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Investigating the use of wollastonite micro fiber in yielding SCC

  • Sharma, Shashi Kant;Ransinchung, G.D.;Kumar, Praveen
    • Advances in concrete construction
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    • v.6 no.2
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    • pp.123-143
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    • 2018
  • Self compacting concrete (SCC) has good flowability, passability and segregation resistance because of voluminous cementitious material & high coarse aggregate to fine aggregate ratio, and high free water availability. But these factors make it highly susceptible to shrinkage. Fibers are known to reduce shrinkage in concrete mixes. Until now for conserving cement, only pozzolanic materials are admixed in concrete to yield a SCC. Hence, this study compares the use of wollastonite micro fiber (WMF), a cheap pozzolanic easily processed raw mineral fiber, and flyash in yielding economical SCC for rigid pavement. Microsilica was used as a complimentary material with both admixtures. Since WMF has large surface area ($827m^2/kg$), is acicular in nature; therefore its use in yielding SCC was dubious. Binary and ternary mixes were constituted for WMF and flyash, respectively. Paste mixes were tested for compatibility with superplasticizer and trials were performed on a normal concrete mix of flexural strength 4.5 MPa to yield SCC. Flexural strength test and restrained shrinkage test were performed on those mixes, which qualified self compacting criteria. Results revealed that WMF admixed pastes have high water demand, and comparable setting times to flyash mixes. Workability tests showed that 20% WMF with microsilica (5-7.5%) is efficient enough in achieving SCC and higher flexural strength than normal concrete at 90 days. Also, stress rate due to shrinkage was lesser and time duration for final strain was higher in WMF admixed SCC which encourages its use in yielding a SCC than pozzolanic materials.

Density Distributions of Metallic Compounds in Particulate Matters (粒子狀 物質中 金屬成分의 密度分布)

  • 허문영;김형춘;손동헌
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.2
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    • pp.9-18
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    • 1986
  • For identification and apportionment of sources emitting particulate matters in environment, the multi-elemental characterization of size-density fractionated particulate matters was carried out. Eight types of samples were tested; soil, flyash released from burning of bunker-Coil, diesel oil, coal, and soft coal, urban road-way dust, urban dust fall, and airborne particulate matter. The fractions of particulate matters obtained by heavy liquid separation methos with a series of dichloromethane-bromoform were then analyzed using atomic absorption spectrophotometry for Ni, Cr, Cu, An, Fe, Al, and Mg. Each sample showed a different concentration profile as a function of density, and a number of useful conclusions concerning characterization of elemental distribution were obtained. From the density distributions of elements in soil, the maximum value was found for all elements in the density range of 2.2 $\sim 2.9g.cm^{-3}$, including the density of $SiO_2$. However, the distribution of metallic compounds with the density lower than $2.2g.cm^{-3}$ was prevalent in urban roadway dust, urban dust fall, and airborne particulate matter. And the density distribution curves of these urban dusts also have the higher distribution at the density of 2.2 - 2.9g.cm^{-3}$, including the density of wind-blown silica. This tendency generally was prevalent in the natural source elements, such as Al, Fe, Mn, and Mg. The maximum values were found in the density ranges of 1.3 $\sim 2.2g.cm^{-3}$ from the density distribution of elements in oil fired flyash. These distributions of anthropogenic source elements, such as Zn, Ni, Cu, and Cr were higher predominately than those of natural source elements. And the higher distribution was found in the density range of $2.2 \sim 2.9g.cm^{-3}$ from the density distribution of elements in coal and soft-coal fired flyash. These distributions showed similar patterns to soil. But anthropogenic source elements somewhat predominated at the density ranges of $1.3 \sim 2.2g.cm{-3} and 2.9g.cm^{-3}$ to soil. Therefore the higher distribution of anthropogenic source elements in the density ranges of $1.3 \sim 2.2g.cm^{-3} and 2.9g.cm^{-3}$ was considered as anthropogenic origin.

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Application of ASTM C 1260 for Cement Matrix Mixed with FlyAsh and Lithium Nitrate (플라이애시와 질산리튬을 사용한 시멘트 경화체의 ASTM C 1260 적용성 검토)

  • Kim, Seong-Kwon;Yun, Kyong-Ku;Hong, Seung-Ho;Kang, Moon-Sik
    • International Journal of Highway Engineering
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    • v.14 no.3
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    • pp.1-7
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    • 2012
  • The purpose of this study was to review application of ASTM C 1260 for cement matrix with flyash and lithium nitrate using reactive aggregate. The experimental program included the accelerated mortar bar test (AMBT: ASTM C 1260) for the slate which was evaluated as reactive aggregate by ASTM C 1260 at the previous study. The cement, which was substituted by 10, 20, 30% flyash containing less than 10% CaO, could control ASR expansion. From the experiment applying lithium nitrate to control ASR, the mortar bar containing lithium nitrate showed more than 0.1% expansion at 14 days. This is probably due to dissolution of lithium nitrate in NaOH solution during test periods. Thus, it is necessary to adopt another test method to verify the control effect of lithium nitrate against alkali-silica reaction.

