• Korean Journal of Materials Research
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• v.22 no.11
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• pp.604-608
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• 2012

Recently, inorganic-organic hybrid materials have attracted much attention not only for their excellent thermal conductivity but also for their flame retardant properties. In this study, the properties of organic-inorganic hybrid insulating materials using inorganic fillers and polyurethane foam with different foaming conditions have been investigated. The addition of 1.5 wt% water to polyurethane as foaming agent shows the best foaming properties. The pore size was decreased in the foaming body with increasing of the $CaCO_3$ addition. The apparent density and thermal conductivity were increased by increasing the $CaCO_3$ addition. With an increasing amount of $CaCO_3$ powder, the flame retardant property is improved, but the properties of thermal conductivity and apparent density tend to decrease. When the addition of fine particles of $CaCO_3$, the apparent density and thermal conductivity were increased and, also, with the addition of coarse particles over $45{\mu}m$ in size, the apparent density and thermal conductivity were increased as well. In this study, the adding of $CaCO_3$ with average particle size of $27{\mu}m$ led to the lowest thermal conductivity and apparent density. After evaluation with different inorganic fillers, $Mg(OH)_2$ showed the highest thermal conductivity; on the other hand, $CaCO_3$ showed the lowest thermal conductivity.

• Journal of the Society of Naval Architects of Korea
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• v.55 no.5
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• pp.448-455
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• 2018

Glass wool is an eco-friendly materials that is manufactured through a continuous process by processing waste glass. This materials is low cost compared with another materials and has excellent thermal conductivity. For this reason, glass wool is installed as insulation system for LNG carriers and as insulation of building wall as well as various industries. The mechanism of insulation of glass wool is the conduction of the wool itself and convection by space between fibers. Therefore, in order to develop the enhanced thermal conductivity of glass wool is necessary to reduce its own conduction or to insert additional material after manufacturing as well as prevent convection. In this respect, many researchers have been actively studying to decrease thermal conductivity of polyurethane foam using by inserted glass wool or change the chemical component of glass wool. However, many research are aiming reduction of glass wool itself. This study focus on post-processing and inserted different materials; silica-aerogel, kevlar fiber 1mm, 6mm and glass bubble. Experimental results show that the thermal conductivity almost decreases with the addiction of glass bubble and silica aerogel.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.753-758
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• 2018

Surface activities including CMC, surface tension, foaming power etc. of the rhamnolipid (RL), a biosurfactant fermented by microorganism were investigated. Both the RL and liquid detergent contained RL showed a good surface activity. For the detergency test, the liquid detergent with RL showed a slightly better performance than that of using an fatty acid. However for the foaming profile, the liquid detergent with RL exhibited a lot of foam volume and the suppression of the rinsing and foaming during rinsing cycles with the RL was not seen. Therefore it can be concluded that RL can be used as a main surfactant or co-surfactant in liquid detergents without functions of foaming suppression or rinse-aid.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.27 no.2
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• pp.55-62
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• 2021

This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO₂), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl₂, and TiO₂ powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

• Journal of the Korean GEO-environmental Society
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• v.12 no.9
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• pp.35-45
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• 2011

This paper is to analyze the behaviors of tunnel support by TDR(Time Domain Reflectometry) sensor using electrical pulse. To analysis the behaviors of tunnel support, Copper tape as sensing materials was studied for on-site installation. Copper tape to the top of the glass tape, foam tape, and shielding the lower part was used electromagnetic shield sheet. For a high sensitivity to load and fill out the measurement noise emissions has been developed for the production of materials. This sensing material through the tunnel model tests for the change by surcharge load in TDR data were analyzed. Varing stiffness and support of conditions were determined the change of TDR data through PVC pipe tunnel section model tests. By comparing TDR data and finite element analysis, the behaviors of the tunnel support materials were analyzed qualitatively.

• International conference on construction engineering and project management
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• 2017.10a
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• pp.89-98
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• 2017

The floor heating method generally uses a wet construction method including the installation of resilient material, lightweight foam concrete, heating piping, and finishing mortar. Such a wet construction method not only delays other internal finishing processes during curing period for two mortar pouring process, but also has a disadvantage that it is difficult to replace the floor heating layer when it deteriorated because it is integrated with the frame. Dry floor heating construction method can be a good alternative in that it can solve these defects. Conversely, when it applied to the wall structure that is vulnerable to the interlayer noise compared with the column-beam structure, the question about the heavy-impact sound(HIS) insulation performance is raised. Therefore, conventional dry floor heating method is hard to apply to the wall structure apartments. Therefore, for the purpose to improve the applicability of dry floor heating method in wall structure apartments, this study investigated the change of floor impact sound, especially HIS insulation performance which is one of the required performance for the floor structure. This study tried to examine whether the change of heavy-impact sound pressure level(SPL) shows a tendency at the significant level according to the shape and mass of the floor structure. Through filed experiments on wall structure apartment, this study confirmed that the form of the raised floor shows better HIS insulation performance than the fully-supported form. In addition, it was also confirmed that the HIS insulation performance increases with the mass on the upper part. Moreover, this study found the fact that a mass of about 30 kg/m² or more should be placed on the upper structure to reduce the heavy-impact SPL according to the bang machine measuring method. Although this study has a limit due to insufficient experiment samples, if the accuracy of this study is increased, it will contribute to the diffusion of dry floor heating by setting the HIS insulation performance target and designing the dry floor heating structure that meets the target.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.34 no.3
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• pp.92-97
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• 2024

