• Title/Summary/Keyword: foaming power

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Studies on the N-Acyl Amino Acid Type Surfactants(4) Surface Active Properties of N-Acyl-N-Methyl-β-Alanine Salts (N-아실 아미노산계 계면활성제에 관한 연구 (제 4 보) N-아실-N-메틸-β-알라닌 염류의 계면활성)

  • No, Seung-Ho;Lee, Sun-Ju;Kim, Tae-Young;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.216-221
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    • 1991
  • Surface activities of four potassium N-acyl-N-methyl-${\beta}$-alaninate including surface tension, foaming power, foam stability, emulsifying power and dispersion power were measured respectively, and critical micelle concentration(cmc) was evaluated. Consequently these anionic surfactants with long chain acyl amide showed good emusifying power of O/W type, foaming, foam stability and dispersion effect.

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Synthesis of Surface Active Properties of Destructible Surfactants with 1,3-Dioxane (1,3-디옥산을 함유한 분해성 계면활성제의 합성의 및 계면 특성)

  • Kim, Chi-Hoi;Roh, Yun-Chan;Kim, Yu-Ok;Nam, Kie-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.61-71
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    • 1996
  • In acid-catalyzed acetal cyclization of long aliphatic aldehydes($R=n-C_7H_{15}$ ; $n-C_9H_{19}$ ; $n-C_{11}H_{23}$) with 1,1,1-tris(hydroxymethyl)propane, 2-alkyl-5-hydroxymethyl-5-ethyl-1,3-dioxanes were obtained. The final products, sodium 2-alkyl-5-(sulfonatedpropylethermethyl)-5-ethyl-1,3-propanesultion in the presence of sodium hydride. These compounds were a new group of destructible surfactants which were readily hydrolyzed and oxidized in natural water reservoirs. Physical properties of these new compounds involved some surface properties such as Krafft point(Kp), critical micelle concentration(cmc), surface tension of aqueous solutions near cmc(${\gamma}_{min}$), foaming power, emulsion power and hydrolysis properties were determined. The destructible surfactants containing 1,3-dioxane ring were synthesized to about $85{\pm}5.5%$ yield. The cmc values of the compounds by ring method were assumed to $0.5{\sim}5.0{\times}10^{-3}mol/L$ range and surface tensions at cmc were $29.5{\sim}33.0dyne/cm$ respectively at $25^{\circ}C$. The foaming power and foam stability were $170{\sim}230mm$ and $52{\sim}135mm$ respectively at $1{\times}10^{-2}mol/L$, foam was occurred rarely below $1{\times}10^{-3}mol/L$. The emulsion property of liquid paraffin was better than that of soybean oil. For hydrolysis property with ph and time, these compounds were decomposed within about 200minutes at $ph1{\sim}2$. Hopefully these compounds are expected to be a good O/W emulsifier that have decomposability in acid and may be used in the process which do not need foaming.

Studies on Heat Sensitivity of Egg Albumen I. Effects of Heating Time and Temperature, pH and NaCl Concentration on Heat Sensitivity of Egg Albumen (난백 의 열감수성 에 관한 연구 I. 가열온도와 시간, pH 및 NaCl농도가 난백의 열감수성에 미치는 영향)

  • 유익종
    • Korean Journal of Poultry Science
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    • v.15 no.1
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    • pp.39-44
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    • 1988
  • This study was undertaken to find out the effect of heating time and temperature, pH and NaCl concentration on heat sensitivity of egg albumen during heat treatment. Sharp increase of the turbidity and rapid decrease of the foaming power were observed when egg albumen was heated at above $60^{\circ}C$. Egg albumen became opaque when it was heated at $60^{\circ}C$ for above 13 minutes or at $65^{\circ}C$ for above 5 minutes. The turbidity was markedly increased at below pH 7 and the foaming power was largely decreased at around pH 4.0 by the heat treatment ($60^{\circ}C$, 5 min). The foam stability was slightly decreased at alkaline pH range by the heat treatment (60t, 5 min). The addition of NaCl up to 0.3M decreased the turbidity. There was no effect of NaCl addition on the foaming power, but the foam stability was decreased by the addition of NaCl at above 0.2M before and after the heat treatment ($60^{\circ}C$, 5 min).

