• Title/Summary/Keyword: free carbon

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Heat transfer enhancement of metal hydride $(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$ for hydrogen storage (수소저장용 금속수소화물$(Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2})$의 전열촉진)

  • Bae Sang-Chul;Yang Yang;Masanori Monde
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.75-80
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    • 2006
  • The effective thermal conductivities of $Mm(La_{0.6-0.8})Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ [TL-492] with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in low pressure range [below 0.5 MPa]. And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99 wt% of carbon fiber. This is a good result comparing to other method which can reach higher effective thermal conductivity but needs much higher mass fraction of additives too.

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Hydrogen production by catalytic decomposition of methane and propane mixture over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄과 프로판 혼합물의 촉매 분해에 의한 수소생산 연구)

  • Lee, Seung-Chul;Yoon, Yong-Hee;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.57-60
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    • 2007
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_{2}$ - free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by SEM image.

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Method and mechanism of dispersing agent free dispersion of short carbon fibers in silicon carbide powder

  • Raunija, Thakur Sudesh Kumar;Mathew, Mariamma;Sharma, Sharad Chandra
    • Carbon letters
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    • v.15 no.3
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    • pp.180-186
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    • 2014
  • This study highlights a novel method and mechanism for the rapid and effective milling of carbon fibers (CFs) in silicon carbide (SiC) powder, and also the dispersion of CFs in SiC powder. The composite powders were prepared by chopping and exfoliation of CFs, and ball milling of CFs and SiC powder in isopropyl alcohol. A wide range of CFs loading, from 10 to 50 vol%, was studied. The milling of CFs and SiC powder was checked by measuring the average particle size of the composite powders. The dispersivity of CFs in SiC powder was checked through scanning electron microscope. The results show that the usage of exfoliated CF tows resulted in a rapid and effective milling of CFs and SiC powder. The results further show an excellent dispersion of CFs in SiC powder for all CFs loading without any dispersing agent.

Excellent field emission properties from carbon nanotube field emitters fabricated using a filtration-taping method

  • Shin, Dong Hoon;Jung, Seung;Yun, Ki Nam;Chen, Guohai;Jeon, Seok-Gy;Kim, Jung-Il;Lee, Cheol Jin
    • Carbon letters
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    • v.15 no.3
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    • pp.214-217
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    • 2014
  • A filtration-taping method was demonstrated to fabricate carbon nanotube (CNT) emitters. This method shows many good features, including high mechanical adhesion, good electrical contact, low temperature, organic-free, low cost, large size, and suitability for various CNT materials and substrates. These good features promise an advanced field emission performance with a turn-on field of $0.88V/{\mu}m$ at a current density of $0.1{\mu}A/cm^2$, a threshold field of $1.98V/{\mu}m$ at a current density of $1mA/cm^2$, and a good stability of over 20 h. The filtration-taping technique is an effective way to realize low-cost, large-size, and high-performance CNT emitters.

Hydrogen production by catalytic decomposition of methane and propane mixture over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄과 프로판 혼합물의 촉매 분해에 의한 수소생산 연구)

  • Lee, Seung-Chul;Yoon, Yong-Hee;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.97-100
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    • 2007
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2$ - free hydrogen . The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by TEM image.

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Effect of Free Radical Scavenging from Green Tea Extraction using Carbon Dioxide Fluid (이산화탄소 유체를 이용한 녹차의 용매 추출물의 래디칼 소거 기능)

  • Kang Ok-Ju
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.936-941
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    • 2005
  • Green tea was extracted with different solvents such as hot water, varying concentrations of ethanol and carbon dioxide fluid. The carbon dioxide fluid extraction of green tea was a very effective extraction method in terms of antioxidant yield and stability. At pressure of 125kgf, antioxidant extract of green tea produced a yield 1.87 and 2.8 times higher than hot water and $95\%$ ethanol extract, respectively. Antioxidant extract of carbon dioxide fluid was also very stable during 7-day storage at 35?.

