• 한국재료학회지
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• 제9권5호
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• pp.503-508
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• 1999

We have investigated the physical and diffusion barrier property of Ti-Si-N film for Cu metallization. The ternary compound was deposited by using reactive rf magnetron sputtering of a TiSi$_2$target in an Ar/$N_2$gas mixture. Resistivities of the films were in range of 358$\mu$$\Omega$-cm, to 307941$\mu$$\Omega$-cm, and tended to increase with increasing the $N_2$/Ar flow rate ratio. The crystallization of the Ti-Si-N compound started to occur at 100$0^{\circ}C$ with the phases of TiN and Si$_3$N$_4$identified by using XRD(X-ray Diffractometer). The degree of the crystallization was influenced by the $N_2$/Ar flow ratio. The diffusion barrier property of Ti-Si-N film for Cu metallization was determined by AES, XRD and etch pit by secco etching, revealing the failure temperature of 90$0^{\circ}C$ in 43~45at% of nitrogen content. In addition, the very thin compound (10nm) with 43~45at% nitrogen content remained stable up to $700^{\circ}C$. Furthermore, thermal treatment in vacuum at $600^{\circ}C$ improved the barrier property of the Ti-Si-N film deposited at the $N_2$(Ar+$N_2$) ratio of 0.05. The addition of Ti interlayer between Ti-Si-N films caused the drastic decrease of the resistivity with slight degradation of diffusion barrier properties of the compound.

• 설비공학논문집
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• 제20권1호
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• pp.49-56
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• 2008

When the outdoor air temperature decreased less than the freezing temperature, frost forms at the surface of heat exchangers and it makes the performance degradation of a heat pump system. In this study, a heat pump system has been developed which has a refrigerant heating device as an auxiliarly heating equipment. To reduce power consumptions of the system, a liquid pump, rather than a compressor, was used to drive refrigerant in the heat pump cycle. Ratio of refrigerant mass flow between a refrigerant heating heat exchanger(GHX) and a outdoor plate heat exchanger(PHX) was varied and the system performance was measured and analyzed. As results, when the refrigerant flow rate to the GHX was decreased, the system performance is decreased due to heat absorption capability restriction of the GHX and small variation of the power consumption in the compressor. The effect on the evaporating and condensing pressure by the distribution ratio of the refrigerant to the each heat exchanger is small compare to the effect by the frequency change in the compressor. When the compressor was replaced by the liquid pump, the capacity of the system decreased a little, however the power consumption decrease approximately 80% compare with the power used in the compressor.

• 공업화학
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• 제16권6호
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• pp.800-808
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• 2005

미생물에 의해 분해되는 랩제조용 복합수지를 개발하고, 이에 대한 제조과정과 물성에 대하여 연구하였다. 이런 목적을 위해 원재료 수지, 산화제, 활제의 종류와 사용량 등 같은 몇 가지 조건을 최적화하였다. 생분해성 랩을 제조하기 위한 복합수지는 polyester 계열에서 PBAS (아디프산, 숙신산 및 1.4-부탄디올의 3성분 공중합체)와 PBAST (숙진산, 아디프산, 디메틸테레프탈레이트 및 1.4-부탄디올의 4성분 공중합체)를 이용하였다. 또한 PBAS에서는 1차 산화방지제로는 Irganox 1010과 1076 (0.1 phrs), 2차 산화방지제로는 Irgafos TNPP (0.2 phrs), PBAST에서는 1차 산화방지제로 Irganox 1076 (0.1 phrs), 2차 산화방지제로 Mark PEP 36 (0.3 phrs)이 가장 좋았다. 수지의 가공성 향상을 위해서 사용하는 활제로는 PBAS에서는 glycerol monostearate, PBAST에서는 palmityl alcohol를 각각 0.8%와 1.0%를 사용하면 충분하였다. 제조된 랩의 안정성은 중금속 용출실험과 UTM을 이용한 인장강도 및 신축률을 측정하여 평가하였다. 시제품에 대한 분해률을 측정하기 위해서 동일 조건의 토양에 매립하여 시간경과에 따른 분해정도를 비교한 결과 40일 정도가 경과하면 약 60%가 분해하는 것으로 나타났다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2007년도 제29회 추계학술대회논문집
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• pp.297-301
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• 2007

초음속 충동형 터빈과 같이 종횡비가 작은 경우 로터 익형은 반경방향으로 동일한 단면을 갖는 형태로 구현된다. 이 경우 터빈 로터는 터빈 동익의 프로파일 직경에 따라 설계에서 의도하지 않은 유로면적분포와 터빈 성능의 차이를 보인다. 본 연구에서는 터빈 동익 프로파일을 정의하는 직경이 터빈 성능에 미치는 영향을 고찰하기 위하여 3개의 다른 위치에서 정의된 터빈 로터에 대한 유동해석을 수행하고 결과를 고찰하였다. 계산 결과 팁에서 단면이 정의된 경우 설계에서 의도한 유로면적 변화를 보이며 다른 프로파일 직경에서 정의된 터빈에 비해 우수한 성능을 보임을 확인하였다.

