• Title/Summary/Keyword: free CaO

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Determination of X-ray and gamma-ray shielding capabilities of recycled glass derived from deteriorated silica gel

  • P. Sopapan;O. Jaiboon;R. Laopaiboon;C. Yenchai;C. Sriwunkum;S. Issarapanacheewin;T. Akharawutchayanon;K. Yubonmhat
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3441-3449
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    • 2023
  • We determined the radiation shielding properties for 10CaO-xPbO-(90-x) deteriorated silica gel (DSG) glass system (x = 20, 25, 30, 35, 40, and 45 mol.%). The mass attenuation coefficient (MAC) has been estimated at photon energies of 74.23, 97.12, 122, 662, 1173, and 1332 keV using a narrow beam X-ray attenuation and transmission experiment, the XCOM program, and a PHITS simulation. The obtained MAC values were applied to estimate the half value layer (HVL), mean free path (MFP), effective atomic number, and effective electron density. Results show that the MAC value of the studied glasses ranges between 0.0549 and 1.4415 cm2/g, increases with the amount of PbO, and decreases with increasing photon energy. The HVL and MFP values decrease with increasing PbO content and increase with increasing photon energy. The recycled glass, with the addition of PbO content (20-45 mol.%), exhibited excellent radiation shielding capabilities compared to standard barite and ferrite concretes and some glass systems. Moreover, the experimental radiation shielding parameters agree with the XCOM and PHITS values. This study suggests that this new waste-recycled glass is an effective and cost-saving candidate for X-ray and gamma-ray shielding applications.

Surgical Experience of Idiopathic Hypertrophic Subaortic Stenosis - Report of A case - (특발성 비후성 대동맥판하 협착증의 수술적 치험 1례 보)

  • 강경훈
    • Journal of Chest Surgery
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    • v.20 no.3
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    • pp.610-618
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    • 1987
  • A 23-y-o male patient was suffered from intermittent fainting and dyspnea on exertion [NYHA Class IIIIV]. 2-D - Echocardiogram and cardiac catheterization with cineangiogram showed typical IHSS findings those were asymmetrical septal hypertrophy [ASH], systolic anterior motion of anterior mitral leaflet [SAM] which induced mild mitral regurgitation [Seller Grade I/IV] and pressure gradient about 60 mmHg between left ventricle and the aorta. Medical treatment with 8-adrenergic blockade [propranolol] and Ca" channel antagonist [Verapamil] had no response. So, we performed trans-aortic ventricular septal myotomy and mymectomy. Resected rectangular muscle bar was 1 Cm x 1 Cm x 4.5 Cm. Post-operative pressure gradient between the left ventricle and the aorta was less than 10 mmHg and SAM. was disappeared with decreased mitral regurgitation grade. Post-operative course was smooth and his symptoms and signs were free without any medication during 12 months follow-up.w-up.

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Properties of the Expansion in Concrete with Electric Arc Furnace Slag Aggregate after Aging (에이징 처리 전기로슬래그골재를 활용한 콘크리트의 팽창특성)

  • 문한영;유정훈;백우열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.613-618
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    • 2002
  • Steel slag produced in steel making process is divided with electric arc furnace slag and converter slag. Compared with the blast furnace slag, converter slag has the expansibility due to the reaction with water and free CaO. Therefore it is specified in Standard Specification for Concrete in Korea that steel slag aggregate must not be used in concrete. In this study, we treat electric arc furnace slag aggregate(EAFSA) for concrete before and after several aging process to reduce expansibility. The fundamental properties are measured, which are specific gravity, unit weight, abrasion value and immersion expansion ratio, as concrete aggregate. To understand the suitability of EAFSA for concrete, we made the concrete with EAFSA and then determined the strength and the volume change in EAFSA concrete. From the results EAFSA treated with steam aging process has potentiality for concrete aggregate.

