• Title/Summary/Keyword: flammable

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THE NUMERICAL SIMULATION OF HYDROGEN JET DIFFUSION FOR HYDROGEN LEAKAGE IN THE ENCLOSED GEOMETRY (밀폐공간에서 수소 누설로 인한 수소 제트 확산에 대한 수치해석)

  • Ahn, Hyuk-Jin;Lee, Sang-Hyuk;Hur, Nahm-Keon;Lee, Moon-Kyu;Yong, Gee-Joong
    • 한국전산유체공학회:학술대회논문집
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    • 2009.04a
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    • pp.176-182
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    • 2009
  • In the present study, a numerical simulation for the diffusion of hydrogen jet in a enclosure was performed to aid the leakage test of the hydrogen for the safety of the hydrogen vehicle. The temporal and spatial distributions of the hydrogen concentration in the test chamber are predicted from the present numerical analyses. Flammable region of 4-74% and explosive region of 18-59% hydrogen by volume was identified from the present results. Factors influencing the diffusion of the hydrogen jet were examined to evaluate the effectiveness of forced ventilation for relieving the accumulation of the leaked hydrogen gas in the chamber, which include location of open windows, size of leakage nozzle, and leakage rate among others. The distribution of the concentration of the leaked hydrogen for various cases can be used as a database in various applications for the hydrogen safety.

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Numerical Analysis of the Extinction and $NO_x$ Emission in Methane/Air Premixed Flame by Hydrogen Addition (메탄/공기 예혼합화염에서의 수소첨가에 의한 소염 및 $NO_x$ 발생특성에 관한 수치해석)

  • Cho, Eun-Seong;Chung, Suk-Ho;Ahn, Kook-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.75-81
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    • 2006
  • Lean premixed combustion is a well known method for low $NO_x$ gas turbine combustor. But lean combustion is usually accompanied by flame instability. To overcome this problem, the hydrogen ($H_2$) was added to main fuel methane to increase flammable limit. In this paper, the effects of hydrogen addition on lean premixed combustion of methane ($CH_4$) were investigated numerically. Results showed that the extinction stretch rate increases and the extinction temperature constant with relatively small amount of $H_2$ addition. The flame temperature and NO emission increase with $H_2$ addition at the same stretch rate and equivalence ratio but it could increase the range of lean extinction and extinction equivalence ratio limit. Eventually, the $H_2$ addition case showed almost same or lower NO emission than no addictive $CH_4$ case in the extinction condition.

A Study on the Combustion Characteristics with Hydrogen Contents of SNG Fuel in Low-Swirl Combustor (저선회 연소기에서 합성천연가스(SNG) 연료의 수소함량에 따른 연소 특성 연구)

  • JEONG, HWANGHUI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.181-189
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    • 2017
  • This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

A Study on the Fluid H in Automotive Air Conditioning System as an Alternative Refrigerant (자동차 공조용 대체 냉매로서의 H냉매에 대한 연구)

  • Choi, Jeong-Won;Nam, Soo-Byeong;Bang, Scott
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.170-176
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    • 2007
  • It is time to prepare the phaseout of R134a, the current refrigerant, in automotive air conditioning system because the EC deadline has been coming with new platform vehicles in 2011 and all vehicles by 2017. Until now a high-pressure carbon dioxide($CO_2$) system is the leading replacement of R134a in European auto-makers but there is no firm agreement in the world automotive market. Recently three new fluids have been announced as the possibilities from Honeywell, DuPont and INEOS Fluor. The new alternative refrigerant should meet the requirements like non flammable, non toxic, no ozone depletion effect and low GWP(under 150 to meet EC regulation). The objectives of this paper are to review the fluid H from Honeywell, the more possible alternative refrigerant in 3 new fluids, compare the properties of R134a & fluid H and see the possibility as a replacement of R134a. In this experimental paper we ran and reviewed the cooling performance data in the bench system, the vehicle and the field test. We found the possibility of fluid H system to meet the R134a system performance with some hardware modifications but agreed that it is still needed to study about the long term safety, environmental effects, material compatibilities and so on.

