• Title/Summary/Keyword: free CaO

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Effect of Methoxyverapamil on Renal Function of Dogs (개의 신장기능에 미치는 메톡시베라파밀의 영향)

  • Ko, Suk-Tai;Lee, Han-Goo;Na, Han-Kwang
    • YAKHAK HOEJI
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    • v.36 no.1
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    • pp.46-55
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    • 1992
  • Methoxyverapamil, $Ca^{2+}$ channel blocker, when given intravenously by means of bolus, produced the transient increase of urine flow, and then methoxyverapamil was infused in this experiments. Methoxyverapamil, when infused into vein, elicited the increase of urine flow ancampanied with the increased glomeralar filtration rate(GFR), renal plasma flow(RPF), excretion amounts of sodium and potassium in urine($E_{Na},\;E_k$) and osmolar clearance(Cosm), wherease produced the no change of free water clearance($C_{H2O}$) and the reduction of reabsorption rates of sodium and potassium in reral tubules($R_{Na},\;R_k$). Methoxyverapamil, when infused into a renal artery, exhibited the diuretic action in only infused Kidney, at this time changes of renal function were the same aspect to that of intravenously infused methoxyverapamil. Methoxyverapamil, when infused into a carotid artery, exhibited the decreased urine flow along with the reduction of Cosm, $C_{H2O}\;and\;E_{Na}$. Above results suggest that methoxyverapamil possess both the diuretic action by direct action in kidney and antidiuretic action through the central function.

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CO Selox Reaction Using Y-type Zeolite Catalytic Membranes

  • Bemardo, P.;Algieri, C.;Barbieri, G.;Drioli, E.
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.13-20
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    • 2006
  • The production of CO-free hydrogen streams for feeding PEM-Fuel Cells using catalytic zeolite membrane reactors was analysed by means of selective oxidation. Tubular FAU (Na-Y) zeolite membranes, prepared by a secondary growth method and Pt-loaded, were used in a flow-through MR configuration. The catalytic tests were carried out at $200^{\circ}C$ and at different pressures with a simulated dry reformate shifted gas mixture ($H_2$ ca. 60%, CO 1 %, plus $O_2,\;N_2,\;CO_2$). The operative $O_2/CO$ stoichiometric equivalent feed ratio was ${\lambda}= 2$. These catalytic tests, reducing the CO concentration down to $10{\sim}50$ ppm, verified the possibility of MR integration after using a low temperature water-gas shift unit of a fuel processor to convert hydrocarbons into hydrogen-rich gas.

Grain Growth Behavior of (K0.5Na0.5)NbO3 Ceramics Doped with Alkaline Earth Metal Ions

  • Il-Ryeol Yoo;Seong-Hui Choi;Kyung-Hoon Cho
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.135-141
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    • 2023
  • The volatilization of alkali ions in (K,Na)NbO3 (KNN) ceramics was inhibited by doping them with alkaline earth metal ions. In addition, the grain growth behavior changed significantly as the sintering duration (ts) increased. At 1,100 ℃, the volatilization of alkali ions in KNN ceramics was more suppressed when doped with alkaline earth metal ions with smaller ionic size. A Ca2+-doped KNN specimen with the least alkali ion volatilization exhibited a microstructure in which grain growth was completely suppressed, even under long-term sintering for ts = 30 h. The grain growth in Sr2+-doped and Ba2+-doped KNN specimens was suppressed until ts = 10 h. However, at ts = 30 h, a heterogeneous microstructure with abnormal grains and small-sized matrix grains was observed. The size and number of abnormal grains and size distribution of matrix grains were considerably different between the Sr2+-doped and Ba2+-doped specimens. This microstructural diversity in KNN ceramics could be explained in terms of the crystal growth driving force required for two-dimensional nucleation, which was directly related to the number of vacancies in the material.

Experimental Study on Behavior of Confined Concrete with Electric Arc Furnace Oxidizing Slag Aggregates (전기로 산화 슬래그 골재를 사용한 콘크리트의 횡 구속 거동에 관한 실험적 연구)

  • Kim, Sang-Woo;Lee, Jung-Mi;Lee, Yong-Jun;Jung, You-Jin;Kim, Kil-Hee
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.195-201
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    • 2011
  • This paper estimates the structural performance of spirally confined concrete having electric arc furnace (EAF) oxidizing slag aggregates. The EAF oxidizing slag is a by-product generated from iron and steel industry. The EAF oxidizing slag have been largely put to low-value-added uses due to its expansive properties of the free-CaO and free-MgO. Recently, this problem has been solved by the advances in steelmaking technology and thereby stabilizing EAF oxidizing slag aggregate. To verify the application of the EAF oxidizing slag aggregate to the structural concrete usage, a total of 27 cylindrical specimens with a diameter of 150 mm and a height of 300 mm were cast and tested. The test parameters were aggregate type and spiral reinforcement yield strength. Experimental results showed that the structural performance of specimens with EAF oxidizing slag aggregates was equivalent to that of confined concrete with natural aggregates.

