• Title/Summary/Keyword: free gas

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Estimation of Synthesis Gas Composition by Biomass Fuel Conditions using Thermodynamic Equilibrium Model (열역학적 평형모델을 이용한 바이오매스 연료조건에 따른 합성가스 조성의 예측)

  • Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.1
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    • pp.79-87
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    • 2015
  • A thermochemical equilibrium model was constructed for predicting composition of synthesis gas in biomass gasification. The model included estimation of equilibrium constants using Gibbs free energy. After constructing the model, the results were compared with the experimental values and predictions from a previous model. Gas compositions were reasonably well agreed with them and showed effects of operational and fuel condition. When the reaction temperature increased, the lower heating values decreased due to the decrease in CH4 concentrations. The methane concentrations were lower than those observed in experimental results. The model was used to predict the gas composition and heating values for the cases of mixed fuel of charcoal and un-dry woodchips. Although downdraft gasifiers require fuels less than 15% of moisture contents, the model results indicated that the mixed fuel with charcoal and woodchips which had over 25% of moisture contents could be used in the downdraft gasifiers. It might be explained by increase in energy density resulting from mixing charcoal. The results imply that the efforts and costs for drying biomass fuels could be reduced by mixing charcoal or fuels with higher calorific values.

AC Breakdown Analysis by Epoxy Thickness in Composite-Insulation (복합절연물내의 에폭시 두께에 따른 AC 절연파괴 분석)

  • Jung, Hae-Eun;Yun, Jae-Hun;Kim, Byoung-Chul;Kang, Seong-Hwa;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.468-469
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    • 2007
  • $SF_6$ gas used widely as insulating component in electric power industry has excellent in insulation and arc extinguishing performance in gas-insulated switchgear. However, the concern about eco-friendly alternative gas is currently rising, because $SF_6$ gas is one of the main greenhouse gases. As one of the study for $SF_6$ free technology, composite-insulation technology is focused in this paper. To analyze the influence by epoxy thickness change, the composite-insulation composed of dry-air and epoxy was used in this paper. To analyze AC breakdown by the epoxy thickness, needle-plane electrode was used and needle was molded by epoxy. Under the gas pressure ranged from 0.1 to 0.6MPa, the breakdown voltage of dry-air were measured in AC electric field. The data of composite-insulation were acquired by changing the thickness of epoxy used in each composite-insulation under the same condition.

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FREE SURFACE FLOW ANALYSIS BY SOROBAN GRID BASED CIP MEHTOD (Soroban grid 기반 CIP법을 이용한 자유표면 유동해석)

  • Im, H.N.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.326-334
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    • 2010
  • In this study, we provide a comprehensive review of the CIP(Constrained Interpolation Pro file/Cubic Interpolated Propagation) method with a pressure-based algorithm that is known as a general numerical solver for soled liquid, gas and plasmas. And also we introduce a body-fitted grid system(Soroban grid) for computation of strongly nonlinear marine hydrodynamic problems such as slamming water on deck, wave impact by green water. This grid system can keep the third-order accuracy in time and space with the help of the CIP method. The grid system consists of the straight lines and grid points. In the 2-dimensional grid case, each grid points moving in these lines like abacus - Soroban in Japanese. The length of each line can be different and the number of grid points in each line can be different. Mesh generation and searching of upstream departure point are very simple and possible to mesh-free treatment. To optimize computation of free-surface and multi-fluid flows, We adopt the C-CUP method. In most of the earlier computations, the C-CUP method was used with a staggered-grid approach. Here, because of the mesh free nature of the Soroban grid, we use the C-CUP method with a collocated-grid approach.

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A Study on the Properties of Platinum Dry Etching using the MICP (MICP를 이용한 Platinum 건식 식각 특성에 관한 연구)

  • Kim, Jin-Sung;Kim, Jung-Hun;Kim, Youn-Taeg;Joo, Jung-Hoon;Whang, Ki-Woong
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.279-281
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    • 1997
  • The properties of Platinum dry etching were investigated in MICP(Magnetized Inductively Coupled Plasma). The problem with Platinum etching is the redeposition of sputtered Platinum on the sidewall. Because of the redeposits on the sidewall, the etching of patterned Platinum structure produce feature sizes that exceed the original dimension of the PR size and the etch profile has needle-like shape.[1] Generally, $Cl_2$ plasma is used for the fence-free etching.[1][2][3] The main object of this study was to investigate a new process technology for the fence-free Pt etching. Platinum was etched with Ar plasma at the cryogenic temperature and with Ar/$SF_6$ plasma at room temperature. In cryogenic etching, the height of fence was reduced to 20% at $-190^{\circ}C$ compared with that of room temp., but the etch profile was not fence-free. In Ar/$SF_6$ Plasma, chemical reaction took part in etching process. The trend of properties of Ar/$SF_6$ Plasma etching is similar to that of $Cl_2$ Plasma etching. Fence-free etching was possible, but PR selectivity was very low. A new gas chemistry for fence-free Platinum etching was proposed in this study.

