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Optimization of Soybean Oil Fatty Acid Methyl Esters Preparation for Sucrose Polyesters Synthesis (Sucrose polyesters 합성에 사용하는 대두유 지방산 메틸에스테르 제조의 최적화)

  • Chung, Ha-Yull;Kim, Suk-Ju;Yoon, Sung-Woo;Yoon, Hee-Nam;Kong, Un-Young
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.240-246
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    • 1992
  • Preparation of soybean oil fatty acid methyl esters (soybean oil FAME) through the transesterification of soybean oil with alkaline catalyst was optimized in terms of contents of residual free fatty acids (FFA) in soybean oil FAME and yield of soybean oil FAME due to the inhibitory effect of FFA on sucrose polyesters synthesis. Soybean oil FAME and residual FFA were analyzed quantitatively by simultaneous gas chromatography on a fused silica capillary column after converting the FFA in soybean oil FAME to tert.-butyldimethylsilyl (TBDMS) derivatives. Transesterification of soybean oil was successfully performed with alkaline catalyst (NaOH, 95%), which resulted in 99.1% yield of soybean oil FAME and less than 0.1% residual FFA contents under the conditions such as $30^{\circ}C$, 20min. and 6:1 molar ratio of anhydrous methanol to soybean oil.

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A Study for Automotive Lamp Manufacturing System Control Composing Ultra melting Process (초음파 접합 공정을 합성한 자동차용 램프 생산시스템 제어에 관한 연구)

  • Lee, Il-Kwon;Kook, Chang-Ho;Kim, Seung-Chul;Kim, Ki-Jin;Han, Ki-Bong
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.46-51
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    • 2014
  • The purpose of this paper is to study of the vehicle lamp manufacturing system composing ultrasonic waves connection process. Making lamp assembly plant, it was produced in the separate process as the injection molding, ultrasonic waves bonding, annealing in the constant temperature, lamp assembling and packing. But the improvement method producing the lamp was added with one-step process by one automation technique. As a result, welding with ultrasonic waves process, the method decreased the energy consumption and noise during ultrasonic waves welding. Therefore, this method used the mathematics modeling for checking validity, it selected the stability and suitable controller using transfer function of plant and bode chart. In this study, the $180^{\circ}$ revolution control system to turn injection part upside down was $M_{eq}\;lcos{\theta}(t)$ because of gravity influence. It effected to unstable condition a system. For solving this problem, it aimed the linearization and stabilization of system by elimination $M_{eq}\;lcos{\theta}(t)$ as applying Free-forward control technique.

Improvement of Adhesion Between metal and Polymer by Ion Assisted Reaction (IAR) (이온 보조 반응법을 이용한 금속과 고분자의 접착력 향상)

  • 최성창;김현주;고석근
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.221-228
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    • 1998
  • Enhancement of adhesion between polymer films and metal films are obtained by forming the hydrophilic functional groups on the polymer surfaces by ion assisted reaction which uses ion beam in reactive gas environments. In ion assisted reaction, ion dose, blown gas flow rate and ion energy were changed from $5\times 10^{14}$ to $1\times 10^{17}\textrm{ions/cm}^2$, from 0 to 8 sccm, and 0.3 to 1.2 kV, respectively. Wetting angle of water on polymer films modified by $ Ar^+$ ion without blowing oxygen decreases to ~$40^{\circ}$. Contact angle of water on polymer films modified by $ Ar^+$ ion with blowing oxygen decreases to ~$20^{\circ}$, and the surface free energy increases to ~70 dyne/$\textrm{cm}^2$. However, contact angle of water on polytetraflouroethylene (PTFE) modified by ion assisted reaction increases with ion dose. The adhesion strength of metal film deposited on the polymer surface was investigated. In the case of the metal film deposited on the untreated polymers, the metal films are detached from the polymer surface. While, In the case of the metal film deposited on the polymers treated by ion assisted reaction, the metal films are strongly adhere to the polymer surfaces.

