• Title/Summary/Keyword: free CaO

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Piezoelectric Properties of Lead-free $Ba(Ti_{0.8}Zr_{0.2})O_3-(Ba_{0.7}Ca_{0.3})TiO_3$ Ceramics for Haptic piezoelectric Actuator (햅틱 압전 액츄에이터용 $Ba(Ti_{0.8}Zr_{0.2})O_3-(Ba_{0.7}Ca_{0.3})TiO_3$ 무면 세라믹스의 압전특성)

  • Park, Min-Ho;Lee, Kab-Soo;Yoo, Ju-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.304-304
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    • 2010
  • 최근 생활에 편리하며 휴대하기 좋은 전자기기들이 개발되고 있다. 휴대폰이나 MP3와 같은 전자기기들은 거의 필수품이라고 할 정도로 우리의 일상생활에 근접하여 있다. 그 종 대표적으로 휴대폰의 종류로 스마트폰과 같은 터치스크린을 이용한 사례는 점차 상승하고 있으며 시간이 지날수록 그 수요는 더욱 많아지고 있다. 때문에 몰입감 제공을 위하여 햅틱장치의 채용이 일반화 되고 있다. 햅틱장치란 가상환경이나 원거리에 있는 환경과 사용자가 상호 작용할 때 사용자에게 촉감이나 힘의 정보를 전달하여 주는 장치로 진동 및 회동 저항에 의해 사용자로 하여금 촉감들 느낄 수 있도록 하는 장치를 뜻한다. 즉, 현실감을 전달을 중점으로 하는 햅틱장치는 빠른 응답 속도와, 진동의 주파수와 크기는 독립적으로 제어가 가능해야 하며 기계적 수용기들을 직접적으로 자극할 수 있어야 한다. 하지만 모바일 햅틱장치의 경우 크기 및 소비전력의 문제로 모든 스펙을 만족하기에는 어려워 좀 더 한정적인 느낌을 제공할 수 없다. 현재까지 모바일 장치에서 햅틱 피드백을 위하여 진동모터나, 솔레노이드, 압전 액츄에이터 등이 많이 사용되어 지고 있다. 그 중 압전 액츄에이터는 입력에너지를 기계적 출력에너지로 변환되는 효과를 이용 한 것으로 압력 센서, 초음파 센서 등 많은 분야에서 응용되고 있으며 변위 범위는 작지만, 크기가 매우 작고 변위 정밀도가 높으며 발생력과 응답속도가 빠르다는 장점이 존재한다. 이를 이용한 햅틱 압전 엑츄에이터의 제작에 사용되는 압전 세라믹스는 높은 전기적 특성을 가질수록 더 졸은 효율을 가지며 이로 인하여 보다 좋은 전기적 특성을 가지는 압전 세라믹스를 필요로 한다. 현재 많이 사용되는 PZT계 세라믹스는 우수한 전기적 특성으로 많이 사용되고 있지만 Pb의 유독성으로 인한 환경문제로 Pb가 포함된 제품을 제한하고 있어 현재 Lead-free의 연구가 이루어지고 있다. Lead-free중 Ba$(Ti_{0.8}Zr_{0.2})O_3$(BZT)는 PZT계 세라믹스를 대체할 차세대 압전 재료로 주목받고 있다. 일반적으로 Lead-free의 압전계수($d_{33}$=100~300pC/N)는 비교적 낮은 값을 보이지만 BZT의 압전계수(BZT $d_{33}$~620pC/N)는 PZT계 세라믹스의 압전계수($d_{33}$=500~600pC/N)와 비교하여 부족하지 않은 압전계수를 보여주며 PZT를 대체할 재료로 주목받고 있다. 본 실험은 햅틱 압전 엑츄에이터용 무연 압전세라믹스의 제작을 위하여 Ba$(Ti_{0.8}Zr_{0.2})O_3-(Ba_{0.7}Ca_{0.3})-TiO_3$(BZT -BCT)의 조성으로 유전 및 압전 특성을 조사하였다.

