• Journal of Energy Engineering
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• v.19 no.4
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• pp.215-220
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• 2010

Hydrogen is a clean and efficient energy source and is expected to take an important role in future energy demand. A possibly good route to produce hydrogen is by using biomass and organic wastes as a source through thermo-chemical conversion technology. In this study, pyrolysis of wood Pellet(Oregon pine) has been carried out in batch type fixed-bed reactor in $N_2$ atmosphere during 20 minutes to determine the optimum hydrogen generating conditions. At the influence of temperature, hydrogen yield was increased with increasing temperature. For the influence of Steam/Biomass Ratio(SBR), hydrogen yield was increased by steam addition at low temperature condition. However, effect of steam addition was insignificant over at SBR = 1. The hydrogen yield was increased with increasing SBR at high temperature condition. From result of $H_2$/CO and $H_2/CH_4$ ratio, dominant reaction was steam reforming in this experimental condition. The optimum condition for hydrogen production was determined as follows: $H_2$ yield = 38.3 vol.% (56.01 L/min kg) at $900^{\circ}C$, SBR=3.

• Journal of Energy Engineering
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• v.25 no.3
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• pp.104-113
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• 2016

This study analyzes correlation between methane gas production and injection of food waste water to motivate to expand renewable energy as a way of GHG (Green House Gas) mitigation to achieve the national GHG target proposed for the climate agreement in Paris last year. Pretreatment of food waste water was processed with pH 6 at $35^{\circ}C$ and used the fixed-bed upflow type reactor with the porous media. As a result of operation of pilot-scaled bioreactor with food waste water, the methane gas production was 6 times higher than the methane gas production of control group with rain water. The average production of methane was $56{\ell}/day/m^3$ which is possible to produce $20m^3$ of methane in $1m^3$ of landfill. As a way of energy source, when it is applied to the landfill over $250,000m^3$, it is also able to achieve financial feasibility along with GHG reduction effect. GHG reductions of $250,000m^3$ scale landfill were assessed by registered CDM project and the annual amount of reductions was 40,000~50,000 $tCO_2e$.

• Journal of Korea Water Resources Association
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• v.38 no.2
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• pp.143-153
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• 2005

Recently, the concern of groynes that provide us with various ecological environment and improvement of scenary near river as well as hydraulic improvement has greatly increased for naturalized river and ecological river restoration. However there is no adequate design guidelines in Korea. Furthermore there is lack of research for installation of groynes in Korea. Thus, in this study, we have conducted hydraulic modeling test for kinds of groyne and changes of permeability and made a study of the analysis for installation factor of groyne. Experimental conditions were the fixed bed model for flow pattern of groyne tip and separation length about changes of groyne length and permeability. The Experiments were conducted to measure velocity and drift angle at groyne tip. The main study kas measured the groyne tip velocity for a factor of scour and drift angle for velocity increase at center of channel. We have suggested the equation about groyne tip velocity rate(tip velocity/ approach velocity) and area rate(groyne area/ flow area). And In recirculation zone of groyne downstream, To study the basic data of groyne about installation interval has analyzed the change of separation length and incidence angle. We have suggested the equation about separation length rate(separation length/ groyne length), changes of permeability and installation angle.

• Journal of Korea Water Resources Association
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• v.41 no.2
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• pp.197-212
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• 2008

Recently, stream flow analysis has been accomplished by one or two dimensional equations and was applied by simple momentum equations and fixed energy conservations which contain many condition limits. In this study, FLOW-3D using CFD (Computational Fluid Dynamics) was applied to stream flow analysis which can solve three dimensional RANS (Reynolds Averaged Navier-Stokes Equation) control equation to find out physical behaviors and the effect of hydraulic structures. Numerical simulation accomplished those results was compared by using turbulence models such as ${\kappa}-{\varepsilon}$, RNG (Renormalized Group) ${\kappa}-{\varepsilon}$ and LES (Large Eddy Simulation). Numerical analysis results have been illustrated by the turbulence energy effects, velocity of flow, water level pressure and eddy flows around the piers and transverse overflow type structures. These results will be able to used by basis data that catch hold of effects on long-term bed elevation changes, sediment accumulations, scours and water aggravations by removal of obsolete transverse over flow type structures in urban stream.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.321-326
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• 2006