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The Segregation of Concrete Containing Atomized Steel Slag Fine Aggregate (개질처리 제강슬래그를 혼합한 굳지않은 콘크리트의 재료분리)

  • Moon, Han-Young;Yoo, Jung-Hoon;Jung, Chul-Hei
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.600-603
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    • 2004
  • Recently, the river sands are in short supply. Gathering sea-sand will be faced with difficulty. Alternative aggregates for concrete are estimated by many researchers. The aggregates are blast furnace slag, steel slag, copper slag, ferro-nickel slag and recycled aggregate and etc. Nevertheless steel slag has been limited in practical use due to its expansibility which is occurred reaction with water and free CaO in slag. Most recently stable management method is to minimize the expansibility researched and developed. First of all, slump, air content, compressive strength and flexural strength are measured in concrete. An estimate is made of the segregation of concrete containing atomized steel slag by Image Analyser program.

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Microstructural modelling of the elastic properties of tricalcium silicate pastes at early ages

  • Do, Huy Q.;Bishnoi, Shashank;Scrivener, Karen L.
    • Computers and Concrete
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    • v.16 no.1
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    • pp.125-140
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    • 2015
  • This paper describes the numerical calculation of elastic properties of a simulated microstructure of cement paste from very early age, when most previous models fail to give accurate results. The development of elastic properties of tricalcium silicate pastes was calculated by discretising a numerical resolution-free 3D vector microstructure to a regular cubic mesh. Due to the connections formed in the microstructure as an artefact of the meshing procedure, the simulated elastic moduli were found to be higher than expected. Furthermore, the percolation of the solids was found to occur even before hydration started. A procedure to remove these artefacts, on the basis of the information available in the vector microstructures was developed. After this correction, a better agreement of the experimental results with calculations was obtained between 20% and 40% hydration. However, percolation threshold was found to be delayed significantly. More realistic estimates of percolation threshold were obtained if either flocculation or a densification of calcium silicate hydrate with hydration was assumed.

A Fundamental Property of Concrete Containing Atomized Steel Slag Fine Aggregate after Reforming Process (개질처리한 제강슬래그 잔골재 사용 콘크리트의 성질)

  • 문한영;유정훈;박영훈;김주용;윤표호;김얼
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.318-321
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    • 2003
  • Steel slag is produced during steel making process. Compared with the blast furnace slag, converter slag has the expansibility due to the reaction with water and free CaO. Therefore it is specified in Standard Specification for Concrete in Korea that steel slag aggregate must not be used in concrete. In this study, atomized steel slag aggregate is conducted from converter slag by the atomizing method. Atomized steel slag and conventional converter slag are same in its composite by nature in the converter but compounds of the composite become different because of different method of slag treatment. Especially atomized steel slag aggregate overcomes expansibility that is the weak point for usage. It is researched whether it has the possibility, suitability for fine aggregate in concrete. Slump and air content are measured in fresh concrete, compressive and bending strength in hardened concrete. These is compared with control concrete with washed sand.

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Effect of Aging Process to Use Steel Slag for Concrete Aggregate

  • Moon, Han-Young;Yoo, Jung-Hoon
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.520-525
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    • 2001
  • Compared with the blast furnace slag, steel slag has the expansibility due to the reaction with water and free CaO. Therefore it is specified in Standard Specification for Concrete in Korea that steel slag aggregate must not be used in concrete. So it is unusual to use steel slag aggregate in concrete. In this study steel slag aggregate processed by several aging process was comparatively satisfied with fundamental properties as concrete aggregate, which are specific gravity, absorption, unit weight, percentage of solids and abrasion value etc. And chemical analysis is observed to understand the effect of aging process in steel slag aggregate. When the strength is measured, it is found that the concrete replacing crushed stone with steel slag aggregate had a little problem without sufficient aging process

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Hydration modeling of high calcium fly ash blended concrere (고칼슘 플라이애시 혼입한 콘크리트의 수화반응 모델에 관한 연구)

  • Fan, Wei-Jie;Wang, Xiao-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.48-49
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    • 2015
  • High-calcium fly ash (FH) is widely used as mineral admixtures in concrete industry. In this paper, a hydration model is proposed to describe the hydration of high-calcium fly ash blended-cement. This model takes into account the hydration reaction of cement, the chemical reaction of fly ash, and reaction of free CaO in fly ash. Using the proposed model, the development of compressive strength of FH blended concrete is predicted using the amount of calcium silicate hydrate (CSH). The agreement between simulation and experimental results proves that the new model is quite effective.