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Implementation of an Earthquake Alarming System Based on Acceleration Monitoring at Coastal LNG Receiving Terminals (해안 천연가스 인수기지에 대한 가속도 계측 기반의 지진경보 시스템 구축)

  • Sun, Chang-Guk;Jung, Byung-Sun;Kim, Joon-Ho;Hong, Seong-Kyeon;Kim, Ki-Seog
    • The Journal of Engineering Geology
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    • v.20 no.3
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    • pp.339-348
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    • 2010
  • As part of preparing for future earthquakes near three LNG receiving terminals located in coastal regions of Korea, acceleration monitoring systems were installed at four free field sites and on a pile foundation beneath a storage tank in a receiving terminal. Several equipments and accessories were devised to successfully install and operate the monitoring system at LNG receiving terminals. Synthetic earthquake-alarming software systems designed for decisionmaking, based on peak ground acceleration computed using the measured data, were developed for rapid response during earthquakes, not only in each local terminal area but also in the central control division. In addition, a framework software linking nationwide data on peak ground accelerations was included in the integrated earthquake alarming system in the central division, for various future applications. The earthquake alarming systems developed in this research for LNG receiving terminals, based on acceleration monitoring, represent a useful framework for industrial facilities located in coastal regions, where geotechnical conditions may show marked spatial variations.

Effect of an Aqueous Chlorine Dioxide Generator and Effect on Disinfection of Fresh Fruits and Vegetables by Immersion Washing (이산화염소수 생성기의 생성효율 및 과.채류에 대한 침지 세정 살균효과)

  • Park, Kee-Jai;Jeong, Jin-Woong;Lim, Jeong-Ho;Jang, Jae-Hee;Park, Hee-Joo
    • Food Science and Preservation
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    • v.15 no.2
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    • pp.236-242
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    • 2008
  • We investigated the optimum concentration of a $NaClO_2$ solution and the amount of gaseous $Cl_2$ for production of high yield and purity of aqueous $ClO_2$ by use of a gaseous chlorine-chlorite $ClO_2$ generator. This system produced lower concentrations of chlorine dioxide and is applicable for direct-use in food processing as a cleaner and sanitizer. The concentration of $NaClO_2$ solution and the amount of gaseous $Cl_2$ was varied from 0.01-0.1% and 100-1,000 g/hr, respectively. The concentrations of chlorite, chlorate, FAC (free available chlorine), and chlorine dioxide that were produced increased with increasing concentration of $NaClO_2$ solution and with the amount of gaseous $Cl_2$. The optimum concentration of $NaClO_2$ solution and amount of gaseous $Cl_2$ were 0.1% and 900 g/hr respectively. $ClO_2$ and FAC produced at these concentrations were 882.0 ppm and 8.0 ppm, with no detection of chlorite and chlorate. The yield and purity of $ClO_2$ were 97.0% and 96.0% respectively. Immersion-cleaning experiments showed that this protocol decreased the level of CFU/g by $10^3$- to $10^4$-fold, with a similar effect on fruit.

Effect of Hydrogen(H2) Addition on Flame Shape and Combustion Products in Mixed Coflow Diffusion Flames of Methane(CH4), Ethane(C2H6) and Propane(C3H8) (동축류 메탄(CH4), 에탄(C2H6), 프로판(C3H8) 혼합 확산화염내의 수소(H2) 첨가가 화염 형상 및 연소 생성물에 미치는 영향)

  • Park, Ho-Yong;Yoon, Sung-Hwan;Rho, Beom-Seok;Lee, Won-Ju;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.6
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    • pp.780-787
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    • 2019
  • As a carbon-free, green growth alternative, internal and external interest in hydrogen energy and technology is growing. Hydrogen was added to co-axial methane, methane-propane, and methane-propane-ethane diffusion flames, which are the main ingredients of LNG, to evaluate its effect on flame formation and combustion products. The variation in combustion products produced by adding hydrogen gradually to diffusion pyrolysis at room temperature and normal pressure conditions was observed experimentally by using a gas analyzer, and the shape of diffusion pyrolysis was observed step by step using a digital camera. The experimental results showed that the production volume of nitrogen oxides tended to increase and became close to linear as hydrogen was added to the diffusion pyrotechnic. This is because the relatively high temperature of heat insulation and fast combustion speed of hydrogen facilitated the production of thermal NOx. On the other hand, CO2 production tended to decrease as hydrogen was added to reduce the overall carbon ratio contained in the mixed diffusion flame of methane, methane-propane, and methane-ethane-propane. This means that the mixed fuel use of LNG-hydrogen in ships may potentially reduce emissions of CO2, a greenhouse gas.