To improve the efficiency of water splitting systems for hydrogen production, the high overvoltages of electrochemical reactions caused by catalysts in the oxygen evolution reaction (OER, Oxygen Evolution Reaction) must be reduced. Among them, LDH (Layered Double Hydroxide) compounds containing transition metal such as Ni, are attracting attention as catalyst materials that can replace precious metals such as platinum that are currently used. In this study, nickel foam, an inexpensive metallic porous material, was used as a support, and NiCo LDH (Layered Double Hydroxide) nanocrystals were synthesized through a hydrothermal synthesis process. In addition, changes in the shape, crystal structure, and water decomposition characteristics of the Mo-doped NiCo LDH nanocrystal samples synthesized by doping Mo to improve OER properties were observed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.3
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• pp.203-212
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• 2005

Cellulose insulation is primarily manufactured from recycled newsprint and treated with fire retardants for the fire resistance. Thanks to the fire retardants, it is not combustible and flammable. In addition to that, Its thermal resistance is much better than that of fiberglass or rock wool. It is made from waste paper and easily decayed when it is demolished, and it has small embodied energy. So it is very environment-friendly building material. For broader use of cellulose insulation in buildings in Korea, it is necessary to test its physical performance to compare the results with the requirements on the Korean Building Code. To this end, apparent thermal conductivity (ka) measurements of Korean-made loose-fill cellulose insulations were recently completed using equipment that was built and operated in accordance with ASTM C 518 and the fire resistance was tested in accordance with ASTM C 1485. Korean loose-fill cellulose has thermal conductivity about 5% greater than the corresponding U.S. product at the same density. This is likely due to differences in the recycled material being used. Both spray-applied and loose-fill cellulose insulation lose about 1.5% of their thermal resistivity for $5.5^{\circ}C$ increase in temperature. The fire resistance of cellulose insulation is increased in linear proportion to the increase of the rate of fire retardant. Thanks to the high fire resistance, cellulose insulation can be used as a substitution of Styrofoam or Urethane foam which is combustible. The thermal conductivity of cellulose insulation was $0.037-0.043W/m{\cdot}K$ at the mean specimen temperature from $4-43^{\circ}C$. It corresponds to the thermal resistance of "Na Grade" according to the Korean Building Code. The effect of chemical content on thermal conductivity was negligible for all but the chemical-free specimen which had the highest value for the thermal conductivity over the temperature range tested. The thermal resistance of cellulose insulation is better than that of fiberglass or rock wool, and its fire resistance is higher than that of Styrofoam or Urethane foam. Therefore it can be substituted for those above considering its physical performance. Cellulose insulation is no more expensive than Styrofoam or rock wool, so it is recommended to use it more widely in Korea.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.920-926
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• 1997

The catalytic glycolysis process is the method of chemical recycling where the polyol and carbamate compounds recovered by transesterification reaction are reused to produce new polyurethane foams. In this work, ethylene glycol, diethylene glycol, and 1,4-butanediol were used to decompose polyurethane foams and various metallic acetates were provided as catalysts. The catalytic glycolsis of polyurethane foams was taken place in the reaction temperature of $180{\sim}200^{\circ}C$. The reaction rates of catalytic glycolysis reaction were indicated by the viscosity of the reaction products at different reaction times. IR and GPC analysis showed the types and the molecular weight distributions of the products. The catalytic glycolysis was profitable for using ethyleneglycol at high temperature. The activities of the catalysts are suitable for K, Na, Tl acetate, and the products are composed of comparatively high-contained amine compounds and carbamate compounds. In the case of Sr acetate and Quinoline, the reaction rate was somewhat low. However, the content of polyol was high and the content of the side-products was low. The foams which were prepared by blending up to 20wt% of recovered polyol with virgin polyols showed better physical properties in tensile strength, hardness, tear strength, and compressive strength compared to those of polyurethane foams from virgin polyol.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.6
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• pp.625-633
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• 2014

Mark III CCS plate is considered in this paper to perform its strength assessment. Mark III CCS plate is designed and constructed by stacking various non-metallic engineering materials such as plywood, triplex and reinforced PU foam that are supported by series of mastic upon inner steel hull structure. From the viewpoint of structural analysis, this plated structure is treated as a laminated anisotropic structure. Commercially available general purpose finite element analysis programs such as MSC PATRAN and MARC are used to develop the finite element (FE) model of the Mark III CCS plate. Because of the characteristics of LNG cargo that the Mark III CCS plate deals with, it is subjected to a wide range of temperature variations, i.e. about $-163^{\circ}C$ to $20^{\circ}C$. Different material properties of the Mark III CCS plate at these temperature levels are considered in the FE model. Using the developed FE model, strength assessment procedure is developed incorporating various anisotropic failure criteria such as Hashin, Hill, Hoffman, Maximum stress and Tsai-Wu. The strength assessment is performed within the initial failure state of the Mark III CCS plate and, as a result, failure details such as failure locations and loads are identified.