• Title/Summary/Keyword: flash flame

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Study on PAN-based carbon fibers containing cellulose treated with flame retardant (난연 처리한 셀룰로오스가 첨가된 PAN계 탄소섬유의 특성 연구)

  • Yang, Jee-Woo;Yu, Jae-Jeong;Yong, Da-Kyung;Chung, Yong-Sik;Lee, Seung-Goo
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.75-75
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    • 2012
  • 탄소섬유는 전구체의 종류에 따라 PAN계, 피치계 그리고 레이온계로 나뉘며 최종 탄소섬유의 특성에도 차이가 있는 것으로 알려져 있다. 최근에는 PAN계 탄소섬유가 세계 시장의 대부분을 차지하고 있으며, PAN계 탄소섬유의 초경량, 고강도, 고탄성, 내약품성 그리고 열안정성 등의 우수한 특성으로 최첨단 고기능성 제품의 복합재로 많이 이용되고 있다. 그러나 탄소섬유가 가지고 있는 높은 열전도성은 적용에 따라 단점으로 작용될 수도 있다. 예를 들면, 로켓 엔진의 노즐이나 원자로의 구조물 그리고 극한조건용 구조재료 등, 고강도 단열특성을 요하는 최첨단 복합재로 응용 범위를 넓히는데 한계로 작용한다. 레이온은 최초의 탄소섬유 전구체였으나 공정상 경제성이 떨어지는 이유로, 지금은 고탄성을 요구하는 특수 목적으로만 소량 생산되고 있다. 레이온의 주원료는 셀룰로오스이며 셀룰로오스는 지구상에서 가장 흔한 재료이므로 오늘날 셀룰로오스를 보강재로 이용하려는 연구가 활발히 진행되고 있다. 본 연구에서는 탄소섬유의 열전도도를 낮추기 위한 방법으로 안정화셀룰로오스를 첨가한 PAN용액을 출발물질로 탄소섬유를 제조하고 특성 연구를 진행하였다. PAN용액에 셀룰로오스의 분산성을 향상시키기 위해 셀룰로오스를 열처리하였다. 이 과정에서 얻어진 안정화 셀룰로오스의 수율을 높이기 위해 셀룰로오스를 난연 처리하였으며, 그 결과 안정화셀룰로오스의 수율을 향상시킬 수 있었다. 안정화셀룰로오스를 첨가시킨 PAN계 탄소섬유의 물리적, 기계적 그리고 열적 특성을 SEM, XRD, 만능 인장시험기, TGA 그리고 Laser Flash Method 등을 통해 주요 특성 및 변화를 관찰한 결과, 순수한 PAN계 탄소섬유의 특성과 유사한 결과를 얻었다. 향후 몇 가지 공정상의 문제점을 개선한다면 흥미로운 결과를 기대할 수 있을 것으로 본다.

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Test Gases for Gas Burning Appliances of New Gas Group (새 가스그룹의 가스기기 시험가스)

  • Ha, Young-Cheol;Kim, Sung-Min;Lee, Chang-Eon;Choi, Kyoung-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.439-444
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    • 2011
  • To determine the test gases for gas appliances of new gas group, the interrelation between gas interchangeability, including thermal efficiency, of 13A gas appliances and present 13A test gases was experimentally investigated. The test results show that the Wobbe indices in the case of incomplete combustion and the flame lifting limit gas for the new gas group are respectively 2% higher than the upper limit and 1% lower than the lower limit of the Wobbe index range. The most suitable composition of R gas is 96 mol% of methane and 4 mol% of propane; LNG could be also used as R gas. Further, analysis results showed that the hydrogen concentration of flash back limit gas could be lowered from 30 vol% to 23 vol%.

Inhibitory Effect of adding Phase Change Material (PCM) to Fire Fighter Protective Clothing on Burn Injuries (Phase Change Material (PCM) 소재 적용 소방보호복의 화상발생 억제효과에 관한 연구)

  • Lee, Jun Kyoung
    • Fire Science and Engineering
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    • v.30 no.3
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    • pp.16-22
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    • 2016
  • Fire fighters rely on fire fighter protective clothing (FFPC) to provide adequate protection in the various hazardous environments. To enhance its protection performance, the FFPC material must be thick and thus it is difficult to achieve weight reduction. One of the methods of overcoming this problem, the addition of phase change material (PCM) to FFPC, is a new technology. In previous studies, the researches was mostly related to the temperature characteristics of the fibers incorporating PCM, but little information is available about its effect on burn injuries. Thus, in this study, the inhibitory effects of adding PCM to FFPC on second degree burns were investigated through numerical calculations. Thermal analyses of biological tissues and FFPC with embedded PCM exposed to several fire conditions causing severe tissue damage were studied by using a finite difference method based on the Pennes bio-heat equation. FFPC with embedded PCM was found to provide significantly greater protection than conventional fire fighting clothing, because the heat of absorption due to the phase change within the material is used to limit the heat conduction of the material.

