• Journal of Electrochemical Science and Technology
• /
• v.7 no.4
• /
• pp.277-285
• /
• 2016

There is a growing demand for simple, cost-effective, and accurate analytical tools to determine the concentrations of biological and environmental compounds. In this study, a stable electroactive thin film of cobalt hexacyanoferrate (Cohcf) was prepared as an in situ chemical precipitant using electrostatic adsorption of $Co^{2+}$ on a silicate sol-gel matrix (SSG)-modified indium tin oxide electrode pre-adsorbed with $[Fe(CN)_6]^{3-}$ ions. The modified electrode was characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical techniques. Electrocatalytic oxidation of hydrazine on the modified electrode was studied. An electrochemical sensor for hydrazine was constructed on the SSG-Cohcf-modified electrode. The oxidation peak currents showed a linear relationship with the hydrazine concentration. This study provides insight into the in situ growth and stability behavior of Cohcf nanostructures and has implications for the design and development of advanced electrode materials for fuel cells and sensor applications.

• Journal of the Korean Ceramic Society
• /
• v.50 no.6
• /
• pp.390-395
• /
• 2013

Nanocrystalline CrN films were deposited on Si (100) substrates by means of asymmetric pulsed DC reactive magnetron sputtering. We investigated the growth behavior, corrosion resistance and mechanical properties of CrN films with a change in the duty cycle and pulse frequency. The grain size of the CrN films decreased from 25.4 nm to 11.2 nm upon a decrease in the duty cycle. The corrosion potentials for the CrN films by DC sputtering was approximately - 0.6 V, and it increased to - 0.3 V in the CrN films which underwent pulsed sputtering. The nanoindentation hardness of the CrN films also increased with a decrease in the duty cycle. This enhancement of the corrosion resistance and mechanical properties of pulsed sputtered CrN films could be attributed to the densification and surface smoothness of the microstructure of the films.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.6
• /
• pp.1543-1550
• /
• 2010

This work presents oxidation of formic acid on Bi-modified Pt nanoparticles of various sizes. The sizes of the studied Pt nanoparticles range from 1.5 to 5.6 nm (detailed in Rhee, C. K.; Kim, B.-J.; Ham, C.; Kim, Y.-J.; Song, K.; Kwon, K. Langmuir 2009, 25, 7140-7147), and the surfaces of the Pt nanoparticles are modified with irreversibly adsorbed Bi. The investigated coverages of Bi on the Pt nanoparticles are 0.12 and 0.25 as determined by coulometry of the oxidation of adsorbed hydrogen and Bi, and X-ray photoelectron spectroscopy. The cyclic voltammetric behavior of formic acid oxidation reveals that the adsorbed Bi enhances the catalytic activity of Pt nanoparticles by impeding a poison-forming dehydration path with a concomitant promotion of a dehydrogenation path. The chronoamperometric results indicate that elemental Bi and partially oxidized Bi are responsible for the catalytic enhancement, when the Bi coverages on Pt nanoparticles are 0.12 and 0.25, respectively. The size effect of Bi-modified Pt nanoparticles in formic acid oxidation is discussed in terms of specific activity (current per unit surface area) and mass activity (current per unit mass).

• Journal of computational fluids engineering
• /
• v.14 no.2
• /
• pp.59-67
• /
• 2009

An accurate prediction of the bypass flow is of great importance in the VHTR core design concerning the fuel thermal margin. Nevertheless, there has not been much effort in evaluating the amount and the distribution of the core bypass flow. In order to evaluate the behavior and the distribution of the coolant flow, a unit-cell experiment was carried out. Unit-cell is the regular triangular section which is formed by connecting the centers of three hexagonal blocks. Various conditions such as the inlet mass flow rate, block combinations and the size of bypass gap were examined in the experiment. CFD analysis was carried out to analyze detailed characteristics of the flow distribution. Commercial CFD code FLUENT 6.3 was validated by comparing with the experimental results. In addition, SST model and standard k-$\varepsilon$ model were validated. The results of CFD simulation show good agreements with the experimental results. SST model shows better agreement than standard k-$\varepsilon$ model. Results showed that block combinations and the size of the bypass gap have an influence on the bypass flow ratio but the inlet mass flow rate does not.

• Coupled systems mechanics
• /
• v.1 no.3
• /
• pp.285-295
• /
• 2012

In this paper, two types of porous burners with radial and axial flow have been modeled numerically and compared. For this purpose, governing equations were solved one-dimensionally for methane-air premix gas. The mechanism used in simulating combustion phenomenon was 15 stage reduced mechanism based on GRI3.0. In order to compare the two burners, the inlet flow rate and fuel-air ratio have been assumed equal for the two burners. The results of the study indicated that reduction in speed and increase in cross-section area in the direction of flow have a considerable influence on the behavior of radial burner in comparison to axial burner. Regarding temperature distribution inside the burner, it was observed that the two above mentioned factors can be influential in temperature of flame propagation region. Also, regarding distribution of CO and NO emission, the results indicate that the porous radial burner has lower emissions in comparison to the axial once. The output radiative heat transfer efficiency of the two burners was also compared and in this case also even the radial porous burner was found to be preferable.

