• Title/Summary/Keyword: foaming agent

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Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).

Rheological Properties and Foaming Behaviors of Modified PP/Nano-filler Composites (개질 폴리프로필렌/나노필러 복합체의 유변학적 특성 및 발포거동)

  • Yoon, Kyung Hwa;Lee, Jong Won;Kim, Youn Cheol
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.494-499
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    • 2013
  • Modified polypropylene (m-PP) was fabricated by furfuryl sulphide (FS) as branching agent and m-PP/nano-filler composites were prepared with silicate and multi-walled carbon nanotube (MWCNT), using a twin screw extruder. The chemical structures and thermal properties of the m-PP were investigated by FTIR and DSC. The chemical structure of the m-PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no district change in melting temperature in case of m-PP, but a certain increase in crystallization temperature was notified and the increase was in the range of $10-20^{\circ}C$. The rheological properties, filler dispersion and foaming behaviors of the m-PP/nano-filler composites were investigated by dynamic rheometer, X-ray diffractometer (XRD) and scanning/transmission electron microscope (SEM/TEM). m-PP/nano-filler composites showed a high complex viscosity at a low frequency, an increase in melt elasticity, and a high shear thinning effect. Compared to pure PP, m-PP and m-PP/nano-filler composites were sufficient to enhance the foaming behavior.

A study on the process optimization of microcellular foaming injection molded air-conditioner drain pen (화학적 초미세 발포 사출성형을 이용한 에어컨 드레인 펜의 공정 최적화에 대한 연구)

  • Kim, Joo-Kwon;Kwak, Jae-Seob;Kim, Jun-Min;Lee, Jun-Han;Kim, Jong-Sun
    • Design & Manufacturing
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    • v.11 no.2
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    • pp.1-8
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    • 2017
  • In this study, we applied microcellular foaming injection molding process to improve the performance of system air-conditioner drain fan which had been produced by injection molding process and studied the optimization of process conditions through 6-sigma process and response surface method (RSM) to reduce weight and deformation of products. Additive type, melt temperature, mold temperature, and injection screw shape were selected as the factor affecting the weight and deformation of the products by carrying out analysis of trivial many through ANOVA and design of experiment (DOE) method. Among the effect factor, we set the addictive type to Long G/F and screw shape to foaming screw which had the highest level of weight reduction and deformation reduction. The amount of foaming agent gas was set at 60 ml, which was the limit beyond which the weight of product did not decrease any more. For melt temperature and mold temperature, we studied the conditions where both weight and deformation were minimized using the RSM. As a result, we set the melt temperature to $250^{\circ}C$, fixed mold temperature to $20^{\circ}C$, and moving mold temperature to $40^{\circ}C$. The improvement effect was analyzed by appling the selected optimal conditions to the production process using the microcellular foaming injection molding. The results showed that the mean weight of product was measured to be 1,420g which was 19% lower than that measured in the current process. The standard deviations of the weights were found to be similar to those in the current process and it showed a low dispersion. The mean deformation was measured to be 0.9237mm, which represented a 57% reduction compared to the mean deformation in the current process, and the standard deviation decreased from 0.3298mm to 0.1398mm. Moreover, we analyzed the process capability for deformation, and the results showed that the short-term process capability increased from 2.73 to 6.60 which was even higher than targeted level of 6.0.

Preparation Technique of Foam-Floater to Level Gauge of LPG Tank with High Pressure (LPG 고압탱크 레벨 게이지(Level Gauge)용 발포부표 제조 기술)

