of a bio-fuel, vehicle fuel is changed for each test. Therefore, the fuel qualities need to apply for a fuel economy test. In this paper, changing patterns of a fuel properties were reviewed during history of fuel standards. Also, the appropriateness of the methods was discussed by calculating and comparing fuel economies with the fuel factors and the constants.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.3
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• pp.447-452
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• 2016

It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

• Journal of Power System Engineering
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• v.5 no.1
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• pp.64-72
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• 2001

According to the regulation of IMO, oil discharge from ships is allowed under 15ppm only and an oil filtering equipment is essential. However, for large ships using heavy fuel oil of over S.G 0.98 and viscosity 380cSt and system oil, it has been in difficulty to process with existing filtering type of oily water separator. A parallel plate type oily water separator which is one of gravity type separators can be used as an assistant equipment for the oil filtering system to meet the present IMO standard of 15 ppm, because it is an efficient method in dealing with a large amount of rich oil with high specific gravity. This work is focused on the fundamental investigation of the performance of the plate type oily water separator by visualization method and PIV(Particle Image Velocimetry) measurement to acquire multi-point velocity data simultaneously. The experimental results showed that the space of the plates acts a significant role in separating process and it was found that an important point to minimize a vortex flow is to flow a large amount of fluid in space of the plates in order to promote the efficiency of separation.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.7
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• pp.965-971
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• 2017

The primary objective of this study was to assess the energy efficiency performance of an optimized hull form capable of saving energy based on existing vessels. The bow shape of existing vessels was investigated, giving consideration to design draft and speed. Resistance performances were also assessed for existing vessels according to operating conditions. Commercial CFD codes and model test materials were used to assess effective power. An optimized hull form with minimum resistance was selected given real operating conditions. The effective horsepower of existing and optimized vessels was estimated at three speeds. Resistance performance for an optimized vessel showed a 6 % improvement in effective horsepower at design speed (12 knots) compared to existing vessels. Quasi-propulsive efficiency employed experimental data, while energy efficiency performance was analyzed based on operating days, bunker fuel oil C cost, daily fuel oil consumption and specific fuel oil consumption. Energy efficiency performance for an optimized vessel showed a gain of 30 million won per year in reduced costs at design speed (12 knots) compared to existing vessels.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.308-320
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• 2022

The high internal resistance (R_int) that develops across the sediment microbial fuel cells (SMFC) limits their power production (~4/10 mW m^-2) that can be recovered from an initial oil-contaminated sediment (OCS). In the anolyte, R_int is related to poor biodegradation activity, quality and quantity of contaminant content in the sediment and anode material. While on the catholyte, R_int depends on the properties of the catholyte, the oxygen reduction reaction (ORR), and the cathode material. In this work, the main factors limiting the power output of the SMFC have been minimized. The power output of the SMFC was increased (47 times from its initial value, ~4 mW m^-2) minimizing the SMFC R_int (28 times from its initial value, 5000 ohms), following the main modifications. Anolyte: the initial OCS was amended with several amounts of gasoline and kerosene. The best anaerobic microbial activity of indigenous populations was better adapted (without more culture media) to 3 g of kerosene. Catholyte: ORR was catalyzed in birnessite/carbon fabric (CF)-cathode at pH 2, 0.8M Na₂SO₄. At the class level, the main microbial groups (Gammaproteobacteria, Coriobacteriia, Actinobacteria, Alphaproteobacteria) with electroactive members were found at C-anode and were associated with the high-power densities obtained. Gasoline is more difficult to biodegrade than kerosene. However, in both cases, SMFC biodegradation activity and power output are increased when ORR is performed on birnessite/CF in 0.8 M Na₂SO₄ at pH 2. The work discussed here can focus on bioremediation (in heavy OCS) or energy production in future work.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.20 no.2
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• pp.152-156
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• 1987

A mixed population of marine bacteria was obtained to catalize the biodegradation of bunker-C fuel oil by means of the enrichment culture technique. Samples used for the enrichment culture were collected from sea water and sediments in the vicinity of Pusan, Chungmu, and Ulsan in Korea. As the biodegradation of bunker-C oil proceeded, the number of bacteria increased from $1.1\times10^6\;to\;8.7\times10^8$ cells per ml when pH was bufferized by 0.1 M Tris-HCl buffer to 7.6, then oil dispersion increased to $OD^{540}$ 2.2 and approximately $48\%$ of the oil was biodegradated in 10 days. Oil dispersion was absolutely dependent on the addition of nitrogen and phosphate sources in sea water. High and low sulfur-containing bunker-C and crude oil could be dispersed similarly. Bunker-C oil was dispersed rapidly at the pH ranging from 7.0 to 8.0 and dispersed to the amount of 7.5 g per liter of sea water medium.