Characterization of an O-Methyltransferase from Streptomyces avermitilis MA-4680

  • Yoon, Young-Dae;Park, Young-Hee;Yi, Yong-Sub;Lee, Young-Shim;Jo, Geun-Hyeong;Park, Jun-Cheol;Ahn, Joong-Hoon;Lim, Yoong-Ho
    • Journal of Microbiology and Biotechnology
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    • v.20 no.9
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    • pp.1359-1366
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    • 2010
  • A search of the Streptomyces avermitilis genome reveals that its closest homologs are several O-methyltransferases. Among them, one gene (viz., saomt5) was cloned into the pET-15b expression vector by polymerase chain reaction using sequence-specific oligonucleotide primers. Biochemical characterization with the recombinant protein showed that SaOMT5 was S-adenosyl-L-methionine-dependent Omethyltransferase. Several compounds were tested as substrates of SaOMT5. As a result, SaOMT5 catalyzed O-methylation of flavonoids such as 6,7-dihydroxyflavone, 2',3'-dihydroxyflavone, 3',4'-dihydroxyflavone, quercetin, and 7,8-dihydroxyflavone, and phenolic compounds such as caffeic acid and caffeoyl Co-A. These reaction products were analyzed by TLC, HPLC, LC/MS, and NMR spectroscopy. In addition, SaOMT5 could convert phenolic compounds containing ortho-dihydroxy groups into O-methylated compounds, and 6,7-dihydroxyflavone was known to be the best substrate. SaOMT5 converted 6,7-dihydroxyflavone into 6-hydroxy-7-methoxyflavone and 7-hydroxy-6-methoxyflavone, and caffeic acid into ferulic acid and isoferulic acid, respectively. Moreover, SaOMT5 turned out to be a $Mg^{2+}$-dependent OMT, and the effect of $Mg^{2+}$ ion on its activity was five times greater than those of $Ca^{2+}$, $Fe^{2+}$, and $Cu^{2+}$ ions, EDTA, and metal-free medium.

Studies on Pollution Characteristics and Sources of Precipitation in Jeiu Island

  • Kang, Chang-Hee;Kim, Won-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E4
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    • pp.191-201
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    • 2002
  • The pH, electric conductivity. and the major ionic components were analyzed for the precipitation samples collected at 1100 Site of Mt. Halla and Jeju city. The quality of analytical data was verified by the comparison of ion balances, conductivities and acid fractions, all of which correlation coefficients were over 0.952. The ionic strengths lower than 10$^{-4}$ M were found in 57 and 28% at 1100 Site and Jeju city respectively. The precipitation in Jeju city was influenced more by the oceanic effect than those in 1100 Site. The acidification of precipitation was caused mostly by S $O_4$$^{2-}$and N $O_3$$^{[-10]}$ in both areas, and the organic acids have contributed to the acidity with only 7~8%. The neutralization factors by N $H_3$ were about 44 and 47% at the 1100 site and the Jeju city, respectively, whereas those by CaC $O_3$were 21 and 24%, and the free acidity were about 38 and 28% at two sites. From the investigation of seawater and soil enrichment factors, the S $O_4$$^{2-}$, N $O_3$$^{[-10]}$ and N $E_4$$^{+}$ were immigrated by other sources rather than from the seawater or soil origins. but not in the case of $Mg^{2+}$, C $l^{[-10]}$ , N $a^{+}$, and $K^{+}$. Factor analysis has shown that the precipitation at the 1100 site had been influenced mostly by anthropogenic sources, followed by soil and sea-water sources. On the other hand, the precipitation at the Jeju city was mainly influenced by oceanic sources, followed by anthropogenic and soil sources.urces.

Application on the CFBC Fly Ash as a Stimulant to Improve the Early Strength of Hydration Portland Cement (슬래그시멘트 초기강도 증진을 위한 자극제로서 CFBC Fly ash의 활용연구)

  • Park, JongTak;Oh, Hongseob;Jung, Gwon Soo;Kang, Chang Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.8-16
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    • 2020
  • As the circulating fluidized bed combustor(CFBC) boilers system to generate electric power increase in order to reduce environmental pollution, a lot of CFBC fly ashes(CFFA) are produced. CFFA has limited use in concrete because it contains free CaO, which can cause cement expansion and rapid initial hydration. In this study, the microstructure and the initial development of compressive strength characteristics were experimentally analyzed to be used as a stimulant to replace natural gypsum by mixing with CFFA and phosphate gypsum to enhance the initial strength of portland blast furnace slag cement. The recycled gypsum was used as flue-gas desulfurization gypsum and phosphate gypsum. Experimental results show that the initial strength development is relatively lower when CFFA and dihydrate gypsum are mixed, but the strength improvement effect of the mixture with CFFA and anhydrous gypsum as an anhydritedII typed crystalized gypsum is similar to that of natural gypsum. As a result, it w as analyzed to have high possibility of use for stimulant of portland blast furnace slag cement.