Seismic attenuation from VSP data in methane hydrate-bearing sediments (메탄 하이드레이트 부존 퇴적층으로부터 획득한 수직탄성파 (VSP) 자료에서의 탄성파 진폭 감쇠)

  • Matsushima, Jun
    • Geophysics and Geophysical Exploration
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    • v.10 no.1
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    • pp.29-36
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    • 2007
  • Recent seismic surveys have shown that the presence of methane hydrate (MH) in sediments has significant influence on seismic attenuation. I have used vertical seismic profile (VSP) data from a Nankai Trough exploratory well, offshore Tokai in central Japan, to estimate compressional attenuation in MH-bearing sediments at seismic frequencies of 30-110 Hz. The use of two different measurement methods (spectral ratio and centroid frequency shift methods) provides an opportunity to validate the attenuation measurements. The sensitivity of attenuation analyses to different depth intervals, borehole irregularities, and different frequency ranges was also examined to validate the stability of attenuation estimation. I found no significant compressional attenuation in MH-bearing sediments at seismic frequencies. Macroscopically, the peaks of highest attenuation in the seismic frequency range correspond to low-saturation gas zones. In contrast, high compressional attenuation zones in the sonic frequency range (10-20 kHz) are associated with the presence of methane hydrates at the same well locations. Thus, this study demonstrated the frequency-dependence of attenuation in MH-bearing sediments; MH-bearing sediments cause attenuation in the sonic frequency range rather than the seismic frequency range As a possible reason why seismic frequencies in the 30-110 Hz range were not affected in MH-bearing sediments, I point out the effect of thin layering of MH-bearing zones.

A Study on the Application of SAW Process for Thin Plate of 3.2 Thickness in Ship Structure (선체외판부 3.2T 박판에 대한 SAW 용접 적용에 관한 연구)

  • Oh, Chong-In;Yun, Jin-Oh;Lim, Dong-Young;Jeong, Sang-Hoon;Lee, Jeong-Soo
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.51-51
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    • 2010
  • Recently just as in the automobile industry, shipbuilders also try to reduce material consumption and weight in order to keep operating costs as low as possible and improve the speed of production. Naturally industry is ever searching for welding techniques offering higher power, higher productivity and a better quality. Therefore it is important to have a details research based on the various welding process applied to steel and other materials, and to have the ability both to counsel interested companies and to evaluate the feasibility of implementation of this process. Submerged-arc welding (SAW) process is usually used about 20% of shipbuilding. Similar to gas metal arc welding(GMAW), SAW involves formation of an arc between a continuously-fed bare wire electrode and the work-piece. The process uses a flux to generate protective gases and slag, and to add alloying elements to the weld pool and a shielding gas is not required. Prior to welding, a thin layer of flux powder is placed on the work-piece surface. The arc moves along the joint line and as it does so, excess flux is recycled via a hopper. Remaining fused slag layers can be easily removed after welding. As the arc is completely covered by the flux layer, heat loss is extremely low. This produces a thermal efficiency as high as 60% (compared with 25% for manual metal arc). SAW process offers many advantages compared to conventional CO2 welding process. The main advantages of SAW are higher welding speed, facility of workers, less deformation and better than bead shape & strength of welded joint because there is no visible arc light, welding is spatter-free, fully-mechanized or automatic process, high travel speed, and depth of penetration and chemical composition of the deposited weld metal. However it is difficult to application of thin plate according to high heat input. So this paper has been focused on application of the field according to SAW process for thin plate in ship-structures. For this purpose, It has been decided to optimized welding condition by experiments, relationship between welding parameters and bead shapes, mechanical test such as tensile and bending. Also finite element(FE) based numerical comparison of thermal history and welding residual stress in A-grade 3.2 thickness steel of SAW been made in this study. From the result of this study, It makes substantial saving of time and manufacturing cost and raises the quality of product.