Dynamic response of a laminated hybrid composite cantilever beam with multiple cracks & moving mass

  • Saritprava Sahoo;Sarada Prasad Parida;Pankaj Charan Jena
    • Structural Engineering and Mechanics
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    • v.87 no.6
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    • pp.529-540
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    • 2023
  • A novel laminated-hybrid-composite-beam (LHCB) of glass-epoxy infused with flyash and graphene is constructed for this study. The conventional mixture-rule and constitutive-relationship are modified to incorporate filler and lamina orientation. Eringen's non-local-theory is used to include the filler effect. Hamilton's principle based on fifth-order-layer-wise-shear-deformation-theory is applied to formulate the equation of motion. The analogous shear-spring-models for LHCB with multiple-cracks are employed in finite-element-analysis (FEA). Modal-experimentations are conducted (B&K-analyser) and the findings are compared with theoretical and FEA results. In terms of dimensionless relative-natural-frequencies (RNF), the dynamic-response in cantilevered support is investigated for various relative-crack-severities (RCSs) and relative-crack-positions (RCPs). The increase of RCS increases local-flexibility in LHCB thus reductions in RNFs are observed. RCP is found to play an important role, cracks present near the end-support cause an abrupt drop in RNFs. Further, multiple cracks are observed to enhance the nonlinearity of LHCB strength. Introduction of the first to third crack in an intact LHCB results drop of RNFs by 8%, 10%, and 11.5% correspondingly. Also, it is demonstrated that the RNF varies because of the lamina-orientation, and filler addition. For 0° lamina-orientation the RNF is maximum. Similarly, it is studied that the addition of graphene reduces weight and increases the stiffness of LHCB in contrast to the addition of flyash. Additionally, the response of LHCB to moving mass is accessed by appropriately modifying the numerical programs, and it is noted that the successive introduction of the first to ninth crack results in an approximately 40% to 120% increase in the dynamic-amplitude-ratio.

The Effect of Delayed Compaction on Unconfined Compressive Strength of Soil-Cement Mixtures (지연다짐이 Soil-Cement의 압축강도에 미치는 영향)

  • 정일웅;김문기;도덕현
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.28 no.4
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    • pp.66-76
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    • 1986
  • This study was attempted to investigate the effects of delayed compaction on the unconfined compressive strengh and dry density of Soil-cement mixtures. Soil-cement construction is a time-consuming procedure. Time-delay is known as a detrimental factor to lower the quality of soil-cement layer. A laboratory test was performed using coarse and fine weathered granite soils. The soils were mixed with 7% cement at optimum moisture content and excess moisture content in part. Socondary additives such as lime, gypsum-plaster, flyash and sugar were tried to counteract the detri-mental effect of delayed compaction. The specimens were compacted by Harvard Miniature Compaction Apparatus at 0,1,2,4,6 hors after mixing. Two kinds of compactive efforts(9 kgf and 18 kgf tamper) were applied. The results were summarized as follows: 1.With the increase of time delay, the decrease rate of dry density of the specimen compacted by 9 kgf tamper was steeper than that of the specimen compacted by 18kgf tamper. In the same manner, soil-B had steeper decreasing rate of dry density than soil-A. 2.Based on the results of delayed compaction tests, the dry density and unconfined compressive sterngth were rapidly decreased in the early 2 hours delay, while those were slowly decreased during the time delay of 2 to 6 hours. 3.The dry density and unconfined compressive strength were increased by addition of 3% excess water to the optimum moisture content during the time delay of 2 to 6 hours. 4.Without time delay in compaction, the dry densities of soil-A were increased by adding secondary additives such as lime, gypsum-plaster, flyash and sugar, on the other hand, those of soil-B were decreased except for the case of sugar. 5.The use of secondary additives like lime, gypsum-plaster, flyash and sugar could reduce the decrease of unconfined compressive strength due to delayed compaction. Among them, lime was the most effective. 6.From the above mentioned results, several recommendations could be suggested in order to compensate for losses of unconfined compressive strenght and densit v due to delayed compaction. They are a) to use coarse-grained granite soil rather than fined-grained one, b) to add about 3% excess compaction moisture content, c) to increase compactive effort to a certain degree, and d) to use secondary additives like line gypsum-plaster, flyash, and sugar in proper quantity depending on the soil types.

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Utilization of Fly Ash as a Source of Mineral Fertilizers III. Boron Phyto-toxicity (Flay Ash 비료화(肥料化) 연구(硏究) III. Flay ash의 붕소(硼素) 독성(毒性))

  • Shin, Jae-Sung;Lim, Dong-Kyu;Seong, Ki-Seog
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.4
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    • pp.299-303
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    • 1993
  • This study was conducted to evaluate the boron phyto-toxicity on soybean grown on the potted soil amended with 20% by weight of fly ash with high and medium boron contents Of two years experiment, the first year experiment observed the direct effect and the 2nd year experiment the residual effect. Soybean growth and yield were normal with incorporation of 20% fly ash with normol B content. With high B flyash, however, the performance of soybean was poor due to B toxicity. Therefore, it is suggested that in determining the application rate of flyash, B content should be taken in account.

