• Title/Summary/Keyword: frequency shifts

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Fluorescence Excitation Spectroscopy of Octatetraene-Xe van der Waals Clusters

  • Kim, Taek-Soo;Choi, Kyo-Won;Kim, Sang-Kyu;Choi, Young-S.;Park, Sung-Woo;Ahn, Doo-Sik;Lee, Sung-Yul;Yoshihara, Keitaro
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.195-200
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    • 2002
  • Fluorescence excitation spectrum of the trans.trans-1,3,5,7-octatetraene(OT)-Xe van der Waals clusters formed in supersonic jet expansions has been obtained. The transition lines corresponding to the van der Waals cluters of OT with Xe are observed in the lower frequency side of the OT band origin. Based on the spectral shifts, fluorescence lifetimes, and concentration dependence of the peak intensities, most of the transition lines are assigned to the $OT-Xe_n$ (n = 1, 2, 3, 4) clusters. Long progressions of a van der Waals vibrational mode are observed for n = 1, 2, 3 and 4 clusters and assigned to rocking of the OT moiety with respect to the Xe atom with the help of ab initio quantum mechanical calculation.

Numerical Investigation on Radiation Characteristics of Noise Propagating through Asymmetry Aero-Intake (비대칭 공기흡입구를 통해 전파하는 소음의 방사특성에 관한 수치적 연구)

  • Park, Yong-Hwan;Kim, Min-Woo;Lee, Kyu-Ho;Lee, Soo-Gab
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.1476-1481
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    • 2007
  • Numerical investigation on radiation characteristics of discrete frequency noise from asymmetry aero-intakes was carried out. The near-field predictions were obtained by solving the linearized Euler equations with computational aeroacoustic techniques consisting of high order finite difference scheme, non-reflecting boundary conditions, oversetgrid techniques. For the prediction of far-field directivity pattern, the Kirchhoff integral method was applied. By comparing the directivities of noise radiating from the scarf and the scoop aero-intakes with that from an axisymmetric aero-intake, it is shown that noise reduction at downward peak radiation angle can be achieved. The scattering of the radiating acoustic wave by background mean flow shifts the peak lobe radiation angle toward ground and increases the amplitude of the acoustic pressure compared with the cases without mean flow effect.

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Design and Simulation of Tunable Dielectric Multilayer (TDM) Filters for RF and MMIC Applications (MMIC화를 위한 RF용 튜닝가능한 다층 박막 유전체 필터 설계 및 시뮬레이션)

  • 윤기완;채동규;임문혁;김동현
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.4
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    • pp.730-735
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    • 2003
  • In this paper, four different types of BSTO tunable bandpass filters with ferroelectrics are proposed. The achievement of the tunability is based on the fact that the increase in the bias voltage leads to the reduction of the effective dielectric constant. Therefore, the center frequency shifts to the higher value with the higher bias voltage. The most frequently used and well-known ferroelectrics are STO and BSTO materials where the STO is mainly used below 100K while the BSTO is used at room temperature. The proposed technology seems very useful and promising for the development of the next-generation wireless communications.

Improvement of CAF estimation performance (CAF 계산의 효율성 개선과 성능 향상)

  • Cho, Se-Young;Kim, Soo-Young
    • Journal of Satellite, Information and Communications
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    • v.4 no.1
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    • pp.21-27
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    • 2009
  • In this paper, we introduce a simulation result of cross ambiguity function (CAF) using time difference of arrival and frequency difference of arrival. This method is generally used to find a geographical location of the unknown radio transmitter. If multiple signals with the same source information are arrived at a receiver via different paths, then they will have different time delays and Doppler shifts. We can estimate the CAF by using these characteristics, and estimate the location of the unknown transmitter. This paper introduces a technique to improve the estimation performance of CAF.

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Dynamic instability response in nanocomposite pipes conveying pulsating ferrofluid flow considering structural damping effects

  • Esmaeili, Hemat Ali;Khaki, Mehran;Abbasi, Morteza
    • Structural Engineering and Mechanics
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    • v.68 no.3
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    • pp.359-368
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    • 2018
  • This paper deals with the dynamic stability of nanocomposite pipes conveying pulsating ferrofluid. The pipe is reinforced by carbon nanotubes (CNTs) where the agglomeration of CNTs are considered based on Mori-Tanaka model. Due to the existence of CNTs and ferrofluid flow, the structure and fluid are subjected to axial magnetic field. Based on Navier-Stokes equation and considering the body forced induced by magnetic field, the external force of fluid to the pipe is derived. For mathematical modeling of the pipe, the first order shear deformation theory (FSDT) is used where the energy method and Hamilton's principle are used for obtaining the motion equations. Using harmonic differential quadrature method (HDQM) and Bolotin's method, the motion equations are solved for calculating the excitation frequency and dynamic instability region (DIR) of the structure. The influences of different parameters such as volume fraction and agglomeration of CNTs, magnetic field, structural damping, viscoelastic medium, fluid velocity and boundary conditions are shown on the DIR of the structure. Results show that with considering agglomeration of CNTs, the DIR shifts to the lower excitation frequencies. In addition, the DIR of the structure will be happened at higher excitation frequencies with increasing the magnetic field.

