• Title/Summary/Keyword: fixed oil

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A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature (필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 -)

  • Lee, Kyong-Hwan;Song, Kwang-Sup;Nam, Ki-Yun
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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Effects of Dietary Fat Levels on Lipid Parameters and Eicosanoids Production of Rats under Fixed N-6/N-3 and P/S Fatty Acid Ratios

  • Lee, Joon-Ho;Ikuo Ikeda;Michihiro Sugano
    • Nutritional Sciences
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    • v.5 no.4
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    • pp.184-189
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    • 2002
  • The effects of dietary Int levels on lipid metabolism under fixed P/S (1.3) and n-6/n-3 (5.1) fatty acid ratios were examined in rats using palm oil, soybean oil and perilla oil. These ratios correspond to the recommended composition of dietary fat for humans. The range of dietary fat levels was 5-20% by weight (11.8-39.3% of total energy). The levels of dietary fat did not influence the concentrations of serum and liver cholesterol, whereas the level of triglycerides was gradually elevated with increasing levels of dietary fat, especially in the liver. The fatty acid composition of tissue phosphatidylcholine seemed to vary with the different levels of fat. The ratio of linoleic acid to arachidonic acid was increased more significantly in the heart than in the liver. In adipose tissue total lipids, the percentages of saturated and monounsaturated fatty acids decreased, whereas the percentage of polyunsaturated fatty acid increased, with increasing dietary Int levels. In addition, though the level of aortic prostacyclin was not uniformly affected by increasing dietary fat levels, thromboxane A2 production by platelets tended to increase with higher levels of dietary fat, suggesting an increased risk of thrombosis in this situation. Thus, even though dietary fat may have desirable compositions of fatty acids, these excessive consumption can produce unfavorable metabolic responses.

Quality Comparison of Activated Carbon Produced From Oil Palm Fronds by Chemical Activation Using Sodium Carbonate versus Sodium Chloride

  • MAULINA, Seri;HANDIKA, Gewa;Irvan, Irvan;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.503-512
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    • 2020
  • Using Na2CO3 versus NaCl as chemical activator, we compared the quality of activated carbon produced from oil palm fronds as raw material. These activators were selected for comparison because both are readily available and are environmentally friendly. In the manufacturing, we used Indonesian National Standard (SNI 06-3730-1995) parameters. For the quality comparison, we determined activated-carbon yield, moisture, ash, volatiles, and fixed-carbon contents; and adsorption capacity of iodine. The best characteristics, assessed by morphological surface analysis and Fourier transform infrared (FTIR) spectral analysis, were observed in the carbon activated by Na2CO3 at an activator concentration of 10% and carbonization temperature of 400 ℃. The results were as follows: activated-carbon yield, 84%; water content, 8.80%; ash content, 2.20%; volatiles content, 14.80%; fixed-carbon content, 68.60%; and adsorption capacity of iodine, 888.51 mg/g. Identification using the FTIR spectrophotometer showed the presence of the functional groups O-H, C=O, C=C, C-C, and C-H in the Na2CO3-activated carbon.

Flow and Heat Transfer Characteristics of $CO_2$/Oil Mixtures in a Circular Tube

  • Kang, Byung-Ha;Lim, Dong-Seop
    • International Journal of Air-Conditioning and Refrigeration
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    • v.16 no.4
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    • pp.117-123
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    • 2008
  • The present study is directed at flow and heat transfer of $CO_2$ and oil mixtures in a circular tube. PAG and POE oils are considered in this study. Flow characteristics of $CO_2$ and oil mixtures have been investigated by flow visualization. Pressure drop has been measured in the range of operating mass flow rate from 0.1 to 0.4 kg/min in a circular tube. Heat transfer characteristics of $CO_2$/oil mixtures have been investigated using a counterflow heat exchanger. In case of pure liquid $CO_2$ as well as $CO_2$ and POE mixtures, flow are seen to be uniform so that $CO_2$ and POE oil are still miscible even at flowing state. However, it is found that $CO_2$ and PAG are not miscible. Pressure drop of $CO_2$/PAG mixtures are much higher than that of $CO_2$/POE mixtures as well as pure $CO_2$ at a fixed mass flow rate. As the concentration of POE oil is increased from 0 to 5 wt%, pressure drop is increased. However, heat transfer rate and heat transfer coefficient of $CO_2$/POE mixtures are much higher than that of $CO_2$/PAG mixtures. The f-factor correlation and Nusselt number correlation for $CO_2$/POE oil mixtures are suggested in this paper.

