• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.723-732
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• 2022

Cracking ammonia inside solid oxide fuel cell (SOFC) stack is a compact and simple way. To prevent sharp temperature fluctuation and increase cell efficiency, the decomposition reaction should be spread on whole cell area. This leading to a question that, how does anode thickness affect the conversion rate of ammonia and the cell voltage? Since the 0D model of SOFC is useful for system level simulation, how accurate is it to use equilibrium solver for internal ammonia cracking reaction? The 1D model of ammonia fed SOFC was used to simulate the diffusion and reaction of ammonia inside the anode electrode, then the partial pressure of hydrogen and steam at triple phase boundary was used for cell voltage calculation. The result shows that, the ammonia conversion rate increases and reaches saturated value as anode thickness increase, and the saturated thickness is bigger for lower operating temperature. The similar cell voltage between 1D and 0D models can be reached with NH₃ conversion rate above 90%. The 0D model and 1D model of SOFC showed similar conversion rate at temperature over 750℃.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.649-653
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• 2003

일반적으로 연료전지에는 알카리형(AFC)과 인산형(PAFC), 고분자형 연료전지(PEMFC) 등과 같이 비교적 저온에서 동작되는 연료전지와 고온형으로 $650^{\circ}C$에서 정온 동작되는 용융탄산염형 연료전지(MCFC)와 운전온도가 약 500~100$0^{\circ}C$로 폭넓게 적용될 수 있는 고체산화물 연료전지(혹은 고체전해질 연료전지, Solid Oxide Fuel Cell, SOFC)가 있다.(중략)

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2026-2031
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• 2007

Hydrogen is receiving much research attention as an alternative substitute for hydrocarbon fuels these days due to its cleanliness and renewability. However, hydrogen should be used with caution because of its high propensity for leak and wide flammable range. This study deals with a situation that hydrogen leaks and then forms a flammable mixture inside 1kW class residential fuel cell. The residential fuel cell was modeled as a box-shaped chamber with vent openings at the top and bottom, filled with various components such as reformer, desulfurizer, fuel cell stack and humidifier. Computational fluid dynamics (CFD) was used to simulate the diffusion, buoyant flow and accumulation of leaked hydrogen in the modeled chamber. From the simulation, the risk region vulnerable to flame was identified and the methods to minimize such hazardous region was discussed. When the vent openings are 1% of the total surface, as the quantity of hydrogen leakage increases the risk regions increases accordingly. As the vent openings of the total surface increased from 1% to 2.3%, averaged hydrogen mole fraction is under 1% in the system.

• Journal of Power Electronics
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• v.18 no.5
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• pp.1303-1314
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• 2018

To match the dynamic lower voltage of a fuel cell stack and the required constant higher voltage (400V) of a DC bus, an H-type structural Boost three-level DC-DC converter with a wide voltage-gain range (HS-BTL) is presented in this paper. When compared with the traditional flying-capacitor Boost three-level DC-DC converter, the proposed converter can obtain a higher voltage-gain and does not require a complicate control for the flying-capacitor voltage balance. Moreover, the proposed converter, which can draw a continuous and low-rippled current from an input source, has the advantages of a wide voltage-gain range and low voltage stress for power semiconductors. The operating principle, parameters design and a comparison with other converters are presented and analyzed. Experimental results are also given to verify the aforementioned characteristics and theoretical analysis. The proposed converter is suitable for application of fuel cell systems.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.1
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• pp.31-39
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• 2014

The performance of fuel cell/gas turbine hybrid systems is highly affected by system configuration. In this study, the performance of a hybrid system combining a molten carbonate fuel cell (MCFC) and an indirectly fired gas turbine was predicted. Firstly, general performance trends of the hybrid system depending on major design parameters were examined. Then, the most feasible design options with the least impact on the MCFC stack design conditions were drawn. The economic advantage of the hybrid system over the basic MCFC only system was evaluated.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.678-685
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• 2011

An Ejector enhances system efficiency, are easily operated, have a mechanically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 75-kW Molten Carbonate Fuel Cell (MCFC) system at KEPCO Research Institute. In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In the first place, a few sample ejectors were manufacured and the entrainment ratio was measured at a dummy stack. Through this experiment, the optimum ejector was chosen. The 75-kW MCFC system equipped with this optimum ejector was operated successfully.

• Journal of Electrical Engineering and Technology
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• v.5 no.2
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• pp.307-318
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• 2010

In this work, an accurate analysis of low frequency current ripple in residential fuel cell power generation systems is performed based on the proposed residential load model and its unique operation algorithm. Rather than using a constant dc voltage source, a proton exchange membrane fuel cell (PEMFC) model is implemented in this research so that a system-level analysis considering the fuel cell stack, power conditioning system (PCS), and the actual load is possible. Using the attained results, a comparative study regarding the discrepancies of low frequency current ripple between a simple resistor load and a realistic residential load is performed. The data indicate that the low frequency current ripple of the proposed residential load model is increased by more than a factor of two when compared to the low frequency current ripple of a simple resistor load under identical conditions. Theoretical analysis, simulation data, and experimental results are provided, along with a model of the load usage pattern of low frequency current ripples.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.542-545
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• 2008

Experiments have been performed to investigate effects of pulsating cathode flow on a 10-cell proton exchange membrane fuel cell (PEMFC) stack. For all the experiments, the flow rate, temperature and relative humidity of hydrogen at the anode inlet are fixed. The effects of the pulsating frequency, amplitude and flow rate at the cathode inlet on performance of 10-cell PEMFC are examined. The polarization and power curves show that the power output and limiting current is substantially increased when the pulsating component is added to cathode flow channel. The maximum power output increases by up to 38% and enhancement of the overall performance is more pronounced at lower flow rate region.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.313-315
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• 2006

Proper water management is important to achieve high performance and durability of Polymer electrolyte fuel cell (PEFC). Among various stack components, gas diffusion layer (GDL) is considered as a core part to determine the gas and water transportation in a cell. To optimize the water management, the changes of properties as well as basic properties of GDLs were investigated before and after clamping of colls. Thickness, electric conductivity, porosity, hydroppobicity etc. were characterized by the same criteria. The amount of residual water after cell operation also was compared by direct measuring of weight. Based on the amount of residual water the endurance on the freeze condition was evaluated.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.59 no.6
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• pp.1087-1094
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• 2010

We have developed a cylindrical multi-terminal capacitive-conductive sensor that could be attached to the internal surface of cooling system pipe to evaluate capacitance and conductivity of heat transfer fluid. It was used as measuring system to diagnose insulating condition, by which was kept a insulating resistance of inner stack and at the same time was cooled electrochemical heat of reaction of FCEV(fuel cell electric vehicle) stack that used a compressed hydrogen gas reacting with oxygen in accordance with variation on thermal degradation of nonconductive heat transfer fluid. Also to assess diagnosis characteristics of heat transfer fluid, i.e. coolant, we have performed accelerated aging test using developed sensor attached to cooling system. Consequently, it was measured dielectric and electric resistance of coolant to estimate and analyse for dielectric properties by degradation condition.