AC susceptibility of the $high-T_c$ superconductor $SmBa_2Cu_2O_y$ (고온초전도체 $SmBa_2Cu_2O_y$ 교류자화율)

  • Kim H;Lee B. Y;Lee J. H;Kim Y. C
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.89-94
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    • 2004
  • The policrystalline$SmBa_2$$Cu_2$$O_{y}$ was synthesized by the solid state reaction method. The dependence of AC susceptibility on temperature and applied ac field was studied. The critical temperature $T_{c}$ is about 92 K. As the ac field is increased, the slope and the value of real part of susceptibility become smaller and the peak position of imaginary part $T_{P}$ was shifted to a lower temperature with peak broadening. Using Bean's model, we determined intergrain critical current density $J_{c}$ and obtained $44 A/{cm}^2$ at 75 K. From the relation of the $J_{c}$ (T)=($1-T/T_{c}$ )$^{\beta}$ we obtained $\beta$=0.8 and found that the Josephson junction type of the $SmBa_2$$Cu_2$$O_{y}$ is SIS junction. The peak of the imaginary part shifts to higher temperature with increasing frequency, f. from Arrhenius plot, we obtained the activation energy of about 0.96 eV.

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Reaction Monitoring of Imine Synthesis Using Raman Spectroscopy

  • Lee, Moon-Kwon;Kim, Hye-Sung;Rhee, Hak-June;Choo, Jae-Bum
    • Bulletin of the Korean Chemical Society
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    • v.24 no.2
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    • pp.205-208
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    • 2003
  • Laser-induced Raman spectroscopy has been utilized to demonstrate its feasibility for studying the kinetics of imine formation in chloroform solvent. The imine formation, by the nucleophilic addition of primary amine to the carbonyl group of ketone, has been monitored at ten minute intervals for eight hours. The intensity of the C=O stretching mode at 1684 $cm^{-1}$ was measured to determine the rate constant of the reaction. In order to correct the sample-to-sample fluctuations in Raman peak area, this peak was normalized to the C-Cl bending peak at 666 $cm^{-1}$. By the peak area change during the course of reaction, the second order rates at three different temperatures have been determined. The substituent effects on the π conjugations of imine product have also been investigated. On the basis of Raman frequency shifts, the delocalization properties of the aromatic system modified by substitution of a hydrogen atom with -Cl and $-CH_3O$ groups could be clearly understood.

Dynamic stability of nanocomposite Mindlin pipes conveying pulsating fluid flow subjected to magnetic field

  • Esmaeili, Hemat Ali;Khaki, Mehran;Abbasi, Morteza
    • Structural Engineering and Mechanics
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    • v.67 no.1
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    • pp.21-31
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    • 2018
  • In this work, the dynamic stability of carbon nanotubes (CNTs) reinforced composite pipes conveying pulsating fluid flow is investigated. The pipe is surrounded by viscoelastic medium containing spring, shear and damper coefficients. Due to the existence of CNTs, the pipe is subjected to a 2D magnetic field. The radial induced force by pulsating fluid is obtained by the Navier-Stokes equation. The equivalent characteristics of the nanocomposite structure are calculated using Mori-Tanaka model. Based on first order shear deformation theory (FSDT) or Mindlin theory, energy method and Hamilton's principle, the motion equations are derived. Using harmonic differential quadrature method (HDQM) in conjunction with the Bolotin's method, the dynamic instability region (DIR) of the system is calculated. The effects of different parameters such as volume fraction of CNTs, magnetic field, boundary conditions, fluid velocity and geometrical parameters of pipe are shown on the DIR of the structure. Results show that with increasing volume fraction of CNTs, the DIR shifts to the higher frequency. In addition, the DIR of the structure will be happened at lower excitation frequencies with increasing the fluid velocity.

A Level Shifter Using Aluminum-Doped Zinc Tin Oxide Thin Film Transistors with Negative Threshold Voltages

  • Hwang, Tong-Hun;Yang, Ik-Seok;Kim, Kang-Nam;Cho, Doo-Hee;KoPark, Sang-Hee;Hwang, Chi-Sun;Byun, Chun-Won;Kwon, Oh-Kyong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.464-465
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    • 2009
  • A new level shifter using n-channel aluminum-doped zinc tin oxide (AZTO) thin film transistors (TFTs) was proposed to integrate driving circuits on qVGA panels for mobile display applications. The circuit used positive feedback loop to overcome limitations of circuits designed with oxide TFTs which is depletion mode n-channel TFTs. The measured results shows that the proposed circuit shifts 10 V input voltage to 20 V output voltage and its power consumption is 0.46 mW when the supply voltage is 20 V and the operating frequency is 10 kHz.

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Fatigue Patterns on Trunk Muscles at Various Asymmetric Twisting Conditions (비틀림 동작에서의 허리근육의 피로도 패턴)

  • Jo, Yeong-Jin;Kim, Jeong-Ryong
    • Journal of the Ergonomics Society of Korea
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    • v.20 no.2
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    • pp.71-82
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    • 2001
  • Twisting posture in lifting tasks has been identified as a risk factor of low back pain. However, it has been usually estimated in terms of compressive stress or muscular activity. Thus, this study was conducted to predict the influence on muscular fatigue during lifting simulation. Fifteen young and healthy subjects were recruited and performed isometric trunk exertions during upright standing, two-level flexions and five-level asymmetric twisting conditions. EMG signals from five primary trunk muscles in right part of body were collected during 20sec for 45 different lifting conditions. RMS(root mean square) and MPF(mean power frequency) parameters were used to analyze the EMG signals. Twisting postures were significant in right erector spinae(ERSR), right latissimus dorsi(LATR), right internal oblique(INOR) for muscular activities. Especially, when trunk was $30^{\circ}$ CCW twisting posture. ERSR and INOR activities increased respectively by 11% and 3%. Regarding the trunk muscle fatigue, we found that MPF shifts in twisting posture increased 2.3 and 2.6 times for ERSR and INOR muscles respectively. Therefore, It is probable for workers to suffer from low back disorders when they were exposed to a extreme twisting posture during prolonged lifting. This study suggests NIOSH(National Institute for Occupational Safety and Health) lifting equation needs the time-duration multiplier in addition to asymmetric multiplier.

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