• Title/Summary/Keyword: fly ashes

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Overview on The Measurement Methods of Unburned Carbon Contents in Coal Fly-Ash (석탄 비산회(Fly-Ash)의 미연탄소 함량 측정방법에 대한 고찰)

  • Hong, EunPyo;Kim, Jung Hyeun
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.131-136
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    • 2014
  • The importance of waste treatments is increasing because of the lack of resources and environmental problems resulted from economic growth policy. Especially, the pollutant dust which is one of the wastes should be treated considerately because it could cause secondary damages on the human health as well as environmental systems. Recently, massive amount of coal fly-ash is being produced in thermoelectric power plants. In this study, we compared two general methods used in estimating the amount of unburned carbon in fly-ashes to categorize the coal fly-ashes into several groups following their carbon contents. One is the "loss on ignition(KS L 5405) method" which estimates the change of mass after combustion, and it is generally used. Another one is measuring $CO_2$ gas content by burning solid carbon in the fly-ash, and it is called "$CO_2$ analysis method."

The pilot study on reclamation of incineration ashes of municipal waste in the demonstrative factory

  • Chang Hui-Lan;Liaw Chin-Tson;Leu Ching-Huoh
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.573-580
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    • 2003
  • In Taiwan there are 21 Municipal Solid Waste Incinerators (MSWI) built to treat 80% of the MSW nationwide. Approximately 2,000 tons of incineration ashes of municipal waste contain reaction ash and fly ash (3:1 by weight)will be produced daily, and this may cause a serious waste problem. According to EPA regulations, reaction ash and fly ash produced after incineration should be properly treated. Landfill capacity barely meets the general demands. More efficient actions should be planned and taken. The study found 'reclamation' should be the optimal solution to this problem. Only limited research and previous successful experiences are available among other countries. An incinerator in Northern Taiwan is chosen for this study to make environmental bricks from the reaction ash and fly ash. From the previous tests, the results of strength test were measured. From the previous test results, the fly ash products have not reached the desired strength; hence, reaction ash is chosen for further pilot study. In the experiment, incineration ashes, cement and gravel are mixed in the ratio of 1:1:1(by weight), to ground concretization aggregate and pelletization aggregate, the concrete products made from the aggregates were of the strength of 108 $kgf/cm^2$ and 142 $kgf/cm^2$ individually. For the purpose of making nonstructural walls which met the State Building Standards. In the study, 50 tons of concrete products was yielded from aggregate and environmental bricks. Further observation and supervision are recommended to ascertain the resource recycling and reclamation. EPA has planned to build three 'Recycling Plants' in northern, middle and southern Taiwan to develop efficient techniques to produce concrete products, sub-base course, soundproofing wall, gravel, artificial fishing reefs, tiles, drainage, bricks and etc. This experiment of the demonstrative plant solves the problem of the incineration ashes and opens another opportunity to reclaim them.

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Basic characteristic of non-sintered binder using by CFBC ash (순환유동층 보일러애시를 활용한 비소성 결합재 기초 특성)

  • Kang, Yong-Hak
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.225-226
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    • 2017
  • Recently, there has been a growing interest in the development of non-sintered binder to reduce CO2 emissions from the cement clinker manufacturing process and a number of studies have been conducted on fly ashes as an industrial by-product. However, in order to utilize fly ashes as a non-sintered binder, it is necessary to solve problems such as safety issues and economical efficiency due to use of an alkali activator. This study evaluates the material properties and compressive strength characteristics of three types of circulating fluidized bed boiler ashes. As a result, it was confirmed that the characteristics of each binder vary depending on the location of the power plant and the types of raw materials. In addition, it has been confirmed that the fluidized bed boiler ash shows a high compressive strength and can be used sufficiently as an non-sintered binder.

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The Proper Mixing Ratio of Fly Ash to Bottom Ash for Use of Highway Embankment and Subgrade Materials (석탄회의 도로성토재 및 노상재로서의 활용을 위한 비회와 저회의 적정혼합비)

  • Chun, Byung Sik;Koh, Yong Il
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.1
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    • pp.177-186
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    • 1992
  • In this study, the proper mixing ratio of fly ash to bottom ash is evaluated and bearing capacity of this mixed ash is examined for use of highway embankment and subgrade materials in large quantities. Independently of the mixing ratio of fly ash to bottom ash or the method of compaction test, maximum dry density ${\gamma}_{dmax}$ and CBR value of anthracite mixed coal ash is greater than that of bituminous mixed coal ash. The mixed ashes to contain more fly ash than that of which the ratio of fly ash to bottom ash is 8 : 2, are slaked readily when the water contents of compaction are greater than optimum moisture content O.M.C. The proper mixing ratios of fly ash to bottom ash are about 5 : 5 to 6 : 4. Coal ashes mixed with these ratios exhibit proper physical and geotechnical properties for use of highway embankment and subgrade materials, and enable coal ashes to be used in large quantities.

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Physico-chemical Characteristics of Ammonia Adsorbed Fly Ash (AAFA)

  • Kim, Jae-kwan;Park, Seok-un;Hong, Jin-pyo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.39-45
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    • 2018
  • Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.