Thermal degradation of styrene dimer fraction (SDF, main compound: 47 wt% of 1,3-diphenylpropane), 5~15% of total products produced during decomposition of waste expanded polystyrene (WEPS) was investigated. Reaction condition of $360^{\circ}C$, and 152 kPa to 202 kPa was an optimum for high pressure degradation. Under this operating condition, the yield of oil was 73.8% and the selectivities to Ben, Tol, EB, SM, and AMS were 0.4, 30.9, 15.0, 19.6, and 4.2%, respectively. Non-catalytic fixed bed continuous degradation was conducted at reaction temperatures of $510{\sim}610^{\circ}C$ and contact time ranges of 2~24 min, where the yield was increased by increasing of reaction temperature and contact time. A $Cr_2O_3$ catalyst showed the highest activity and SM yield among acid, base, and redox catalysts. The conversion of 74.6% and the yield of Ben, Tol, EB, SM, and AMS were 0.4, 21.6, 9.7, 17.9, and 3.5%, respectively at $560^{\circ}C$ and contact time of 24 min. It is thought that styrene is converted to EB and other secondary products throughout the formation of diradicals of styrene.

• Applied Chemistry for Engineering
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• v.2 no.2
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• pp.165-174
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• 1991

The kinetics and the mechanism for the selective oxidation of ethylene on the supported monolithic silver catalyst were experimentally investigated in a fixed bed tubular reactor. The formation rates of ethylene oxide and carbon dioxide were measured at the atmospheric pressure with various combinations of partial pressures of ethylene and oxygen at temperature range of $225-300^{\circ}C$, conversion with 1.2-7.5 %, and then the mechanism of the selective oxidation of ethylene was verified. Their formation rates fitted with the Langmuir-Hinshelwood mechnism. The ethylene oxide and carbon dioxide are produced by reation of adsorbed ethylene with monoatomic oxygen adsorbed on the active sites of Ag-surface, and their formation rate equation are expressed as : $R_{EO}={\frac{k_1K_0{^{1/2}}K_EK_SP_{02}{^{3/2}}P_E}{(1+{\sqrt{K_0P_{02}}}+K_EP_E+K_PP_P)^2(1+{\sqrt{K_SP_{02}})^2}}$ $R_C={\frac{k_2K_0{^3}K_EK_S{^{7/2}}P_{02}{^{13/2}}P_E}{(1+{\sqrt{K_0P_{02}}}+K_EP_E+K_PP_P)^7(1+{\sqrt{K_SP_{02}})^7}}$ The activation energies of ethylene oxide and dioxide and carbon dioxide formations can be estimated to be 12.25 and 17.85 Kcal/mol, respectively.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1129-1135
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• 1999

The reduction of $SO_2$ by CO over supported cobalt catalysts was investigated within the temperature range of $350{\sim}550^{\circ}C$, initial $SO_2$ concentration of 1000~10000 ppm, $CO/SO_2$ molar ratio of 1.0~3.0 and space velocity of $5000{\sim}15000h^{-1}$. Several types of supports such as ${\gamma}-Al_2O_3$, $TiO_2$ were tested. The $SO_2$ conversion and selectivity to elemental sulfur were investigated using a differential fixed bed reactor at atmospheric pressure. The catalyst prepared by wet impregration of 5 wt % cobalt on ${\gamma}-Al_2O_3$ showed $SO_2$ conversion higher than 90% and COS yield lower than 6% at temperature above $400^{\circ}C$. The optimum $CO/SO_2$ molar ratio was investigated as 2.0. At higher $CO/SO_2$ molar ratio, the $SO_2$ conversion became higher but the main product was COS. The effect of $SO_2$ concentration and space velocity over $SO_2$ conversion and COS yield was not appreciable in the experimental range. The activated cobalt phase was detected as $CoS_2$ and the $CoS_2$ phase unchanged even after reaction.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.618-624
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• 2007