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Development of a Bottle-Free Multipurpose Incubator for Generating Various Bacterial Culture Conditions

  • Yang, Nam-Woong;Lim, Yong
    • Journal of Microbiology
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    • v.43 no.1
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    • pp.28-33
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    • 2005
  • The purpose of this study was to develop a multipurpose incubator, without the gas cylinders (bottles) which are required for $H_2$ and $CO_2$ supplementation. In our bottle-free multipurpose incubator, the $H_2$ and $CO_2$ were generated by chemical reactions induced within the chamber. The reaction between sodium borohydride and acetic acid at a molar ratio of 1:1 was used to generate $H_2$, according to the following formula: $4NaBH_4+2CH_3COOH+7H_2O{\rightarrow} 2CH_3COONa+Na_2B_4O_7+16H_2$, whereas the other reaction, citric acid and sodium bicarbonate at a 1:1 molar ratio, was used to generate $CO_2$, according to the following formula: $C_6H_8O_7+3NaHCO_3{\rightarrow}Na_3(C_6H_5O_7)+3H_2O+3CO_2$. Five species of obligate anaerobic bacteria, one strain of capnophilic bacterium, and one strain of microaerophilic bacterium were successfully cultured in the presence of their respective suitable conditions, all of which were successfully generated by our bottle-free multipurpose incubator. We conclude that, due to its greater safety, versatility, and significantly lower operating costs, this bottle-free multipurpose incubator can be used for the production of fastidious bacterial cultures, and constitutes a favorable step above existing anaerobic incubators.

Seismic Properties Study of Gas Hydrate in Deep Sea using Numerical Modeling Technique (수치 모델링 기술을 이용한 심해 가스 하이드레이트의 탄성파 특성 연구)

  • Shin, Sung-Ryul;Yeo, Eun-Min;Kim, Chan-Su;Park, Keun-Pil;Lee, Ho-Young;Kim, Young-Jun
    • Geophysics and Geophysical Exploration
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    • v.9 no.2
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    • pp.139-147
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    • 2006
  • We had conducted a numerical modeling to investigate seismic properties of gas hydrate with field parameters acquired over the East sea in 1998. We used a 2-D staggered grid finite difference method to generate synthetic elastic seismograms for multi-channel seismic survey, OBC (Ocean Bottom Cable) survey and VCS (Vertical Cable Seismic) survey. The results of this study showed that the method using staggered grid yielded stable results and could be used to seismic imaging. We could find out the high amplitude anomaly and the phase reversal phenomenon of reflection wave at interface between the gas hydrate layer and free gas layer such a BSR (Bottom Simulating Reflector) which is the evidence for existence of gas hydrate in seismic reflection data. And we computed the reflection coefficients at the incident angles corresponding to offset distance with the synthetic seismograms. The reflection coefficients acquired from the numerical modeling were nearly consistent with the reflection coefficient computed by Shuey's equation.

A Generator of Gaseous Singlet Oxygen

  • Matsuura, Teruo;Sato, Hideya;Suzuki, Nobutaka;Matsumoto, Masakatsu
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.409-411
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    • 2002
  • In order to prevent side reactions due to free radical formation occurring in the reactions of singlet oxygen generated in solution phse, it was required that singlet oxygen is generated in gas phase from an apparatus of a solid-gas system. We have accomplished to construct an apparatus generating singlet oxygen in solid-gas system, which is composed of a flexible optical fibre tube connected by a dye-sensitizer probe containing rose bengal dye on polymer or inorganic material. Through the optical fibre tube visible light from a laser and an oxygen stream are passed into the sensitizer probe where singlet oxygen is generated. The determination of singlet oxygen was carried out by two methods. One involves the detection of the luminescence of singlet oxygen at 1268 mn and the other involves the chemiluminescence reaction of a dihydroisobenzofuran with singlet oxygen emitting luminescence at 456 nm.

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Shock Waves in He II induced by a Gas Dynamic Shock Wave Impingement (기체역학적 충격파의 입사에 의해 유도된 초유동헬륨중의 충격파)

  • ;H. Nagai;Y. Ueta;K. Yanaka;M. Murakami
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.23-26
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    • 2002
  • Two modes of shock waves propagating in He II (superfluid helium), this is a compression and a thermal shock waves, were studied experimentally by using superconductive temperature sensors, piezo pressure transducers and Schlieren visualization method with an ultra-high-speed video camera (40,500 pictures/sec). The shock waves are induced by a gas dynamic shock wave impingement upon a He II free surface. It is found that the shock Mach number of a transmitted compression shock wave is up to 1.16, and the shock Mach number of a thermal shock wave coincides well with the second sound velocity under each compressed He II state condition. The temperature rise ratio of an induced thermal shock wave to that of an incident gas dynamic shock wave was found to be very small, as small as 0.003 at 1.80K.

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Development of Ceramic Composite Membranes for Gas Separation: III. Examination of Membrane Characteristics by the Gas Permeation Model (기체분리용 세라믹 복합분리막의 개발: III. 기체투과 모델에 의한 막의 특성 규명)

  • 현상훈;윤성필;강범석
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.905-911
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    • 1992
  • Model equations for the gas permeation through a ceramic composite membrane were derived for examining the existence of crack, the reproducibility, and the microstructural properties of composite membranes. From the results of analyzing the nitrogen permeability data through alumina-tube supported TiO2 and SiO2 composite membranes, the extent of cracking, and the formation and structure of membrane top-layers were modelled. It was proved that the crack-free and reproducible composite membranes could be easily prepared only by the pore-filled coating within pores of the support in the sol-gel coating process.

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Vibrational Characteristics of the Gas Pipelines Conveying Flow (유체가 흐르는 가스파이프의 진동 특성)

  • Kim, Kyung-Tae;Lee, Sung-Soo;Lee, Seong-Woo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.2
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    • pp.337-343
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    • 2012
  • This work investigates the vibrational characteristics of the underground gas pipelines. Experiments were conducted to analyze the effects of various parameters on the vibrational characteristics from the emergency detection point of view. Influences of the various types of impact exerted on the pipe, height of free fall and measuring locations were analyzed. Especially, the difference between the vibrational signal generated by the direct impact on the pipe and the ambient noise was successfully identified. To validate the experimental observation, computer simulation was also performed with constant properties(elasticity, fluid velocity and internal pressure) which are directly conjectured from the accompanying experiment with a real pipe system.