A Study on PCP Adsorption in Various Paddy Soils of the Choongbook Area (충북지방(忠北地方) 답토양(沓土壤)에 대(對)한 PCP 흡착에 관한 연구(硏究))

  • Ok, Hwan-Suk;Lee, Jae-Koo
    • Applied Biological Chemistry
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    • v.15 no.3
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    • pp.229-240
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    • 1972
  • Not only in order to determine reasonable application amounts of PCP in terms of soil texture, but also to get basic data for fish-toxicity-free treatment by estimating fish toxicity, some aspects of PCP adsorption were observed taking various paddy soils with different physico-chemical characteristics in the Choongbook Area as samples. The results obtained are summarized as follows: 1. There was a positive correlation between PCP adsorption and clay contents, total nitrogen, organic matter, cation exchange capacity, exchangeable bases, and phosphorus absorption coefficients, respectively; whereas there was a negative one between PCP adsorption and pH. Although they were not significant, it was remarkable that there was a relatively large amount of correlation between PCP adsorption and clay contents, $H^+,\;Mg^{++}$, and CEC, respectively. 2. PCP adsorption in terms of soil texture was in the order of Clay>Loam>Sandy loam. 3. Although PCP adsorption in the $H_2O_2-treated$ soils decreased remarkably, it was not proportional to the humus contents. 4. The order of PCP adsorption in the exchangeable base-treated soils was H^+-exchanged soil>$K^+-soil$>$Na^+-soil$>$Ca^{++}-soil$>Mg^{++}-soil. 5. Langmuir's and Freundlich's adsorption isotherms were applicable to the PCP adsorption, and thereby were able to be calculated maximum adsortion amounts of PCP, bond energy, and the depths of adsorption layers. 6. Maximum adsorbed amounts of PCP were 212.14 mg/100gr in Clayey loam, 97.28 to 121.59mg/100gr in Loam, and 32.92 to 91.74mg/100gr in Sandy loam, respectively. 7. The depths of mixed layers of limiting application for fish-toxicity-free treatment were 0.88cm of the Jinchun soil, the shallowest and 4.29 cm of the Naesan-ri Sandy loam, the deepest.

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Engineering Characteristics of Ultra High Strength Concrete with 100 MPa depending on Fine Aggregate Kinds and Mixing Methods (잔골재 종류 및 혼합방법 변화에 따른 100 MPa 급 초고강도 콘크리트의 공학적 특성)

  • Han, Min-Cheol;Lee, Hong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.536-544
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    • 2016
  • Recently, with the increase in the number of high rise and huge scaled buildings, ultra-high strength concrete with 80~100 MPa has been used increasingly to withstand excessive loads. Among the components of concrete, the effects of the kinds and properties of fine aggregates on the performance and economic advantages of ultra-high strength concrete need to be evaluated carefully. Therefore, this study examined the effects of the type of fine aggregates and mixing methods on the engineering properties of ultra-high strength concrete by varying the fine aggregates including limestone fine aggregate (LFA), electrical arc slag fine aggregate (EFA), washed sea sand (SFA), and granite fine aggregate (GFA) and their mixtures. Ultra-high strength concrete was fabricated with a 20 % water to binder ratio (W/B) and incorporated with 70 % of Ordinary Portland cement: 20 % of fly ash:10 % silica fume. The test results indicate that for a given superplasticizer dose, the use of LFA resulted in increases in slump flow and L-flow compared to the mixtures using other aggregates due to the improved particle shape and grading of LFA. In addition, the use of LFA and EFA led to enhanced compressive strength and a decrease in autogenous shrinkage due to the improved elastic properties of LFA and the presence of free-CaO in EFA, which resulted in the formation of C-S-H.

Study on Stable Use of Stainless EAF Oxidizing Slag as Fine Aggregate of Concrete (스테인리스 전기로 산화슬래그의 콘크리트용 잔골재 활용방안 검토)

  • Cho, Bong-Suk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.133-142
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    • 2014
  • Recently, more focus is shift to imbalances in aggregate market supply and demand and an exhaustion of natural resources. In this situation, Electric arc furnace oxidizing slag (EAF Slag) has high application possibility as aggregate for concrete due to similar property with general aggregate. In this study, We've got the plan to assure the chemical stability of EAF Slag, and then experimentally tested the mechanical performance and durability for the fine aggregate used EAF Slag. On this test result, we suggest the application plan. At the result of this study, it shows that EAF slag would reduce the surface defect such as pop-out due to natural aging for the fixed hour and adjustment the grain size of EAF Slag. And mechanical performance and durability according to the replacement rate of concrete service, were revealed more than equal or equal compare to general aggregate. Hereafter, quality control must precede not to impede the beauty of concrete surface as assure the safety for aging and processing. And, to establish the environmental resource recycling system for by-products of steel, it should be made development of various application and guideline of quality control for the EAF slag aggregate. Moreover, it must be constantly studied all kind of engineering performance and durability for related to this study.