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A Study on Reaction Characteristics of Stabilized Red Yellow Soil with Flyash (적황색토와 프라이애쉬 안정처리토의 반응특성)

  • 정두영;이병석;이광준
    • Journal of the Korean Geotechnical Society
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    • v.17 no.2
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    • pp.59-72
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    • 2001
  • 적황색토와 플라이애쉬의 혼합비율에 증가에 따라 건조밀도도 증가하며 최적함수비는 감소하는 경향이고 2차 첨가재인 소석회 및 시멘트 첨가에 의한 건조밀도의 증가는 보이나 처리토의 경량화의 범위는 1:03~1:0.5 정도임을 확인할 수 있었다. 프라이애쉬의 혼합비율이 증가해도 프라이애쉬의 고유산화칼슘(CaO)의 함유량이 적으면 유리산화칼슘의 증가도 크지 않으나, 2차 첨가재인 소석회 및 시멘트 첨가량의 증대에 따라 증가한다. 이는 첨가재에 의한 수화반응의 증가로 확인되며, 본 처리토는 Ion 교환작용과 Pozzolan 반응 생성물인 규산칼슘석회수화물(5CaO.6SiO$_2$.5$H_2O$, Tobermorite)과 알민산유산석회수화물(3CaO.Al$_2$O$_3$.3CaSO$_4$.32$H_2O$, Ettringite)가 주된 반응생성물이며 확인된 알민산유산석회수화물(Ettringite)의 회절 X-선 강도는 2차 첨가재의 첨가에 따른 수화반응으로 수화물은 점차 증가하며 상대적으로 일축압축강도도 상응한 강도발현을 하여 고결화 효과에 기여하고 있음을 보여준다.

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A study on the engineering optimization for the commercial scale coal gasification plant (상용급 석탄가스화플랜트 최적설계에 관한 연구)

  • Kim, Byeong-Hyeon;Min, Jong-Sun;Kim, Jae-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.131.1-131.1
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    • 2010
  • This study was conducted for engineering optimization for the gasification process which is the key factor for success of Taean IGCC gasification plant which has been driven forward under the government support in order to expand to supply new and renewable energy and diminish the burden of the responsibility for the reduction of the green house gas emission. The gasification process consists of coal milling and drying, pressurization and feeding, gasification, quenching and HP syngas cooling, slag removal system, dry flyash removal system, wet scrubbing system, and primary water treatment system. The configuration optimization is essential for the high efficiency and the cost saving. For this purpose, it was designed to have syngas cooler to recover the sensible heat as much as possible from the hot syngas produced from the gasifier which is the dry-feeding and entrained bed slagging type and also applied with the oxygen combustion and the first stage cylindrical upward gas flow. The pressure condition inside of the gasifier is around 40~45Mpg and the temperature condition is up to $1500{\sim}1700^{\circ}C$. It was designed for about 70% out of fly ash to be drained out throughout the quenching water in the bottom part of the gasifier as a type of molten slag flowing down on the membrane wall and finally become a byproduct over the slag removal system. The flyash removal system to capture solid particulates is applied with HPHT ceramic candle filter to stand up against the high pressure and temperature. When it comes to the residual tiny particles after the flyash removal system, wet scurbbing system is applied to finally clean up the solids. The washed-up syngas through the wet scrubber will keep around $130{\sim}135^{\circ}C$, 40~42Mpg and 250 ppmv of hydrochloric acid(HCl) and hydrofluoric acid(HF) at maximum and it is turned over to the gas treatment system for removing toxic gases out of the syngas to comply with the conditions requested from the gas turbine. The result of this study will be utilized to the detailed engineering, procurement and manufacturing of equipments, and construction for the Taean IGCC plant and furthermore it is the baseline technology applicable for the poly-generation such as coal gasification(SNG) and liquefaction(CTL) to reinforce national energy security and create new business models.

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A Study on Rainfall-induced Erosion of Land Surface on Reinforced Slope Using Soil Improvement Material (지반 개량재에 의한 보강사면의 강우시 표면침식에 관한 연구)

  • Kim, You-Seong;Kim, Jae-Hong;Bhang, In-Hwang;Seo, Se-Gwan
    • Journal of the Korean Geotechnical Society
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    • v.29 no.1
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    • pp.49-59
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    • 2013
  • Heavy rainfall intensity may cause shallow slope failures and debris flow by rill erosion and scour on land surface. The paper represents the difference between native soil (weathered soil) and reinforced soil, which is mixed by hardening agent with flyash as main material, for investigating experimental findings of rill erosion and erosion. Results obtained from artificial rainfall simulator show that erosion rate of reinforced soil mixed with hardening agent is reduced by 20% because an amount of eroded soil on slope surface is inversely proportional to the increase of soil strength. For example, rainfall of 45mm (at the elapsed time of 25mins in rainfall intensity of 110mm/hr) triggers rill erosion on native soil surface, but the rill erosion on reinforced soil surface does not even occur at 330mm rainfall (at the elapsed time of 3hrs in rainfall intensity of 110mm/hr). As a result of slope stability analysis, it was found that the construction method for reinforced soil surface would be more economical, easy and fast construction technology than conventional reinforcement method.