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Influence of Transgenic Corn on the In vitro Rumen Microbial Fermentation

  • Sung, Ha Guyn;Min, Dong Myung;Kim, Dong Kyun;Li, De Yun;Kim, Hyun Jin;Upadhaya, Santi Devi;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.12
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    • pp.1761-1768
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    • 2006
  • In this study, the comparative effects of transgenic corn (Mon 810 and Event 176) and isogenic corn (DK729) were investigated for their influence on in vitro rumen fermentation. This study consisted of three treatments with 0.25 g rice straw, 0.25 g of corn (Mon810/Event176/DK 729) mixed with 30 ml rumen fluid-basal medium in a serum bottle. They were prepared in oxygen free conditions and incubated at $39^{\circ}C$ in a shaking incubator. The influence of transgenic corn on the number of bacterial population, F. succinogenes (cellulolytic) and S. bovis (amylolytic), was quantified using RT-PCR. Fermentative parameters were measured at 0, 2, 4, 8, 12 and 24 h and substrate digestibility was measured at 12 and 24 h. No significant differences were observed in digestibility of dry matter, NDF, ADF at 12 and 24 h for both transgenic and isogenic form of corns (p>0.05) as well as in fermentative parameters. Fluid pH remained unaffected by hybrid trait and decreased with VFA accumulation as incubation time progressed. No influence of corn trait itself was seen on concentration of total VFA, acetic, propionic, butyric and valeric acids. There were no significant differences (p<0.05) in total gas production, composition of gas (methane and hydrogen) at all times of sampling, as well as in NH3-N production. Bacterial quantification using RT-PCR showed that the population number was not affected by transgenic corn. From this study it is concluded that transgenic corn (Mon810 and Event 176) had no adverse effects on rumen fermentation and digestibility compared to isogenic corn. However, regular monitoring of these transgenic feeds is needed by present day researchers to enable consumers with the option to select their preferred food source for animal or human consumption.

Experimental and CFD Study on the Exhaust Efficiency of a Smoke Control Fan in Blind Entry Development Sites (맹갱도 굴진 작업공간내 방재팬의 화재연 배기효율에 관한 현장실험 및 CFD 연구)

  • Nguyen, Vanduc;Kim, Dooyoung;Hur, Wonho;Lee, Changwoo
    • Tunnel and Underground Space
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    • v.28 no.1
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    • pp.38-58
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    • 2018
  • The ventilation system plays a crucial role in underground mine safety. The main objective of the ventilation system is to supply sufficient air to dilute the contaminated air at working places and consequently provide tenable environment during the normal operation, while it also should be capable of controlling the fire propagation and facilitate rescue conditions in case of fire in mines. In this study, a smoke control fan was developed for the auxiliary ventilation as well as the fire smoke exhaust. It works as a free-standing auxiliary fan without tubing to dilute or exhaust the contaminated air from the working places. At the same time, it can be employed to extract the fire smoke. This paper aims to examine the smoke control efficiency of the fan when combined with the current ventilation system in mines. A series of the site experiments and numerical simulations were made to evaluate the fan performance in blind entry development sites. The tracer gas method with SF6 was applied to investigate the contaminant behavior at the study sites. The results of the site study at a large-opening limestone mine were compared with the CFD analysis results with respect to the airflow pattern and the gas concentration. This study shows that in blind development entry, the most polluted and risky place, the smoke fan can exhaust toxic gases or fire smoke effectively if it is properly combined with an additional common auxiliary fan. The venturi effect for smoke exhaust from the blind entry was also observed by the numerical analysis. The overall smoke control efficiency was found to be dependent on the fan location and operating method.