• Title/Summary/Keyword: formation behaviors

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Sintering Behavior of $B_4C-SiC$ Composite ($B_4C-SiC$ 복합체의 상압소결거동)

  • 김득중;강을손
    • Journal of the Korean Ceramic Society
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    • v.31 no.7
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    • pp.739-744
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    • 1994
  • The B4C-C system was investigated to gain an understanding of the sintering behaviors of B4C. In order to get sintered density of 97% TD, sintering temperature of 225$0^{\circ}C$ was necessary. Since such a high temperature operation is actually difficult on a commercial basis, our objective was to examine the possibility of decreasing the sintering temperature by adding SiC. The addition of SiC in B4C increases the sintering rate about at 210$0^{\circ}C$ and results in a fine microstructure with more than 98% relative density on 55 wt% B4C-40wt% SiC-5 wt% C composition. The probability of liquid phase sintering was investigated, but the evidences of liquid phase formation were not observed with XRD and TEM observation. It was proposed that the addition of SiC and carbon to B4C reduce interface energy during sintering, which results in enhanced grain-boundary diffusion. Thus, the enhanced grain-boundary diffusion and retarded grain growth by SiC improve densification.

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Mechanism and Behavior Characteristic of Space Truss Unit for Post-tensioning

  • Kim, Jin-Woo;Kim, Sang-Jin
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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    • v.6 no.1
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    • pp.38-43
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    • 2003
  • This paper presents the results of a post-tensioning test and analysis of a pyramidal unit structure that is basic element for space structures. The behavior characteristics was analyzed and compared with the numerical analysis and the mechanism in test model was confirmed with geometrical analysis. The results of this paper show that the behaviors of space structures can be predicted in multi-directional Mero joint system. And the authors suggest the possibility of erection and shaping formation with comparatively small post-tensioning, and space structure with the mechanism should consider the nonlinear behavior due to large deformation.

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Aspects of Mixture Formation in a Swirl Type GDI Engine (스월형 GDI 엔진의 연료혼합특성 연구)

  • 김기성;박상규
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.2
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    • pp.260-271
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    • 2003
  • For the Purpose of understanding the mixing phenomena of a GDI(Gasoline Direct Injection) engine, the spray behaviors and fuel distributions were investigated in a single cylinder transparent GDI engine. The experimental engine is a swirl type GDI engine with a SCV(Swirl Control Valve). PLIF(Planar Laser Induced Fluorescence) system with KrF Excimer laser was used for the measurement of the fuel distributions. The effects of SCV opening angles and the injector specifications on the fuel distribution characteristics were investigated. As a result, it was found that the SCV opening angle had a great effect on the fuel distributions in the late stage of compression process by changing the flow fields in the combustion chamber.

EVOLUTION OF A MASS ACCRETING PROTOSTAR OF ONE SOLAR MASS UNDER QUASI-HYDROSTATIC EQUILIBRIUM

  • Yun, Hong-Sik
    • The Bulletin of The Korean Astronomical Society
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    • v.3
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    • pp.18-23
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    • 1978
  • The evolutionary tracks of a protostar of one solar mass under quasi-hydrostatic equilibrium are computed with mass-accretion time scales of $10^3,\;10^4,\;10^5\;and\;10^6$ years, and their resulting behaviors in the H-R diagram are discussed. It is found that there exists a critical time scale of mass accretion, which reverses the course of their evolutionary tracks. A value of the critical time scale appears to lie between $10^3\;and\;10^4$ years. The physical cause for the presence of the critical time scale is discussed. Finally, it is proposed that star formation requires at least several $10^3$ years before any star is born out of dark dense interstellar clouds.

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Strain Properties of Sn-Substituted PLZT(7.5/70/30) for Application of Ceramic Actuator (세라믹 엑튜에이터 응용을 위한 Sn 치환의 PLZT(7.5/70/30)의 변형특성)

  • 고태경;강현구;박재환
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.512-520
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    • 1998
  • PLZT(7.5/70/30) was initially a cubic phase having diffuse phase transition at high temperatures. Sn-sub-stitution for PLZT(7.5/70/30) underwent an irreversible phase transition from cubic to rhom-bohedral structure. However PLZTS(7.5/70/30/y=5 & 10) could be reversibly switched from paraelectric to ferroelectric phase under electric field without showing a significant change in crystal structure. With in-creasing the amount of Sn-substitution the P-E behaviors of the PLZTS became more antiferroelectric which was similar to the effect of La-substitution of PLZT. Our study may suggest that Sn-substitution ef-fectively weakens a formation of long-range order between polar Ti-or Zr- containing octahedra which greatly affects strain properties.