Measurement and Prediction of Autoignition Temperature of n-Butanol and sec-Butanol System (노말부탄올과 2차부탄올 계의 최소자연발화온도의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.48-53
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    • 2012
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Butanol+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Butanol and sec-Butanol which constituted binary system were $340^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Butanol+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Measurement of Autoignition Temperature of Propionic Acid and 3-Hexanone System (Propionic acid와 3-Hexanone 계의 최소자연발화온도의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.28 no.4
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    • pp.44-49
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    • 2014
  • The autoignition temperaturs (AIT) of solvent mixture is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AIT and ignition delay time for Propionic acid and 3-Hexanone system by using ASTM E659 apparatus. The AITs of Propionic acid and 3-Hexanone which constituted binary system were $511^{\circ}C$ and $425^{\circ}C$, respectively. The experimental AIT of Propionic acid and 3-Hexanone system were a good agreement with the calculated AIT by the proposed equations with a few average absolute deviation (A.A.D.). And Propionic acid and 3-Hexanone system was shown the minimum autoignition temperature behavior (MAITB).

A Study of Minimum Autoignition Temperature Behavior (MAITB) of Benzene and n-Hexane Mixture (벤젠과 노말헥산 혼합물의 최소자연발화온도 거동에 관한 연구)

  • Ha, Dong-Myeong;Kim, Kyu-Hyun
    • Fire Science and Engineering
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    • v.27 no.1
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    • pp.8-13
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    • 2013
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for Benzene and n-Hexane system by using ASTM E659 apparatus. The AITs of Benzene and n-Hexane which constituted binary system were $583^{\circ}C$ and $240^{\circ}C$, respectively. The experimental AITs of Benzene and n-Hexane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Combustion Characteristics of Stratified Mixture in a Constant Volume Combustion Chamber with Sub-chamber( I ) (부실식 정적연소실내 층상혼합기의 연소특성( I ))

  • Kim, B.S.;Kwon, C.H.;Ryu, J.I.;Ryu, J.I.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.1
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    • pp.65-75
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    • 1995
  • The present study was investigated combustion characteristics of methane-air mixtures at stratified charge in a constant volume combustion chamber. The results indicated that even the vety lean mixture, which is normally not flammable in single chamber type, could be burned within. a comparatively short time by using sub-chamber with stratified charge method. And the lean inflammability limit of mixture in a main chamber was about ($\phi_m$cr=O.46, when the equivalence ratio of a sub-chamber was $\phi_s$= 1.0. Initial time of pressure increase and total burning times were decreased and maximum combustion pressure. was increased as the equivalence ratio of both sub and main chamber approached unity. Specifically, initial time of pressure increase and total burning times were greatly affected rather by. the equivalence ratio of sub-chamber than that of main chamber. The maximum combustion pressure was little affected if the total equivalence ratio lies in the same range.

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50% Flashover Voltage and V-t Characteristics for $SF_6-N_2$ Mixtures under Positive & Negative Ligtning Impulse Voltage ($SF_6-N_2$ 혼합가스의 정.부극성 뇌충격전압에 대한 50% FOV와 V-t 특성)

  • Song, W.P.;Kim, J.D.;Koh, H.S.;Kim, D.O.;Kwon, Y.H.;Cho, K.B.;Lee, C.H.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.300-303
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    • 1991
  • Sulphur-hexafluoride has extensively been used as an insulating gas of electric power equipment in substation for its high dielectric strength, non-toixity and non-flammable properties. But it is very expensive and is liquidizable under the condition of low temperature and high pressure. And it is very sensible to the locally high electric field strength. To resolve these problems, we studied 50% FOV and V-t characteristics of $SF_6-N_2$ mixtures under positive and negative lightning impulses using a 25mm rod-plane gap. 50% FOV of $SF_6-N_2$ 50% mixture was about 85% of pure $SF_6$ and it was known that $SF_6-N_2$ mixtures can be used as an economic substitution insulating gas for $SF_6$.

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Analysis of Parameters Affecting the Consequence of the Flash Fire Accident by the Release of Heavy Gas (무거운 가스의 누출에 의한 플래쉬화재사고에서 사고결과에 미치는 매개변수의 영향 분석)

  • Kim, Tae-Ok;Lee, Hern-Chang;Ham, Byeong-Ho;Cho, Ji-Hoon;Shin, Dong-Il;Jang, Seo-Il
    • Journal of the Korea Safety Management & Science
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    • v.8 no.6
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    • pp.29-39
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    • 2006
  • The effect of parameters on the consequence of the flash fire accident by the release of heavy gas(in this study, xylene vapor) was analyzed. Simulation results showed that the distance with the lower flammable limit($X_{LFL}$) was increased with the increase of the release hole diameter. For the case of the elevated release, $X_{LFL}$ was increased with the increase of the wind speed and the release height, but $X_{LFL}$ was not affected by the wind speed for the release on the ground level. Therefore, the accident in the elevated release was more dangerous than the release on the ground level. In this condition, the release height had more effect on $X_{LFL}$ at the night time than the daytime and in the urban area than the rural area.