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Local Difference of Na-Pump Activity in the Rabbit Sinoatrial Node (토끼 동방결절 부위에 따른 Na-Pump활동도의 차이에 관한 연구)

  • Seo, Jong-Jin;Moon, Hyung-Ro;Earm, Yung-E
    • The Korean Journal of Physiology
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    • v.19 no.2
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    • pp.113-125
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    • 1985
  • Electrophysiological difference of the central and peripheral area of the sinoatrial node in the rabbit was studied by glass microelectrode technique. Effects of $K^+,\;Na^+,\;Cs^+,$ adrenaline and ouabain on the action potential of the two areas were investigated, and transient hyperpolarization ($K^+-induced$ hyperpolarization) which developed following readmission of potassium after having pre-treated with $K^+-free$ Tyrode solution for 10 minutes was analyzed. The results obtained were as follows ; 1) The frequency of the spontaneous action potential recorded in the periphery of the SA node was faster than the central area. Reduction by $Cs^+$ and increase by O mM $K^+$, $10^{-6}M$ adrenaline and $10^{-6}M$ ouabain in the frequency of action potential were noticed more prominently in the peripheral than the central area. On the contrary, the frequency in the central area was more decreased than the Peripheral area by 13 mH $K^+$ and 1 mM $Co^{2+}$. 2) The amplitude of the K+_induced hyperpolarization was very small in the central area but large in the peripheral area. Transient hyperpolarization was abolished by ouabain and low sodium, and decreased by cooling the tissue $(17^{\circ}C)$. 3) By changing the concentration of $Ca^{2+}$ in the perfusate, the amplitude and the rate of transient hyperpolarization were increased in the high $Ca^{2+}$ concentration. It could be concluded that the central area of the SA node is less susceptible to the inhibition of Na-Pump and more susceptible to Ca-blocker and high concentration of $K^+$. The Na-Pump activity of the central area measured by means of transient hyperpolarization is found to be much less active than that of the peripheral area.

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Effect of Verapamil on Renal Function in Dog (Verapamil이 개의 신장기능에 미치는 영향)

  • 고석태;허영근
    • YAKHAK HOEJI
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    • v.35 no.2
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    • pp.85-98
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    • 1991
  • Verapamil, $Ca^{2+}$-channel blocker, when given into vein or into carotid artery, produced the decrease of urine flow accompanied with the decreased amounts of Na$^{+}$ and $K^{+}$ excreted in urine ($E_{Na}, E_{K}$) and with the decreased clearances of free water (C$_{H_2O}$) and osmolar substance (C$_{osm}$), and then increased reabsorption of Na$^{+}$ and $K^{+}$ in renal tubules (R$_{Na}$, R$_{N}$), glomeruler filtration rate (GFR) and renal plasma flow (RPF) were inhibited when verapamil was given into carotid artery, but were only tendency of reduction when given intravenously. Verapamil, when infused into a renal artery, exhibited diuresis accompanied with the increased GER, RPF, E$_{Na}$ and E$_{K}$, with the decreased filtration fraction (FF) in only infused kidney. At the same time, $C_{H_2O}$ was not changed, R$_{Na}$ and R$_{K}$ were reduced. Antidiuretic action by verapamil administered into vein or into carotid artery in normal kidney was reversed to diuretic action in denervated kidney. At this time, parameters of renal function exhibited the opposite phenomena compared to that elicited by verapamil in normal kidney, wherease renal denervation did not influence the action of verapamil infused into a renal artery. Above results suggest that verapamil produce both antidiuresis through nervous system centrally, not endogenous substances and diuresis by direct action in the kidney. Diurectic action are caused by hemodynamic improvement through dilatioon of vas efferense and by greatly inhibited reabsorption of electrolytes in distal tubules.

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