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Influence of Activation Temperature on Micro- and Mesoporosity of Synthetic Activated Carbons

  • Park, Soo-Jin;Jung, Woo-Young
    • Carbon letters
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    • v.2 no.2
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    • pp.105-108
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    • 2001
  • In this work, the activated carbons (ACs) with high micropores were synthesized from the polystyrene (PS) with KOH as activating agent. And the influence of activation temperature on porosity of the ACs studied was investigated. The porous structures of ACs were characterized by nitrogen adsorption at 77K using BET and D-R equations, and MP and BJH methods. The weight loss behaviors of the samples impregnated with KOH were also monitored using thermogravimetric analyzer (TGA). As a result, it was found that the samples could be successfully converted into ACs with well-developed micropores. From the results of pore size analysis, it was confirmed that elevated activation temperature does lead to the formation and deepening of microstructures without significant change in mesostructures. A thermogravimetric study showed that KOH could suppress the thermal decomposition of the sample, resulting in the increase of carbon yields.

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Spectroscopic Analysis on Hydroquinone Clathrates for an Application to Storage/Recovery of Olefin Compounds (올레핀 저장/회수 기술 응용을 위한 하이드로퀴논 크러스레이트의 분광학적 분석 연구)

  • Lee, Jong-Won;Pratik, Dotel;Kang, Seong-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.5
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    • pp.437-443
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    • 2013
  • Clathrate samples, using hydroquinone as a host and ethylene or propylene as a possible guest, were prepared and analyzed by means of spectroscopic measurements. Obtained results showed that ethylene can form clathrate compounds with hydroquinone at 4.0MPa and room temperature, while propylene cannot form clathrate compounds. Different formation behaviors of these two olefin compounds can be applied to a clathrate-based storage/recovery of ethylene in a selective way, and can provide useful information on the cavity size of the formed clathrate compounds.

Behavior of catalyst layer during the growth of carbon nanotubes for field emission application by thermal chemical vapor deposition

  • Park, Jong-Bong;Kim, Do-Jin;Choi, Sung-Yool;Ahn, Seong-Deok;Lee, Jin-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.694-696
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    • 2002
  • Growth behaviors of carbon nanotubes (CNTs) are studied in terms of catalyst by using scanning electron microscopy and transmission electron microscope (TEM). Catalyst films deposited on various substrates are agglomerated into nano-islands during the heat-up to the growth temperature. In particular, we focus on the direct investigation of the microstructures of the CNTs and the interface of CNTs-catalyst-substrate using cross-sectional TEM. We investigate relationship to the subsequent CNTs growth on each nucleation site. The growth of CNTs depends on the catalyst itself but not the silicide formation between the catalyst and the substrate.

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Mixed-Island Formation and Electronic Structure of Metallo-Porphyrin Molecules on Au(111)

  • Kim, Ho-Won;Jeong, Gyeong-Hun;Gang, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.303-303
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    • 2011
  • Orderings and electronic structures of organic molecules on metal substrates have been studied due to possible applications in electronic devices. In molecular systems, delocalized pi-electrons play important roles in the adsorption behaviors and electronic structures. We studied the adsorption and electronic structures of Co-Porphyrin molecules on Au(111) using scanning tunneling microscopy (STM) and spectroscopy (STS) at low temperature. Molecules form closely packed two-dimensional islands on Au(111) surface with two different types, having different shape evolutions in our energy-dependent STM observations. The Kondo resonance state, occurred by spin exchange interaction between the Co center atom and conduction electrons in the metal substrate, was observed in one type, while it was absent in the other type in scanning tunneling spectroscopy measurements. Possible origins of two molecular shapes will be discussed.

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Composite Crystal Phases of Authigenic Heulandite-clinoptilolite from Sandstones and Its Crystal-chemical Significance (사암에서 산출되는 속성 기원 휼란다이트-클리놉틸로라이트의 복합 결정상의 그 결정화학적 의의)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.82-92
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    • 1996
  • The coarse-grained (0.05∼0.2mm) zeolites occur as the single-crystal cement in the sandstones of the Chunbuk Formation in the Pohang area. The zeolite cements unusually consist of the composite phases of heulandite and clinoptilolite and in a crystal. The zeolite crystals show chemical zoning ranging from 3.56 to 4.10 in Si/(Al+Fe), and tend to become continuously more silicic and alkalic from the margin toward inside of the crystal. The DTA and high-temperature XRD analyses also show complex patterns of both zeolites. Such a composite crystal showing chemical zoning and complex thermo-chemical behaviors indicates that heulandite and clinoptilolite are constituting a solid solution resulted from the coupled substitution of K+Si4+=Ca2+Al3+.

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