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A Study on the Preparation of Solvent-Free Low Foaming Scouring Agents (무용제형 저기포성 정련제의 제조에 관한 연구)

  • Keun, Jang-Hyoun;Kim, Seung-Jin;Hahm, Hyun-Sik;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.760-769
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    • 1993
  • Solvent-free low foaming scouring agents(LFSA) were prepared by blending of polyoxyethylene(30) octadecylbenzylammonium chloride(POAC), block copolymer of propylene oxide-ethylene oxide[p(PO-b-EO) glycol], Sedlan FF-200(FF-200) and sulfonic acid-amine condensate of polyoxyethylene(10) nonylphenyl ether(PSAC). In consequence of several tests, FF-200/POAC/p(PO-b-EO) glycol/PSAC/water (20g/10g/5g/5g/60g) mixture (LFSA-5) showed good cleaning power, penetrating ability, emulsifiability and stability to alkali, and gave less problem in water pollution. Scouring effect of LFSA-5 was investigated by the change of percentage of exhaustion before and after scouring at various dyeing temperatures. The percentage of exhaustion of the unscoured PET fabric was 4.5% at $70^{\circ}C$, while that scoured with LFSA-5 was 1.3% at the same temperature, which proved LFSA-5 to be a good scouring agent. Moreover, the foaming power of LFSA-5 measured by Ross and Miles method was 6mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 20mm at $80^{\circ}C$. As a result, LFSA-5 proved a good low foaming scouring agent.

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Anti-Foaming Properties of Polypropylene Glycol Oleates (올레산 폴리프로필렌글리콜 에스테르류의 소포특성)

  • Li, Hai-Yan;Choi, Hyoung-Chul;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.146-151
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    • 2011
  • In this study, by using oleic acid and polypropylene glycol, good natured antifoaming agent for suitable electronics process under the alkaline conditions were synthesized. For the synthesized mono and diesters, acid value, hydroxyl value was measured, and identified by FT-IR and $^1H-NMR$ spectroscopy. Surface properties such as surface tension, critical micelle concentration(cmc) for diluted aqueous solution was measured, and tested the antifoaming properties according to the difference of alkyl chain length, various concentration, temperature and pH. The surface tension of synthesized antifoaming agent, PPMO(Polypropylene glycol monooleate) was 24.3 dyne/cm, PPDO(Polypropylene glycol dioleate) was 23.7 dyne/cm. By increasing of the alkyl chain length, surface tension was decreased slightly, and showed good antifoaming properties at 0.06 wt% concentration and $50^{\circ}C$, pH 11. These synthesized compounds are expected to apply as a suitable antifoaming agents in the semiconductor and the PCB(Printed Circuit Board) manufacturing process.

Preparation and Effects of Low Foaming Acidic Degreasing Agents for Aluminum (알루미늄용 저기포성 산성탈지제의 제조와 그의 탈지효과)

  • Ha, Kyung-Jin;Park, Hong-Soo;Bae, Jang-Soon;Kim, Young-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.71-77
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    • 1997
  • Low foaming acidic degreasing agent(LFADAs) were prepared by blending sorbitol, n-octanoic acid, MJU-100A, Tetronix T-701, Na-dioctyl sulfosuccinate, Demol C, and phosphoric acid. The physical properties of LFADAs tested with aluminum specimen showed the following results ; when 3wt% LFADA-6 was performed at $70^{\circ}C$, the degreasing rate was 95% which is comparitively good, and the percentage of etching was 0.275% which was found to be less than that of commercialized product. When 20wt% of LFADA-6 was added at $65^{\circ}C$, the percentage of derusting was 92% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

Synthesis and Properties of Anionic Surfactants Using Sarcosine and Taurine (사코진과 타우린을 이용한 음이온 계면활성제의 합성 및 물성)

