• 제목/요약/키워드: flame retardant treatment

검색결과 67건 처리시간 0.024초

인계 화합물의 첨가에 의한 폴리우레탄의 난연성 (Flame Retardant Properties of Polyurethane by the Addition of Phosphorus Compounds)

  • 정영진
    • 한국화재소방학회논문지
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    • 제20권4호
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    • pp.110-115
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    • 2006
  • 폴리우레탄에 인계 화합물을 첨가하여 폴리우레탄폼을 제조하였으며, 인계 화합물이 제조된 폴리우레탄폼의 기계적 물성과 난연성에 미치는 영향에 대하여 고찰하였다. 폴리우레탄과 인계 난연제인 Tri(chloroisopropyl) phosphate(TCPP), Triethyl phosphate(TEP), Trimethyl phosphate(TMP) 각각을 약 $90^{\circ}C$에서 혼합시켜 혼합물로부터 제조된 경질 폴리우레탄폼에 대한 여러 실험을 통하여 기계적 물성뿐만 아니라 난연 효과도 상당히 향상됨을 확인하였다. Cone calorimeter를 이용하여 열방출율(heat release rate, HRR)을 측정하여 난연 첨가제의 함량에 따른 재료별 난연 특성을 평가하였다. 그리고 Scanning Electron Microscope(SEM)을 사용하여 난연제를 첨가하여 만든 폴리우레탄폼의 morphology를 관찰한 결과 순수한 폼과 마찬가지로 매우 균일한 형태의 cell 분포를 가짐을 확인하였다.

난연특성을 가지는 EVA/Intumescent/나노클레이 복합재료 제조 및 교호집성재(Cross Laminated Timber) 적용 기술 (Preparation of EVA/Intumescent/Nano-Clay Composite with Flame Retardant Properties and Cross Laminated Timber (CLT) Application Technology)

  • 최요석;박지원;이정훈;신재호;장성욱;김현중
    • Journal of the Korean Wood Science and Technology
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    • 제46권1호
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    • pp.73-84
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    • 2018
  • 최근 들어 늘어나고 있는 도시형 화재 사고와 건축 외장재에 따른 화재 피해 사례의 증가에 따라 난연처리기술의 중요성이 부각되고 있다. 특히, 목재를 기반으로 한 건축재료의 활용에 있어서 난연처리기술은 더욱 중요하게 평가되고 있다. Intumescent 시스템은 비할로겐계 난연처리기술의 하나로, 발포와 탄화층 형성을 통하여 난연성을 구현하는 시스템이다. 본 연구에서는 Intumescent 시스템을 적용하기 위해 Ethylene vinyl acetate (EVA)를 매트릭스로 채용하여 복합재료를 제조하였다. Intumescent 시스템의 난연특성을 강화하기 위해 나노클레이를 함께 적용하였다. Intumescent 시스템과 나노클레이 기술을 함께 적용한 복합재료를 시트상의 시험편으로 가공한 후, 이를 활용하여 표면의 난연특성이 강화된 새로운 구조의 교호집성재를 제작하였다. Intumescent 시스템을 적용한 복합재료의 연소특성 평가에서 최대 열방출량이 효과적으로 감소되는 것을 확인할 수 있었다. 표면에 부착된 구조에 따라 CLT는 두 단계에 걸친 연소 현상이 발생했다. 또한, 심부 연소 과정에서 최대 열방출률이 크게 감소하는 경향을 확인할 수 있었다. 이러한 특성은 목재의 연소과정에 있어 연소 확산지연효과가 있을 것으로 판단된다. 표면단판에 대한 난연처리기술 및 복합재료 적용 최적화 기술을 통해 보다 화재특성이 개선된 CLT 구조체 개발이 가능할 것으로 기대된다.

붕산처리(硼酸處理) 합판(合板)의 열판건조(熱板乾燥) 및 동적(動的) 탄성율(彈性率)에 관(關)한 연구(硏究) (Studies on Press Drying and Dynamic Elastic Modulus of Plywood Treated with Boric Acid)