Does Falling Oil Prices Impact Industrial Companies in the Gulf Cooperation Council Countries?

  • AL SAMMAN, Hazem;JAMIL, Syed Ahsan
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.2
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    • pp.89-97
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    • 2021
  • This research aims to investigate the impact of falling oil prices at the beginning of 2020 on 82 industrial companies listed on the GCC stock markets. The research sample period is divided into two periods pre-COVID and during COVID covering the period starting 1st January 2020 to May 15, 2020. The research uses the Panel Least Square (PLS) method and Panel Generalized Method of Moments (GMM) with fixed and random effects in each country. The results of GMM models reveal a positive relationship between oil prices and the share prices of industrial companies in the Gulf countries, which confirms that the share prices of industrial companies in the Gulf Cooperation Council (GCC) countries have been negatively affected by the decline in oil prices with the beginning of 2020. The findings show that the highest impact of falling oil prices has been recorded in the industrial companies in the kingdom of Saudi Arabia. However, the falling of oil prices does not have a significant effect on industrial companies in the state of Qatar. The research results suggest that GCC economies have to move on the path of non-reliance on Oil and gas-driven economy.

Evaluation of Nigella sativa Seed Constituents for Their in vivo Toxicity in Mice

  • EI-Hadiyah, T.M.;Raza, M.;Mohammed, O.Y.;Abdallah, A.A.
    • Natural Product Sciences
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    • v.9 no.1
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    • pp.22-27
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    • 2003
  • This study was designed to investigate the effects of main constituents of Nigella sativa (NS) seed on the survival and CNS responses in experimental animals. The toxicological investigations were conducted for the determination of median lethal doses $(LD_{50})$ of NS seed constituents [i.e. aqueous extract (AE), fixed oil (FO), volatile oil (VO)] and main components of its VO [i.e. thymoquinone (TQ), ${\alpha}-pinene$ (AP) and p-cymene (PC)]. A part of this study includes evaluation NS constituents in the induction of minimal neurological deficit (MND) as a parameter for neurotoxicity using chimney test. In this study, the i.p. $LD_{50}$ values of AE, FO, VO, TQ (suspended In 0.5%CMC), TQ (dissolved in corn oil), AP and PC, were 3020, 3371, 1853, 616.6, 90.3, 1726 and 1523 mg/kg, respectively. All the NS constituents can be considered moderately toxic ($LD_{50}$ ranged from 616.6 to 3371 mg/kg), except the oily solution of TQ, which was very toxic ($LD_{50}$ was 90.3 mg/kg). It appeared that the toxicity of the whole VO is mainly due to its content of TQ and to some extent PC. All the NS constituents induced different degrees of MND at certain dose levels. The median neurotoxic (or sedating) doses $(TD_{50})$ of AE, FO, VO, TQ (suspended in CMC) and AP and PC, were 950, 1403, 306, 88.1, >173 and 368 mg/kg, respectively. TQ was the most potent component in inducing MND, whereas the FO and AE were the least. Neurotoxicity induced by the VO in the chimney test may refer basically to its contents of TQ and to some extent PC and AP.

Friction Assessment of Canola Oil on Contact Bearing Materials

  • Okechukwu, Nicholas Nnaemeka;Byun, JaeYoung;Kim, JongSoon;Park, JongMin;Kwon, SoonGoo;Chung, SungWon;Kwon, SoonHong;Choi, WonSik
    • Tribology and Lubricants
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    • v.36 no.1
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    • pp.11-17
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    • 2020
  • In manufacturing operations, oil plays a crucial role in reducing friction and wear among interacting surfaces at varying velocities, loads, and temperature. Hydrocarbon oil is considered the origin of lubrication oils. However, this base oil has been limited in its use as it is a principal cause of pollution. This research focuses on identifying a biodegradable base oil lubricant that possesses a stable coefficient of friction and viscosity with temperature. Friction analysis is conducted by employing a pin on a disk tribotester with a fixed load of 10 N at varying sliding speeds ranging from 0.06 m/s to 0.34 m/s. Oil viscosity analysis is perfomed at room temperature by using a rotary viscometer. Tests are performed using canola oil and paraffin oil as lubricants. The results indicate that the viscosity of canola oil is more efficient than paraffin oil. The non-dimensional characteristic number according to the Stribeck curve reveals an elastohydrodynamic lubrication regime with canola oil lubrication. A comparison of both lubricants reveals that, the friction efficiency of canola oil and paraffin oil does not differ considerably. However, the friction in canola oil is observed to decrease more than that in paraffin oil at an elevated sliding speed. The tests confirm that canola oil is potent in minimizing the friction coefficient of SCM440 bodies interacting with one another as well as acted upon by load.