Vibration characteristics of functionally graded carbon nanotube-reinforced composite double-beams in thermal environments

  • Zhao, Jing-Lei;Chen, Xu;She, Gui-Lin;Jing, Yan;Bai, Ru-Qing;Yi, Jin;Pu, Hua-Yan;Luo, Jun
    • Steel and Composite Structures
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    • v.43 no.6
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    • pp.797-808
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    • 2022
  • This paper presents an investigation on the free vibration characteristics of functionally graded nanocomposite double-beams reinforced by single-walled carbon nanotubes (SWCNTs). The double-beams coupled by an interlayer spring, resting on the elastic foundation with a linear layer and shear layer, and is simply supported in thermal environments. The SWCNTs gradient distributed in the thickness direction of the beam forms different reinforcement patterns. The materials properties of the functionally graded carbon nanotube-reinforced composites (FG-CNTRC) are estimated by rule of mixture. The first order shear deformation theory and Euler-Lagrange variational principle are employed to derive the motion equations incorporating the thermal effects. The vibration characteristics under several patterns of reinforcement are presented and discussed. We conducted a series of studies aimed at revealing the effects of the spring stiffness, environment temperature, thickness ratios and carbon nanotube volume fraction on the nature frequency.

Vibration response of rotating carbon nanotube reinforced composites in thermal environment

  • Ozge Ozdemir;Ismail Esen;Huseyin Ural
    • Steel and Composite Structures
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    • v.47 no.1
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    • pp.1-17
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    • 2023
  • This paper deals with the free vibration behavior of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. The temperature-dependent beam material is assumed to be a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix and five different functionally graded (FG) distributions of CNTs are considered according to the variation along the thickness, namely the UD-uniform, FG-O, FG-V, FG-Λ and FG-X distributions where FG-V and FG-Λ are unsymmetrical patterns. Considering the Timoshenko beam theory (TBT), a new finite element formulation of functionally graded carbon nanotube reinforced composite (FGCNTRC) beam is created for the first time. And the effects of several essential parameters including rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force and moments due to temperature variation are considered in the formulation. By implementing different boundary conditions, some new results of both symmetric and non-symmetrical distribution patterns are presented in tables and figures to be used as benchmark for further validation. In addition, as an alternative advanced composite application for rotating systems exposed to thermal load, the positive effects of CNT addition in improving the dynamic performance of the system have been observed and the results are presented in several tables and figures.

Development of fluorination methodology for carbon-fluorine bond formation: nucleophilic fluorinating reagents in the mid-2000s

  • Bae, Dae Young;Lee, Eunsung
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.3 no.2
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    • pp.129-133
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    • 2017
  • Since carbon-fluorine (C-F) bonds play a key role to improve bioavailability and lipophilicity, they have found commonly in pharmaceuticals, radiopharmaceuticals, agrochemicals, and material science. Advances on the efficient method to introduce fluorine to complex organic molecules are mainly results of development of fluorination reagents and transition metal catalysts. In this mini-review, we want to emphasize two representative nucleophilic fluorinating reagents regarding carbon-fluorine bond formation, which were developed in the mid-2000s.

Chromate Removal from Wastewater using Micellar Enhanced Ultrafiltration and Activated Carbon Fibre Processes; Validation of Experiment with Mathematical Equations

  • Bade, Rabindra;Lee, Seung-Hwan
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.98-104
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    • 2008
  • In this study, chromate and cetylperidinium chloride (CPC) removal from artificial wastewater was monitored by using micellar enhanced ultrafiltration (MEUF) and activated carbon fibre (ACF) adsorption hybrid processes. For the efficient chromate removal, molar concentration of the CPC should be five times that of chromate and it should be at least one critical micelle concentration (CMC). The MEUF was found to be effective in the chromate removal while ACF in the CPC adsorption to produce chromate and CPC free effluents. The chromate and CPC removal was 99.8% from MEUF-ACF process. Effluent chromate concentration was exponentially correlated with molar ratio of CPC to chromate and pH.