  • 김종만
    • Journal of the Korean Wood Science and Technology
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    • 제15권3호
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    • pp.56-67
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    • 1987
  • Plywoods used for construction as a decorative interior material are inflammable and can make fire accidents, causing destruction of human life and property. Therefore, it is indeed required to make fire-retardant treated plywood. In this study, 3.7mm yellow meranti plywoods were soaked in 18% boric acid solutions and tap water by hot-cold bath for 1/2, 2/2, 4/2, 6/2 hours and redrying of treated plywoods was carried out by press drying at the platen temperature of 110, 130, 160, $180^{\circ}C$ and then it was conducted to investigate solution absorption, drying rates, dynamic young's modulus. specific gravity and fire-retardant factors such as burning point, flame spread length. flame exhausted time, back side carbonized area and weight loss by treating time, treating solutions and platen temperature. The results are as follows; 1. When plywood was impregnated with the hot bath temperature of $70^{\circ}C$ for 1. 2, 4, 6 hours and the cold bath temperature of $15^{\circ}C$ for 2 hours respectively, retentions of boric acid were 1.565, l.597, 1.643, 1.709kg/$(30cm)^3$ and all of them exceeded the minimum retention [1.125kg/$(30cm)^3$] even in the shortest treatment. 2. In hot-cold bath method for 1/2 hours, the drying rates of treated plywood remarkably increased with the extension of platen temperature of 110, 130, 160, $180^{\circ}C$ and the values of boric acid treated plywood were 5.900, 10.196, 45.42, 54.958m.c%/min and the values of water treated plywood were 6.014, 12.373, 46.520, 55.730m.c%/min and drying rates of water treated plywood were faster than those of boric acid treated plywood. 3. The values of boric acid treated plywoods in dynamic young's modulus were widely higher than those of water treated plywoods. And it can be observed that there were highly significant differences for treating time between dynamic young's modulus, and the values of boric acid plywoods increased with the extension of treating time but on the contrary water treated plywoods were decreased values with prolonged time 4. It was observed that there were highly significant differences for platen temperature between dynamic young's modulus. When the values of water treated plywoods in dyna nic young's modulus were abruptly decreased according to the rise of platen temperature. boric acid treated plywoods showed rather increased values at $160^{\circ}C$ of platen temperature. And in 2- way interactions, there were also highly significant for dynamic young's modulus between treating time x treating solutions and platen temperature x treating solutions. 5. Correlation coefficients of fire-retardant factors were shown in table 5. It could be recognized that there were close correlations between the treating solutions and burning point, flame spread length, back side carbonized area, flame exhausted time and weight loss, but there was no correlation between fire-retardant factors and treating time and platen temperature. 6. From table 6, it can be observed that there were highly significant differences for burning point, flame spread length, flame exhausted time, back side carbonized area, weight loss between treating solutions. And in 2-way interactions, there were highly significant for burning point, flame spread length, weight loss between treating time $\times$ treating solutions.

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암모늄염으로 처리된 느티나무의 난연성 시험 (Flame Retardancy of Zelkova Sarrata Treated with Ammonium Salts)

  • 정영진
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.399-406
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    • 2010
  • This study was performed to test the flame retardancy of zelkova sarrata-based materials by the treatment of ammonium salts. Zelkova sarrata plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium chloride (AMSL), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for zelkova sarrata, the flame retardancy improved due to the treated ammonium salts in the virgin zelkova sarrata. However the specimen shows increasing CO over virgin zelkova sarrata and It is supposed that toxicities depend on extents. Also, the specimen with ammonium salts showed the higher total smoke release (TSR) than that of virgin plate. Of specimens treated with ammonium salts the ammonium chloride handled the test side was considered a improved inhibitory effect of combustion.

난연성 폴리아크릴로니트릴 고분자 섬유 및 복합소재 연구 동향 (A Review of Flame Retarding Polyacrylonitrile (PAN) Fibers and Composites)

  • 김종호;구본철
    • Composites Research
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    • 제32권6호
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    • pp.342-348
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    • 2019
  • 고분자 재료의 사용이 늘어남에 따라 난연성 고분자 재료에 대한 연구가 더욱 활발히 진행되고 있다. 고분자 재료의 난연성 향상을 위한 방법으로 제조된 섬유의 후처리 또는 섬유내 난연제의 도입에 관한 연구가 진행되고 있다. 많은 고분자들 중 탄소섬유 전구체인 폴리아크릴로니트릴(PAN)은 의류용으로도 많이 사용되고 있어서 낮은 난연성을 지닌 PAN으로 이루어진 소재의 난연성 향상이 절실히 요구되고 있다. 본 총설 논문에서는 PAN 섬유의 후처리(안정화 또는 화학반응)을 통한 난연성 PAN 섬유와, 유/무기 소재(실리카, 2차원 소재, 탄소나노튜브)과 함께 혼합하여 섬유로 제조하는 난연성 PAN 복합소재의 제조에 대한 연구를 소개하고자 한다.