  • Kim, Byoung-Sik;Hong, Joo-Hee;Chung, Yongjae;Heo, Kwang-Beom
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.361-368
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    • 2006
  • The purpose of this study is to invent the preparation technique of the foam-floater used as a level gauge of liquefied petroleum gas (LPG) tank under high pressure, which has not only closed pores but also has under 5 wt% changingrate in case of depositing 72 h in room-temperature LPG. In pressure-resistance and deposition experiment, the prepared foam-floaters with different sulfur (325 Mesh and 400 Mesh) and foaming agent (dinitrosopentamethylenetetramin; DPT and azodicarbonamide; AC) had a marginal difference in its weight changing-rate. However, the prepared floater with sulfur 400 Mesh and the foaming agent AC had smaller pores and higher closed pore-rate. Under $50kg_f/cm^3$ hydraulic pressure, the floater with medium thermal (MT) carbon showed a lower weight changing-rate than semi reinforcing furnace (SRF) carbon. Providing a post-treatment to the prepared floater, the hardness and the pressure-resistance of the inner pore-wall of floater were increased. Prepared floaters having a specific gravity below 0.30 were distorted and broken, and other floaters with a specific gravity above 0.35 were not useful as a floater because of the low buoyancy. Therefore, it was considered that the floaters with a specific gravity between 0.3~0.35 are the most useful as a floater under $50kg_f/cm^3$ pressure-resistance.

A Physical Properties of Lightweight Foamed Concrete According to Lightweight Aggregate Types and Foaming agent Types (경량골재와 기포제 종류에 따른 경량기포 콘크리트의 물리적 특성)

  • Kim, Ha-Seog;Lee, Sea-Hyun;Sun, Jung-Soo;Kim, Jin-Man
    • Journal of the Korea Concrete Institute
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    • v.28 no.4
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    • pp.435-444
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    • 2016
  • In Korea, approximately 48% of all households live in apartments, which are a form of multi-unit dwellings, and this figure increases up to 58%, when row houses and multiplex houses are included. As such, majority of the population reside in multi-unit dwellings where they are exposed to the problem of floor impact noise that can cause disputes and conflicts. Accordingly, this study was conducted to manufacture a high-weight, high-stiffness foamed concrete in order to develop a technology to reduce the floor impact noise. For the purpose of deriving the optimum mixing ratio for the foamed concrete that best reduces the floor impact noise, the amounts of the foaming agent, lightweight aggregate and binder were varied accordingly. Also, the target characteristics of the concrete to be developed included density of over $0.7t/m^3$, compressive strength of over $2.0N/mm^2$ and thermal conductivity of under 0.19 W/mK. The results of the experiment showed that the fluidity was very excellent at over 190 mm, regardless of the type and input amount of foaming agent and lightweight aggregate. The density and compressive strength measurements showed that the target density and compressive strength were satisfied in the specimen with 50% foam mixing ratio for foamed concrete and in all of the mixtures for the lightweight aggregate foamed concrete. In addition, the thermal conductivity measurements showed that the target thermal conductivity was satisfied in all of the foamed concrete specimens, except for VS50, in the 25% replacement ratio case for Type A aggregate, and all of the mixtures for Type B aggregate.

Mechanical Properties of Rapid-Setting Latex Modified Mortar for Antifoam Agent Type and Content (소포제 종류 및 혼입률에 따른 초속경 라텍스개질 모르타르의 역학적 특성)

  • Lee, Bong-Hak;Hong, Chang-Woo;Lee, Joo-Hyung;Kim, Dong-Ho
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.249-256
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    • 2001
  • The purpose of this study was to remove the excessive air foaming which was produced in mixing the RSLMC(latex-modified concrete with rapid-setting cement) by choosing the best antifoam agent type. A series of RSLMM(latex-modified mortar with rapid-setting cement) experiments were carried out as a basic experiments for RSLMC with the main experimental variables such as antifiamer types(A, B, C, D), antifoamer contents(0, 1, 2, 3%), and latex contents(10, 15%). Air content test and compressive strength tests were carried out to measure the improved properties of RSLMM. SEM analysis, also, was carried to observe the formation of latex film. The results of RSLMM showed that the decrease of 50% air content was obtained by admixturing an antifoam agent by 1%. This made the strength enhanced and the workability be within the purposed. The best properties of compressive strengths was obtained at latex content of 15% and D antifoam agent of 1%. compressive strength increased about 32.6%. The analysis of SEM results no difference in a formation of later film.