thermochemical methane reforming consisting of two steps on Cu/Fe/Zr mixed oxide media was carried out using a fixed bed infrared reactor. In the first step, the metal oxide was reduced with methane to produce CO, $H_2$ and the reduced metal oxide in the temperature of 1173 K. In the second step, the reduced metal oxide was re-oxidized with steam to produce $H_2$ and the metal oxide in the temperature of 973 K. The reaction characteristics on the added amounts of Cu in Cu/Fe/Zr mixed oxide media and the cyclic tests were evaluated. With the increase of the added amount of Cu in Cu/Fe/Zr mixed oxide media, the conversion of $CH_4$, the selectivity of $CO_2$ and the $H_2/CO$ molar ratio were increased, while the selectivity of CO was decreased in the first step. On the other hand, the evolved amount of $H_2$ was decreased with increasing the added amount of Cu in the second step. The $Cu_xFe_{3-x}O_4/ZrO_2$ medium added with Cu of x = 0.7 showed good regeneration properties in the 10th cyclic tests indicating that the medium had high durability. In addition, the gasification of the deposited carbon in the water splitting step was promoted with the addition of Cu in the media.

• Applied Chemistry for Engineering
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• v.21 no.3
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• pp.328-332
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• 2010

In this study, porous ZnO sphere and Cu-ZnO composite were synthesized by coprecipitation method in diethylene glycol solvent. The physicochemical properties of as-prepared composite materials were characterized by SEM, XRD, $N_2$-sorption and $H_2$-TPR. A series of porous Cu-ZnO with different Cu contents (0, 6.6, 21.3, 36.4, 54.6, 77.8 wt%) was investigated for CO oxidation activity in a fixed bed reactor system. With increasing Cu content in Cu-ZnO the surface area and micropore volume of Cu-ZnO are decreased and Cu (36.4 wt%)-ZnO shows higher activity for CO oxidation compared to the others.

• Health Policy and Management
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• v.12 no.2
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• pp.43-75
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• 2002

This study focuses on the factors that make the financial structure of hospitals in Korea different, and on recommended courses of action that could be very helpful to hospitals in maintaining a sound financial structure. Data used in this study were collected from 132 hospitals with complete general data of present conditions as well as financial statements. They were chosen from the 174 hospitals that passed the standardization audit undertaken by the Korean Hospital Association from 1996 to 2000 for the purpose of accrediting training hospitals. The dependent variable in this study is financial structure. It consists of liabilities as against total assets (total liabilities to total assets, short-term liabilities to total assets, long-term liabilities to total assets, short-term borrowings to total assets, long-term borrowings to total assets). The independent variables are ownership type, hospital type, location, whether or not a representative is a director of the hospital, the possibility of changing a hospital director, bed size, period of establishment, asset structure, profitability, growth, tax shields, business risk, competition. The factors that appear to have the strongest impact on the liabilities to total assets of all the hospitals sampled are ownership type, hospital type, profitability, tax shields, and business risk. It was found that not-for-profit private hospitals and for-profit private hospitals have more liabilities than public hospitals, and tertiary medical institutions have less liabilities than the secondary general hospitals. Moreover, hospitals earning more at the expense of high business risk have a distinct tendency to lower liabilities. Concerning the current ratio, it was found that factors such as ownership type, hospital type, period of establishment, asset structure, and business risk are the more significant variables. The current ratio of public hospitals is higher than that of both not-for-profit private hospitals and for-profit private hospitals, and the current ratio of tertiary medical institutions is higher than that of general hospitals. As business risk is higher in hospitals compared to other businesses, the current ratio becomes higher; this is because it is assumed that for fear of bankruptcy, hospitals lessen liabilities to total assets. On the other hand, as hospitals become older, the fixed assets to total assets become lower. It is remarkable that in hospitals, the factors affecting liabilities to total assets have an opposite regression coefficient sign against factors affecting current ratio. It brings out the same results borne out by the old financial theories and researches, in which a lot of the liabilities of hospitals are considered as the cause of worsening liquidity. Therefore, it is very important for hospitals to maintain a sound financial structure in order to survive using the rational acquisition and maintenance of capital.