유-무기 하이브리드 방염제의 성능특성에 관한 연구 (Study on the Performance Characteristics of Organic-Inorganic Hybrid Flame Retardants)

  • 조경래;김시국
    • 한국화재소방학회논문지
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    • 제31권4호
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    • pp.12-19
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    • 2017
  • 본 논문은 유-무기 하이브리드 방염제의 성능특성에 관한 연구로써 건축물의 실내장식물로 많이 사용되고 있는 MDF 합판을 이용하여 유-무기 하이브리드 방염제 처리 유 무에 따른 실험시료를 제작하였다. 그 후 $45^{\circ}$ 연소시험기를 이용한 방염성능 측정실험과 콘칼로미터를 이용한 연소특성 측정실험을 진행을 진행하여 유-무기 하이브리드 방염제의 성능특성을 확인하였다. 실험결과 유-무기 하이브리드 방염제의 경우 무기물 및 유기물의 장점 모두 가지고 있어 내열성 및 내구성, 부착성이 크게 향상되는 것을 확인할 수 있었다. 또한, 연소가스 발생량의 저감효과와 연기발생의 감연효과 등 방염성능이 우수하게 나타났다.

코로나 방전처리에 의한 폴리에스테르 및 P/C 혼방직물의 복합기능화 가공(I) -난연 및 위생가공- (Multi-Functional Finish of Polyester and P/C blend Fabrics by Corona Discharge(I) -Flame-Retardant and Sanitary Finish-)

  • Lee, Bang One;Pak, Pyong Ki;Lee, Hyun Ja;Lee, Hwa Sun
    • 한국염색가공학회지
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    • 제9권2호
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    • pp.1-9
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    • 1997
  • This paper was carried out to introduce flame retardant and antibiotic properties to polyester(PET) and polyester/cotton(P/C) blend fabrics. PET and P/C blend fabrics were treated by a paddry-cure method in the aqueous solutions of the finishing agents(JA 6034, JA 6050, DC-5700). The corona discharge technique was applied to increase the polar group of the polymer surface. The characteristics of the treated fabric were investigated by means of scanning electron microscope (SEM) and electron spectroscopy for chemical analysis(ESCA), and water penetration time, limiting Oxygen index(LOI), and K/S value were also measured. Wettability of the fabrics was increased considerably with the corona discharge treatment. ESCA was used to elucidate the surface chemical composition of the fabrics treated with the corona discharge. Relative Ols intensity increased and oxygen was incorporated in the form of -C-O-, -C=O, and O=C-O on the polymer surface. The current study indicated that corona discharge treatment was effective for modifying the polymer surface.

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난연처리된 목재의 연소속도에 관한 연구 (A Study on the Burning Rate of Fire Retardant Treated Wood)

  • 박형주
    • 한국안전학회지
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    • 제22권6호
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    • pp.46-54
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    • 2007
  • The purpose of this study was to examines the burning rate of fire retardant treated wood in the cone heater with a one-dimensional integral model. The wood samples used in this study were four species. The species of woods are Redwood, White oak, Douglas fir and Maple. Each sample was nominally 50mm thick and 100mm square. Samples were exposed to a range of incident heat fluxes 10 to $35kW/m^2$ using the cone heater. A one-dimension integral model has been used to predict burning rate, heat of gasification, flame heat fluxes, charring rate and char depth of samples. As a result measurement of mass loss rate, softwoods(Redwood and Douglas fir) has relatively low value than those for hardwoods(White oak and Maple). Average charring rate of woods in case of fire retardant treatment showed reduction effect of 41.29%, 50.00%, 48.18% and 60.82% for Redwood, Douglas fir, White fir and Maple, respectively. Almost all the predictions from integral model showed faster charring than those measured. Average difference between predictions and experimental data was 16%, 9.5% and 11.8% for N, F1 and F2 respectively. Water-soluble fire retardant used in this study find out more effect in hardwood than softwood from the result of measurement of mass loss rate and average charring rate.

마이크로웨이브 건조목재의 방염처리 스케줄 (Flame-resistant treatment schedule of Microwave drying wood)

  • 박철우;허재원;임남기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 추계 학술논문 발표대회
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    • pp.27-28
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    • 2011
  • This research aims to secure fundamental data for the development offire-retardant wood by soaking dried wood in fire-retardant liquid. To dry wood, optimal drying conditions for softwood usually used as structural material and hardwood usually used as finishing or furniture material were derived by varying the microwave outputs and heating times of microwave wood drying equipment. The research foundthat each specimen needs 8 to 15 minutes of heating time depending on water content and output. For softwood, fire-retardant liquid equivalent to about 10 percent of the total mass of the specimen infiltrated into the dried wood, of which the water content was reduced to 5~6 percent.

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