A Study on the Development of an Oil Sweep System for Small Patrol Vessels (소형 경비함정 장착용 유흡착장비 개발에 관한 연구)

  • Lee, Si Chan;Kim, Hyung Gyu;Park, Yong Hee;Kim, Jong Ho;Lee, Yong Jun;Kim, Dae Il
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.2
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    • pp.282-287
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    • 2018
  • Due to limitations in responding to oil spill incidents that are urgent or that cover a wide area with only oil spill response vessels, Korea Coast Guard (KCG) patrol vessels are utilized. In this study, we have developed an oil sweep system suitable for small patrol vessels. The equipment consists of three components - fixed support, poles, and slide fixers - and can be fastened with a toggle pin to a fall prevention bar on small patrol vessels without welding or additional efforts for installation. The respective weights of each component - fixed support, poles (2 pcs), and slide fixers (4 pcs) - are approximately 9.2 kg, 6.5 kg, and 3.5 kg. The 3 m-pole, which is rotatable 180 degrees horizontally, is folded deckward when replacing oil absorbents. As the development of this equipment has improved the method of deploying and retrieving oil absorbents on KCG small patrol vessels, we expect that more efficient oil spill cleanup will be possible.

ADMINISTRATION OF CROTON OIL EFFECTED IN THE INTESTINAL MUCOUS CELL OF MICE (파두유(巴豆油) 투여(投與)가 생쥐의 장관점액세포(腸管粘液細胞)에 미치는 영향(影響))

  • Han, Kyung-Taik
    • The Journal of Internal Korean Medicine
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    • v.1 no.1
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    • pp.98-106
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    • 1976
  • In order to study the effect of croton oil on the mucous cell in the mice intestin the experimental animals were injected with 0.1gm body weight of croton oil through intraperitoneally. They were sacrificed by ether anesthesia and obtained from distal small intestine and duodenum and colon, and fixed in 10% meutral formal. After embedded in paraffin, sectioned in 5 micro thickness, and stained with P.A.S (Periodic Acid Schiffis) reaction. The average number of the mucous cell was counted in each specimen over 20 fields under 450 magnification. The following results were obtained; 1) An average number of mucous cell began rapidly increase from 15 min and reached high average number after injection of croton oil of mucous cell from 30-60 min after injection. 2) An average number of mucous cell rapidly increase after injection of croton oil and were not reduced normal level by time lapsed 48 hrs. 3) The mucous cell showed with tape of time after injection of croton oil. A type and B type decrease and showed recovery C type decrease and recovery. 4) According to the above findings, it is presumed that croton oil accelerate secretion of mucin of the mucouse cell and production of mucin in growing mucous cell.

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A Study of Upgrading of Pyrolysis Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste (혼합폐플라스틱 열분해 왁스오일의 고급화 연구)

  • Lee, Kyong-Hwan;Nam, Ki-Yun;Song, Kwang-Sup;Kim, Geug-Tae;Choi, Jeong-Gil
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.321-324
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    • 2009
  • Upgrading of pyrolysis wax oil has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation using HZSM-5 catalyst are compared with the thermal degradation and also was studied with a function of experimental variables. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The product characteristic from thermal degradation shows a similar trend with that of raw pyrolysis wax oil. This means the thermal degradation of pyrolysis wax oil at high degradation temperature is not sufficiently occurred. On the other hand, the catalytic degradation using HZSM-5 catalyst relative to the thermal degradation shows the high conversion of pyrolysis wax oil to light hydrocarbons. This liquid product shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Also, in the catalytic degradation the experimental variable such as catalyst amount and reaction temperature was studied.

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