Characteristics of Multi staged Combustion on a Double-cone Partial Premixed Nozzle (이중 콘형 부분 예혼합 GT 노즐의 다단 연소특성)

  • Kim, Han Seok;Cho, Ju Hyeong;Kim, Min Kuk;Hwang, Jeongjae;Lee, Won June
    • Journal of the Korean Institute of Gas
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    • v.24 no.1
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    • pp.49-55
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    • 2020
  • Experimental investigations were conducted to understand the multi-staged combustion characteristics of a swirl-stabilized double cone premixed burner nozzle used for industrial gas turbines for power generation. Multi-staged combustion is implemented by injecting the fuel through the existing manifold of the side slots as well as through the apex of the cone with two fuel injection angles which are slanted or axial. NOx and CO emissions, and wall temperature distributions were measured for various fuel distributions and operating conditions. Results show that NOx emissions are decreased when the fuel distribution to the apex is 3% of the total amount of fuel, which is due to more uniform fuel distribution inside the nozzle, hence less hot spots at the flame. NOx emissions are rather increased when the fuel distribution to the apex is 8% of the total amount of fuel for axial fuel injection by occurrence of flash back in premixing zone of burner.

Analysis of Development Trends on Bio-based Environmental Transformers Oils in Power Sector (전력분야의 바이오 기반 친환경 전기 절연유 적용에 관한 개발 동향 분석)

  • Kim, Jae-Kon;Min, YoungJe;Kim, Mock-Yeon;Kwark, ByeongSub;Park, Hyunjoo
    • Tribology and Lubricants
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    • v.38 no.2
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    • pp.41-52
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    • 2022
  • Mineral electrical insulating oil, which is widely used in transformers, exhibits excellent cooling performance and transformer efficiency. However, given that it is composed of petroleum-based components, it is weak in terms of biodegradability. This causes environmental problems in case of leakage and a low flash point, which is a factor that would cause great damage in the event of a fire in a substation. In this context, the use of eco-friendly electric insulating oil composed of bio-based vegetable oil and synthetic ester, which has excellent biodegradability and flame retardancy performance, has recently been expanded to the field of electric power, and various research and development (R&D) studies are in progress. According to different research results, vegetable oil and synthetic ester manufacturing technology, thermal stability, oxidation stability, property change, and quality control, which are characteristics of eco-friendly electrical insulating oils, are major factors affecting the maintenance of insulating oil properties. In addition, power companies have established and operated quality control standards according to the use of eco-friendly electrical insulating oil as they expand the exploitatoin of renewable energy in electricity production. In particular, deterioration and oxidation characteristics were jointly identified in R&D as an important influencing factor according to the content of saturated and unsaturated fatty acids present in vegetable oils and synthetic esters in power transformer applications.

An Experimental Study on Fire Safety Performance of Glass Wool Sandwich Panel (그라스울 샌드위치패널의 화재 안전 성능에 대한 실험적 연구)

  • Kweon, Oh-Sang;Yoo, Yong-Ho;Kim, Heung-Youl;Min, Se-Hong
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.21-27
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    • 2012
  • A real A real scale fire test was performed in accordance with KS F ISO 9705 test method to investigate the combustion characteristics of glass wool sandwich panels. To do this, six kinds of specimens having different density and thickness were examined. The glass sandwich panels were installed inside the room, which had internal dimensions of 2.4 m wide${\times}3.6m$ deep${\times}2.4m$ high. also, combustion characteristic are determined through the exposure of specimens to flame by the propane gas burner has a capacity of 100 kW (10 minutes) and 300 kW (10 minutes) for total 25 minutes of test time. Results of the real sale fire test, it was found that maximum HRR of each specimen was 333.2~365.5 kW, maximum heat flux was 12.4~12.9 kW/$m^2$ And, maximum internal temperature for all specimens was not over $500^{\circ}C$. During the real scale fire test, flash-over didn't occur and the difference by density and thickness of specimen was not found from the results of HRR, heat flux, and internal temperature measurement.