  • Cho, Jung-Eun;Shin, Hye-Rin;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.102-107
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    • 2019
  • Anionic surfactants were synthesized by using an sarcosine, taurine and fatty alcohol with varying the carbon chain length. The structure of synthesized surfactants was confirmed by $^1H$ NMR analysis. The critical micelle concentration of the synthetic anionic surfactant was $10^{-2}{\sim}10^{-4}mol/L$ and the surface tension value at the critical micelle concentration was between 21 and 39 mN/m. It was confirmed by the Ross-Miles method that the synthetic surfactant with the carbon chain of 12 showed a good foaming power and stability. In addition, the surfactant using the sacosine was found to have a good affinity in soybean oil while that using taurine in benzene. The physical properties of synthesized surfactants were determined by measuring the critical micelle concentration, foaming power and emulsifying stability.

A Study on the Styrofoaming Method by UHF Heating (초고주파 가열을 이용한 스티로폼 제조기술 연구)

  • Han Doo Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.1
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    • pp.94-103
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    • 2005
  • The low foamed high strengthen styrofoam samples made by dielectric heating are discussed. We used the oscillator which have the frequency of 13.6 MHz and the power of 7 kW. 3 times expanded beads by steaming method were used in our foam-molding test. Internal fusion properties and density of internal structure were improved by dielectric foaming process. At the temperature of $105-110^{\circ}C$, the internal fusion property was maximally improved.

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Development of Vibroacoustic Stimulation Seat for a Movie Theater Chair (영화관 의자용 음향진동자극 시트의 개발)

  • Moon, Deok-Hong
    • Journal of Power System Engineering
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    • v.17 no.1
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    • pp.42-49
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    • 2013
  • The global movie industry is continuing rapid growth through application of the latest technology. 3D movies are being produced and shown for a more effective viewing experience. Special chairs for audiences are being experimentally manufactured and installed for the greatest viewing effect. This special chair has a structure that applies vibrating stimuli to specific parts of the body by attaching vibration transducers to theater chairs and synchronizing it with each scene of the movie. In a previous study, it has been confirmed that we can analyze the vibration transfer characteristics of sponge seats through the application of an experimental modal analysis method and obtain design variables easily. In this paper, we examine the major design parameters needed in the development of a foaming sponge seat in which auxiliary springs are inserted to improve the vibration transfer effect of a chair seat. Through analyzing several prototypes by applying experimentation as well as the experimental modal analysis method, it was confirmed that the effect of vibration transfer can be improved through the use of an auxiliary member.

Synthesis and Characteristics of Alkaline Degreasing Agents for Steel Containing Degreasing Components (탈지조성에 따른 철강용 알칼리탈지제의 합성 및 특성)

  • Park, Eun-Seok;Chung, Dong-Jin;Park, Hong-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.81-86
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    • 2003
  • To prepare alkaline degreasing agents(SADAs), tetrasodium pyrophosphate(TSPP), $Na_2CO_3$, Tetronix T-701 (T-701), Na-dioctyl sulfosuccinate(303C), Demol C, and MJU-100A were blended. The prepared degreasing agents were tested with steel specimens and the results were as follows. The degreasing powers of SADA-6($Na_2CO_3$ 50g/TSPP 25g/T-701 10g/303C 15g/Demol C 12g/MJU-100A 8g/water 130g mixture) for press-rust preventing oil were 98% and 99% degreasing at 4wt%, 70 $^{\circ}C$ and 90 $^{\circ}C$, respectively; for quenching oil, the degreasing power of SADA-6 was 92% degreasing at 4wt% and 70 $^{\circ}C$. From these results, it was proved that the SADA-6 exhibits a good degreasing power. Foam heights measured immediately after foaming by Ross & Miles method and Ross & Clark method at 6wt% and 60 $^{\circ}C$ were 16mm and 40mm, respectively. SADA-6 was proved a good low foaming degreasing agent.