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A Fundamental Study on the Converter Slag Coarse Aggregate Used in Concrete (전로슬래그 굵은골재를 콘크리트용으로 사용하기 위한 기초적 연구)

  • 문한영;유정훈;정호섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.233-236
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    • 1999
  • In this paper, we carried out fundamental experiments to use the steel manufacturing slag as a concrete aggregate. Generally there are two types of slag, the blast-furnace slag and the steel manufacturing slag. The latter is classified by the difference of manufacturing method of steel into the convertor slag and the electric-furnace slag. The steel manufacturing slag mainly contains SiO2 and CaO as the chmical composition. The reaction with water and a little of free CaO in the steel manufacturing slag makes the expansion of volume change. Therefore, we primarily investigated physical properties, expansion mechanism, pH value, aging effects and aging methods in the steel manufacturing slag. Then compressive strength of concrete with steel slag aggregate is measured.

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The Properties of Steel Slag Aggregate Treated with Aging Process in Concrete (에이징 처리한 콘크리트용 제강슬래그 골재의 품질)

  • 문한영;유정훈;천승환;백우열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.105-108
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    • 2001
  • In this paper, we evaluated the suitability of steel slag(is divided with electric arc furnace slag and converter slag) as concrete aggregate by measuring physical and chemical characteristics of it. The steel slag mainly contains SiO$_2$ and CaO as the chemical composition. The reaction with water and a little of free CaO in the slag causes slag's volume to expand. Therefore, we used several aging methods in order to decrease the characteristics of slag volume expansion. The physical properties of steel slag aggregate are researched and then the strength of concrete with the steel slag aggregate is measured.

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Studies on the clinker formed in thermal power plants (화력발전소에서 생성된 크링커에 대한 연구)

  • Park, Hyun-Joo;Nam, Chang-Hyun;Yun, Yeo-Chan;Lee, Tae-Won
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.34-40
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    • 2003
  • Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.

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A Study on the Properties of Electric Arc Furnace Slag and Converter Slag Aggregate (전기로 및 전로슬래그 골재의 품질에 대한 고찰)

  • Yoo, Jung-Hoon;Cho, Young-Kwon;Kim, Kwan-Ho;Lee, Joon-Gu;Shim, Jong-Sung;Park, Cheol-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.149-152
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    • 2006
  • In this paper, we researched and compared the properties of steel slag(is divided with electric arc furnace slag and converter slag) as concrete aggregate by measuring physical and chemical characteristics of it. The steel slag mainly contains SiO2 and CaO as the chemical composition. The reaction with water and a little of free CaO in the slag causes slag's volume to expanse. Therefore, we used several aging methods in order to decrease the characteristics of slag volume expansion. The physical properties of steel slag aggregate is researched and then the strength of concrete with the steel slag aggregate is measured.

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Fundamental Properties of Converter Slag Aggregate Treated with Accelerated Aging (촉진에이징처리한 전로슬래그 골재의 기초물성)

  • 문한영;유정훈;천승환
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.275-278
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    • 2000
  • In this paper, we carried out fundamental experiments to use steel manufacturing slag as a concrete aggregate. Generally, there are two types of slag, the blast-furnace slag and the steel manufacturing slag. The latter is classified by the difference of manufacturing method of steel into the convertor slag and the electric-furnace slag. The steel manufacturing slag mainly contains $SiO_2$ and CaO as the chemical composition. The reaction with water and a little of free CaO in the steel manufacturing slag made the expansion of volume change, Therefore, we primarily investigated physical properties, expansion mechanism, pH value, aging effect and aging methods in the steel manufacturing slag, Then compressive strength of concrete with steel slag aggregate is measured.