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경량 난연성 성형체의 특성에 관한 연구

  • 강영구;강정식;조명호
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1999.06a
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    • pp.265-268
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    • 1999
  • 경량 건축소재는 협소공간의 고도 이용과 건설 분야의 양적, 질적인 측면에서 급속한 성장으로 건축자재의 경량화, 고급화 및 다양화를 요구하고 있으며 이에 PE, PP, PS, PVC 등의 플리스틱 foam 및 저밀도 콘크리트 등의 경량 건축 소재에 대한 연구가 지속되고 있다. 경량 건축소재로 사용되는 플라스틱류는 대부분 난연화 및 강도유지를 위해 난연제, 섬유 및 무기충진제 등를 첨가하거나 고밀도화하여 사용하며 경량화를 위해 foaming agent를 사용하여 기포를 발생시켜 경량화하여 성형된다. (중략)

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The comparison of treating finishing agent using foaming and padding method (거품과 패딩법을 이용한 가공제 처리 비교)

  • 신유식;이기풍;송병갑;이형달;박철용
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.235-236
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    • 2003
  • 섬유의 습식 가공은 에너지 집약적 산업이다. 대부분의 에너지는 가공시 사용된 많은 양의 수분을 증발시키고, 건조하는데 소모되어진다. 따라서 거품가공은 물 소비를 감소시켜 에너지를 절약하고 폐수를 감소시키는데 주된 목적이 있다(1). 거품가공은 직물에 부가된 물의 양을 감소시켜 건조단계에서 상당한 에너지 소비(30~80%)를 감소시키는 것으로 알려져 있고(2~3), 최근에는 낮은 wet pick-up율에 의한 가공제 처리의 성능 및 수지의 가교분포에 대한 효과 등에 관한 많은 연구가 이루어지고 있으나 미흡한 점이 많이 보고되고 있다.(4~7) (중략)

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Surface improvement of Polypropylene structural foam by foaming agent amount (발포사출성형품의 외관 품질 개선 관한 연구)

  • Kim Dong-Hak;Kwak On-Sub
    • Proceedings of the KAIS Fall Conference
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    • 2004.11a
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    • pp.292-295
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    • 2004
  • 본 연구에서는 발포사출성형품의 단점인 외관 품질을 개선하기 위해 순간 금형가열방식인 MmSH(Momentary Mold Surface Heating)을 사용하였다. 또한 발포제의 함량에 따른 발포 체의 구조를 살펴보았다. 일반발포사출과 MmSH방식을 사용 발포사출의 표면거칠기를 비교한 결과 표면이 개선된 것을 볼 수 있었고 발포제의 함량에 따른 발포체의 구조는 함량이 증가함에 따라 중량 감소로 셀 수 증가를 보였지만 어느 한계 이후에서는 영향을 미치지 않는 것으로 보여진다.

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A study on the fabrication of foamed glass by using refused coal ore and its physical properties (석탄 폐석을 이용한 발포유리의 제조 및 물리적 특성 연구)

  • Lim, Tae-Young;Ku, Hyun-Woo;Hwang, Jong-Hee;Kim, Jin-Ho;Kim, Jung-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.266-273
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    • 2011
  • Foamed glass was fabricated by using glass powder and foaming agents. For the glass powder, we used sodalime glass which's manufactured by using refused coal ore obtained as by-product from Dogye coal mine in Samcheok. And for the foaming agents, we used Calcium carbonate, Calcium phosphate and powder of shale type refused coal ore itself which has high content of carbon materials. We additionally used liquid binder for forming, and mixed together. And we formed rectangular shape and treated $800^{\circ}C$ for 20 min in an electrical furnace. The various kinds of foam glass samples were fabricated according to the kinds of foaming agents. The physical properties of samples, as specific gravity and compressive strength, were measured. Pore structure of each samples were investigated too. Foam glass with specific gravity of 0.4~0.7 and compressive strength of 30~72 kg/$cm^2$. Especially we get satisfying foam glass sample with low specific gravity of 0.47 and high compressive strength of 72 kg/$cm^2$ by the use of liquid calcium phosphate as foaming agent. It also had small and even shape of pore structure. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a foamed glass panel for construction and industrial materials.