• Computers and Concrete
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• 제4권5호
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• pp.377-402
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• 2007

The paper presents quasi-static plane strain FE-simulations of strain localization in reinforced concrete beams without stirrups. The material was modeled with two different isotropic continuum crack models: an elasto-plastic and a damage one. In case of elasto-plasticity, linear Drucker-Prager criterion with a non-associated flow rule was defined in the compressive regime and a Rankine criterion with an associated flow rule was adopted in the tensile regime. In the case of a damage model, the degradation of the material due to micro-cracking was described with a single scalar damage parameter. To ensure the mesh-independence and to capture size effects, both criteria were enhanced in a softening regime by nonlocal terms. Thus, a characteristic length of micro-structure was included. The effect of a characteristic length, reinforcement ratio, bond-slip stiffness, fracture energy and beam size on strain localization was investigated. The numerical results with reinforced concrete beams were quantitatively compared with corresponding laboratory tests by Walraven (1978).

• International Journal of Air-Conditioning and Refrigeration
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• 제9권2호
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• pp.19-27
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• 2001

In the present study, the effects of film Reynolds number (60∼200) and volumetric content of non-absorbable gases (0∼10%) in water vapor on the absorption process of aqueous LiBr solution were investigated experimentally. The formation of solution film on the horizontal tubes of six rows was observed to be complete for Re>100. Transition film Reynolds number was found to exist above which the Nusselt number and Schmidt number diminishes with solution flow rate. As the concentration of non-absorbable gases increased, mass transfer rate decreased more seriously than heat transfer rate did. the degradation effects of non-absorbable gases seemed to be significant especially when small amount of non-absorbable gases was introduced to the pure water vapor.

• Food Science and Biotechnology
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• 제15권4호
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• pp.555-558
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• 2006

The chemical reduction of Pseudomonas syringae subsp. phaseolicola alginates produces neutral polymers of D-mannose and L-gulose in source specific ratios. L-Gulose was highly sensitive to degradation by 1N HCl at $100^{\circ}C$. As hydrolysis time increased, gulose recovery decreased to 22% after 4 hr, whereas 98% of the D-mannose was recovered under the same conditions. Thin layer chromatography showed the formation of a second product upon L-gulose acid hydrolysis. This new product had a rate of flow (Rf) value of 0.58, identical to that of 1,6 anhydro-${\beta}$-D-mannopyranose and very close to that of 1,6 anhydro-${\beta}$-D-glucopyranose (Rf=0.60). Because of the difference in acid sensitivity between L-gulose and D-mannose, normal acid hydrolytic techniques applied to reduced alginates produces erroneous mannuronic acid (M): guluronic acid (G) ratio's unless one accounts for the differential rates of destruction of each sugar.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.257-258
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• 2022

In this study, as a part of the study to alleviate the durability degradation due to low tensile performance and cracking of concrete, two kinds of catechol functional chitosan (Cat-Chit) were replaced at a ratio of 5, 10, 15, 20% as a mixed water substitute to evaluate the fluidility and strength characteristics of mortar.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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• pp.131-134
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• 2005

Anaerobic reductive dechlorination of tetrachloroethylene(PCE) to ethylene was investigated by performing laboratory experiments using semi-continuous flow two-in-series soil columns. The columns were packed with soils obtained from TCE-contaminated site in Korea. Site ground water containing lactate(as electron donor and/or carbon source) and PCE was pumped into the soil columns. During the first operation with a period of 50 days, injected mass ratio of lactate and PCE was 620:1 and incomplete reductive dechlorination of PCE to cis-DCE was observed in the columns. However, complete dechlorination of PCE to ethylene was observed when the mass ratio increased to 5,050:1 in the second operation, suggesting that the electron donor might be limited during the first operation period. During the degradation of cis-DCE to ethylene, the concentration of hydrogen was $22{\sim}29mM$. These positive results indicate that the TCE-contaminated groundwater investigated in this study could be remediated through biological anaerobic reductive dechlorination processes.

• Computers and Concrete
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• 제29권 5호
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• pp.323-334
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• 2022

In order to study the axial compression performance of basalt-fiber reinforced recycled concrete (BFRRC) filled circular steel tubular short columns, the axial compression performance tests of seven short column specimens were conducted to observe the mechanical whole-process and failure mode of the specimens, the load-displacement curves and the load-strain curves of the specimens were obtained, the influence of design parameters on the axial compression performance of BFRRC filled circular steel tubular short columns was analyzed, and a practical mathematical model of stiffness degradation and a feasible stress-strain curve equation for the whole process were suggested. The results show that under the axial compression, the steel tube buckled and the core BFRRC was crushed. The load-axial deformation curves of all specimens show a longer deformation flow amplitude. Compared with the recycled coarse aggregate (RCA) replacement ratio and the basalt fiber dosage, the BFRRC strength has a great influence on the peak bearing capacity of the specimen. The RCA replacement ratio and the BFRRC strength are detrimental to ductility, whereas the basalt fiber dosage is beneficial to ductility.