Study on Fly Ash as a New Raw Material in Paperboard Process (제지용 신규원료 플라이애시의 적용 가능성 평가)

  • Kim, Chul-Hwan;Lee, Ji-Young;Lee, Hui-Jin;Gwak, Hye-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.4
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    • pp.78-83
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    • 2010
  • In this study, the possibility of the use of a new raw material in paperboard industry was investigated. Fly ash is one of the residues generated in the combustion of coal and generally captured from the chimney of coal-fired power plant. This material is utilized in many industries including cement, soil stabilization, composite etc., but it is not used in paper industry. Three types of fly ashes were collected from Hadong, boryeong and Seocheon steam power plants and we investigated their properties by scanning electron micrographs and particle size distribution. Papers were manufactured with KOCC and fly ashes, and the physical properties such as bulk, tensile strength, internal bond strength and ISO brightness were measured to identify the effects of fly ash on the paper properties.

Utilization of Fly Ash as a Source of Mineral Fertilizers -I. Mineralogical Characteristics (Fly ash 비료화(肥料化) 연구(硏究) -I. Fly ash의 광물학적(鑛物學的) 특성(特性))

  • Shin, Jae-Sung;Seong, Ki-Seog;Kim, Maun-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.309-314
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    • 1987
  • This study was conducted to examine mineralogical aspects on anthractite and bituminous coal-fired power-plant ashes as a source of mineral fertilizer. Fly ashes contain dominant amounts of silica and alumina and considerable quantitites of potassium and boron. However, potassium and silica present in unavailable forms for plant growth. X-ray, DTA, and IR analysis of ash particles indicated the formation of new mineral, mullite with shape of which were spherical in the surface morphologies of SEM. Detailed SEM investigation showed the presence of imbedded blocky shape silicate material.

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Properties of Ground Solidification Materials using Vietnam CFBC Fly Ash (베트남 CFBC 플라이애시를 사용한 지반고화재의 특성)

  • Kim, Keeseok;Lee, Jaewon;Lee, Dongwon;Yu, Jihyung;Hoang, Truong Xuan;Minh, Ha;Min, Kyongnam
    • Resources Recycling
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    • v.27 no.3
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    • pp.39-47
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    • 2018
  • According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.

Effect of Properties of Fly-ashes on the Characteristics of Fly-ash Mortars (플라이애시 종류에 따른 플라이애시 모르타르의 특성에 대한 연구)

  • Kim, Joo-Hyung;Park, Byoung-Sun;Jung, Sang-Hwa;Choi, Young-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.439-445
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    • 2016
  • Recently, a large number of researches about concrete containing high volume fly-ash(HVFA) have been carried to obtain carbon dioxide reduction, resource recycle and durable option in concrete industry. The quality of fly-ash such as chemical composition and fineness has high variability due to the differences of used fuels, operation condition in power plant. The aim of this study is to investigate the performances of fly-ash cement mortar containing different type of fly-ashes. The basic analysis of fly ash such as chemical composition, SEM image analysis were performed. Many mortar specimens were fabricated to evaluate the properties (compressive strength, drying shrinkage and carbonation) of mortar with various fly ash. From the test results, the quality of each fly ash must be considered and fully weighted in fly ash concrete.

Manufacturing of Artificial Lightweight Aggregates using a Coal Fly Ash Discharged from Fluidized Bed Combustor (유동층(流動層) 연소기(撚燒器)로 부터 발생(發生)된 석탄(石炭) 비산(飛散)재를 이용(利用)한 인공경량골재(人工輕量骨材) 제조(製造))

  • Kang, Min-A;Kang, Seung-Gu
    • Resources Recycling
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    • v.20 no.1
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    • pp.54-60
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    • 2011
  • The spherical artificial aggregates (AAs) with a diameter of 8 mm, which contains fly ashes discharged from the fluidized bed combustion in a thermal power plant and clay were manufactured by direct sintering method at $1050{\sim}1250^{\circ}C$ for 10 minutes. The effect of fly ash contents on the bloating phenomenon in the AAs was analyzed. The AAs containing fly ash of the amount under 50 wt% showed the black-coring and bloating phenomena. The AAs containing fly ash of the amount over 5Owt%, however, the specific gravity was increased and the color of specimens fully changed to black. These color change phenomena were caused from the formation of FeO by the reduction reaction of almost $Fe_2O_3$ component by the excessive reducing atmosphere formed simultaneously with the rapid emission of the gases generated from the high contents of unburned carbon of with increasing the added fly ash amount. Specific gravity was decreased as fly ash contents increased in the case of sintering at the same temperature condition. Water absorption of all specimens except of the specimens containing 10 wt% fly ashes decreased with increasing sintering temperature. These were because a liquid phase was formed as the increasing the sintering temperature. In the case of the specimens manufactured in this study containing fly ashes discharged from the fluidized bed combustor in a the thermal power plant and 10~90 wt% of clay, the specific gravity was 0.9~1.8 and the water absorptivity was 8~60%, therefore it is considered that those results can be applied to the light or heavy aggregates.