• Journal of ILASS-Korea
• /
• v.19 no.2
• /
• pp.75-81
• /
• 2014

Swirl flow in the gun type burner has a decisive effect on the stabilization of the flame, improvement of the combustion efficiency, and also a reduction of NOx. This swirl flow is created by the spinner which is inside the airtube that guide the combustion air. Gun type burner has generally the inner devices composed nozzle adapter, spark gap ignitor, and spinner. These inner components change the air flow behavior passing through air tube. Meanwhile, turbulent characteristics of this air flow are important to understand the combustion phenomena in the gun type burner, because the mixture of fuel and air are depended on. However, nearly all of the studies have been analyzed the turbulent flow of simplified combustion formation without the inner devices. So, this study conducted the measurement using by hot-wire anemometer and analyzed turbulent flow characteristics of the swirl flow discharged from the air tube with inner devices. Turbulence characteristics come up in this study were turbulence intensity, kinetic energy and shear stress of the air flow with the change of the distance of axial direction from the exit of the air tube.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2004.03a
• /
• pp.499-505
• /
• 2004

A Propulsion System of the CRW(Canard Rotor Wing) type UAV(Unmanned Aerial Vehicle) was composed of the turbojet engine to generate the propulsive exhaust gas, and the duct system including straight bent ducts, tip-jet nozzles, a master valve and a variable main nozzle for three flight modes such as lift/landing mode, low speed transition flight mode and high speed forward flight mode. In this study, in order to operate safely the propulsion system, the dynamic Performance behavior of the system was modeled and simulated using the SIMULIN $K^{ }$, which is the user-friendly GUI type dynamic analysis tool provided by MATLA $B^{ }$. In the transient performance model, the inter-component volume model was used. The performance analysis using the developed models was performed at various flight condition, valve angle positions and fuel flow schedules, and these results could set the safe flight mode transition region to satisfy the inlet temperature overshoot limitation as well as the compressor surge margin. Performance analysis results using the SIMULIN $K^{ }$ performance program were compared with them using the commercial program GSP.m GSP.

• Proceedings of the Korean Vacuum Society Conference
• /
• 1995.06a
• /
• pp.151-151
• /
• 1995

Nitrogen implantation process has been applied for improvement of wear resistance of Z Zircaloy-4 fuel cladding materials. Nitrogen was implanted at 120 ke V to a total do range of 1xHP ions/cm2 to 8xlO17 ions/cm2 at various temperatures of 298"C to 676"C. The m microstructure changes by nitrogen implantation were analyzed by using TEM, XRD 뻐d A AES, cmd then wear behavior was evaluated by ball-on-disc wear testings at various loads a and sliding velocity under unlubricated condition. Nitrogen implantation produced ZrNx nitride above 4.37x1017 ions!cm2 as well as heavy d dislocations, which enhanced microhardness of the implanted surface of up to 900 Hk from 2 200 Hk of unimplanted substrate. Hardness was also found to be increased with increasing i implantation temperature and enhanced up to OOOHk at 620 "C. the wear resistance was g greatly improved with increasing total ion do않 as well as implantation temperature. The effective enhancement of wear resistance at high dose and tem야ratures is believed d due to significant hardening associated with high degree of precipitation of Zr nitrides and g generation of prismatic dislocation I$\infty$ps.infty$ps.

• International Journal of Automotive Technology
• /
• v.8 no.2
• /
• pp.149-154
• /
• 2007

The engine behavior in a transient condition is important to not only emission regulations but also fuel economy. A fast response gas analyzer can be a useful tool to investigate exhaust gas in a transient operation. It should be designed to analyze gas concentration with a short time constant by a fast sampling module and an appropriate measuring method for each emission element. In this study, a new fast sampling module is introduced and flow analysis is performed by numerical simulation. The analysis has shown the proper operating condition and the sensitivity of the module for practical application. Calculated flow to the sampling module has $0.5{\sim}4%$ error, while backflow toward the expansion tube is expected when pressure in CP (Constant Pressure) chamber is over 0.6 bar. For a stable supply of flow to the optical cell, sample gas pressure should be in the range, $0.35{\sim}1.90$ bar, when the pressure in the CP camber and the optical cell are 0.2 bar and 0.158 bar, respectively.

• Journal of the Korean institute of surface engineering
• /
• v.27 no.4
• /
• pp.207-214
• /
• 1994

In consideration of global environmental protection and fuel saving, aluminum alloy sheets for auto body panels such as hood, fender etc., are expected one of the most promising materials for weight saving of cars. The chemical conversion coating is required to prevent the filiform corrosion occurring on painted aluminum. However the conventional process for the composited material mixed with aluminum and steel is complexs; aluminum part is chromated and assembled to the body, and then the steel body undergoes Zn phosphating. In order to overcome the low productivity due to the complex process and the environmental problem with a conventional process, a simultaneous zinc phosphating process for alsuminum and steel in an assembled condition is demanded. Newly developed phosphate solution has been investigated to characterize the phosphating behavior under various conditions. The optimum conditions of the phosphating solution for the application of the paint treatment derived as follows : about 0.3 for the ratio of Zn to $PO_4$, , 200~500 ppm for the concentration of fluoride ion, and 2.5~4.0 for pH. The concentration of dissolved aluminum ion must be kept below 2--ppm and suitable accelerator is found to be a mixture of 1g/$\ell$ $NO_2\;^-$, and 6g/$\ell$ $NO_3\;^-$.