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The Effect of Refractory Crucible on Microstructure of Duplex Stainless Steel Cast with Gadolinium during Air Induction Melting (대기용해 시 내화물 도가니의 종류가 가돌리늄(Gadolinium)을 함유한 듀플렉스 스테인레스 강의 미세조직에 미치는 영향)

  • Ahn, Ji-Ho;Lim, Jae-han;Moon, Byung-Moon
    • Journal of Korea Foundry Society
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    • v.35 no.5
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    • pp.114-119
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    • 2015
  • This paper reports the effect of a refractory crucible type on the microstructure of duplex stainless steel (DSS) cast with the addition of gadolinium using air-induction melting. Grade 4A DSSs with 1 wt% of gadolinium (Gd) were fabricated in various crucibles including alumina ($Al_2O_3$), magnesia (MgO), calcia (CaO) coated with yttria ($Y_2O_3$) and graphite. The standard free energies of the formation of calcium and yttrium oxide were lower than those of gadolinium oxide and other crucible elements based oxide. The yield of Gd in DSS using $Al_2O_3$, MgO, CaO-coated $Y_2O_3$ and graphite was 5, 19, 83 and 96%, respectively. As Gd yield increased, the amount of Gd-based inclusions increased, the size of the inclusions were reduced, and the inclusions became evenly distributed.

Evidence for Singlet Oxygen Involvement in Cell-free Myeloperoxidase/$H_2O_2$/ Chloride Sytem: Exclusion of Hydroxyl Radical Involvement (Cell-free Myeloperoxidase/$H_2O_3$/Chloride System에서 Singlet Oxygen이 관여한다는 실험적 증거)

  • Chung Myung-Hee;Kim Yong-Sik
    • The Korean Journal of Pharmacology
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    • v.20 no.1 s.34
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    • pp.1-11
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    • 1984
  • The present study was performed to determine oxygen metabolites involved in cell-free MPO/$H_2O_2/Cl^-$ system by observing the effects of their scavengers on NADH oxidation and ethylene production from methional by the action of MPO prepared from human leukocytes. It was clearly demonstrated that NADH was oxidized by the cell-free MPO/$H_2O_2/Cl^-$ system as evidenced by complete inhibition of the oxidation of the substrate in the presence of eiher azide or catalase, or by omitting $Cl^-$. The MPO-mediated oxidation of NADH was completely abolished by a $^1O_2$ quencher, DABCO but not by $OH{\cdot}$ scavengers, mannitol, benzoate, formate and methanol. In ethylene assay, no ethylene was detected from methional in the MPO/$H_2O_2/Cl^-$ system with evident production of the gas by xanthine-oxidase and $Cu^{++}-H_2O_2$ systems which are suggested to generate $OH{\cdot}$. From the results obtained, it is concluded that $^1O_2$ is a major mediator with exclusion of $OH{\cdot}$ involvement in the cell-free MPO-mediated oxidation.

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SUPERSTRUCTURES OF Bi-Sr-Ca-Cu-O SUPERCONDUTORS (Bi-Sr-Ca-Cu-O계열 초전도체의 초구조)

  • Nam, Gung-Chan;Lee, Sang-Yun
    • Korean Journal of Materials Research
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    • v.4 no.3
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    • pp.268-279
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    • 1994
  • The x-ray powtler pattern of single phase $Bi_2S_2CaCu_2O_{8+x}$ has been identified and fullyindexed using a pseudotetragonal subcell with a= 5.408, c = 30.83 $\AA$ and an incommensurate supercellwith reciprocal lattice vector, X$q^*$, given by $q^*=0.211b^*-c^*$. The x -ray powder pattern of the Pb-free110K superconductor phase "$Bi_2S_2CaCu_2O_{10+x}$" has many lines which belong t.o an incommensuratesupercell. Using elect.ron d~ffraction pImt.ographs as a indexing guide, an indexing scheme for the powderpattern has been obtained. The unit cell has a geometrically orthorhombic subcell a=5.411, b= 5.420, c=37.29(2) $\AA$. Supercell reflections have indices that are derived from the subcell k, 1 indices by addition uf$\pm q^*$, where $\pm q^*=0.211b^*-0.78c^*$The incommensurate con~ponent In the b dwection, $\delta$, is the same for both phases but on going from2212 to 2223 phase, the superlattic component in the c direction changes from commensurate($\varepsilon$=1) toincommensurate($\varepsilon$=0.78).X>$\varepsilon$=0.78).

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