• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.6
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• pp.649-656
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• 2011

A model for the numerical simulation of lithium-ion batteries (LIBs) is developed for use in battery cell design, with a view to improving the performances of such batteries. The model uses Newman-type electrochemical and transfer $theories^{(1,2)}$ to describe the behavior of the lithium-ion cell, together with the Levenberg-Marquardt optimization scheme to estimate the performance or design parameters in nonlinear problems. The mathematical model can provide an insight into the mechanism of LIB behavior during the charging/discharging process, and can therefore help to predict cell performance. Furthermore, by means of least-squares fitting to experimental discharge curves measured at room temperature, we were able to obtain the values of transport and kinetic parameters that are usually difficult to measure. By comparing the calculated data with the life-test discharge curves (SB LiMotive cell), we found that the capacity fade is strongly dependent on the decrease in the reaction area of active materials in the anode and cathode, as well as on the electrolyte diffusivity.

• Journal of Korean Association for Spatial Structures
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• v.7 no.5
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• pp.75-82
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• 2007

The present work measured and analyzed changes in the acoustics of a sound field which has a retractable ceiling. An 1/20 scale model of an openable space was built and measurement was carried out by varying the opened area of a ceiling. The most widely used room acoustic and design parameters, RT, EDT, and D50 were investigated. The results suggest that the use of RT as an acoustic design parameter may not be proper in an openable space and further it is likely to mislead the initial acoustic design of such spaces. It is mainly due to the characteristics of RT in which non-exponential decay processes are linearly fitted. Early decay times were found to be decreased in proportion to increaing the ratio of opened area. D50, an index of speech intelligibility, was effectively shows the influence of openings on the acoustics. It is also found that EDT and D50 at the seats, not directly exposed to the opened part of a ceiling, were almost linearly decreased in proportion to the ratio of opened area, while little influence was found for the opening ratio larger than 40% at the directly exposed seats to the opened part of a ceiling.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.11
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• pp.893-900
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• 2021

In this study, air density in a narrow test section is measured using a laser absorption spectroscopy system that detects oxygen absorption lines. An absorption line pair at 13156.28 and 13156.62 cm^-1 are detected. A gas chamber with a height of 40 mm is used as a narrow test section. A triangular spiral-shaped laser path is applied in the gas chamber to amplify absorption strength by extending laser beam path length. A well-known logarithm amplifier and a secondary amplifier are used to electrically amplify absorption signal. An AC-coupling is applied after the logarithm amplifier for signal saturation prevention and noise suppression. Procedure of calculating spectral absorbance from output signal is introduced considering the logarithm amplifier circuit configuration. Air density is determined by fitting the theoretically calculated spectral absorbance to the measured spectral absorbance. Test conditions with room temperature and a pressure range of 10~100 kPa are made in a gas chamber using a Bourdon pressure gauge. It is confirmed that air density in a narrow test section can be measured within a 16 % error through absorption signal amplification using a triangular spiral-shaped beam path and a logarithm amplifier.

• Journal of the Korean Electrochemical Society
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• v.3 no.1
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• pp.49-56
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• 2000

In the present we.k, temperature dependence of oxygen diffusivity in the polyvinyl chloride (PVC) film $D_f$ formed on gold electrode was investigated using steady-state rotating disk electrode (RDE) technique and modulated electrohydrodynamic (EHD) impedance technique. Both the diffusion rate defined as the ratio of oxygen diffusivity in the PVC film to the film thickness $D_f/\delta_f$ and the time constant $\delta_f^2/D_f$ for oxygen diffusion through the PVC film were obtained from plot of the limiting current versus disk rotation speed and from filing the EHD impedance spectra experimentally measured to those theoretically calculated on the basis of the diffusion equation for mass transport through the non-conductive and porous film, respectively. By combining measured $D_f/\delta_f$ with $\delta_f^2/D_f$, we determined $\delta_f\;and\;D_f$ at room temperature separately. As temperature increased, it appeared that the $D_f$ value measured for the PVC film-covered gold RDE was enhanced more rapidly than that $D_s$ value in the solution measured for the PVC film-free gold RDE. This means that the pores glowing with increasing temperature act as effective diffusion paths within the film. The present in-situ steady-state and modulated EHD measurements prove to be effective for determining $\delta_f\;and\;D_f$, separately and at the same time the porosity of the PVC film at temperatures below glass temperature $T_g$ of the film.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.6-10
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• 2006

The sulphur spinel $FeCr_{2-x}M_xS_4$(M=Ga, In) have been studied with Mossbauer spectroscopy, x-ray diffraction (XRD), and vibrating sample magnetometer. The XRB patterns for samples $FeCr_{2-x}M_xS_4$(M=Ga, In: x=0.1, 0.3) reveal a single phase, which the Ga and In ions are partially occupied to the tetrahedral (A) site. The Neel temperature for the Ga substituted samples increases from 180 to 188 K, with increase from x=0.1 to 0.3. While, it decreases from 173 to 160 K, for the In substituted samples of the x=0.1 and 0.3, respectively. The Mossbauer spectra were collected from 4.2 K to room temperature. We have analyzed the Mossbauer spectra using eight Lorentzian lines fitting method for the $FeCr_{2-x}In_xS_4$(x=0.1) at 4.2 K, yielding the 1311owing results; $H_{hf}=146.0kOe,\;{\Delta}E_Q=1.88mm/s,\;\theta=36^{\circ},\;\phi=0^{\circ},\;\eta=0.6$, and R=1.9. The Ga ions enter into the both sites octahedral (B) and tetrahedral (A), simultaneously the same amounts of Fe ions migrate from the A to the B site, this result is an agreement with XRD results, too. The ${\Delta}E_Q$ of the A and B site in Mossbauer spectra of the samples $FeCr_{2-x}Ga_xS_4$(x=0.3) are 0.83 and 2.94mm/s, respectively. While they are 0.56 and 2.36mm/s for the $FeCr_{2-x}In_xS_4$(x=0.3). It is noticeable that the ${\Delta}E_Q$ for the Ga doped samples are larger than that of the corresponding In doped samples, in spite of the larger ionic radius for In ions. The bond lengths of Cr-S, for the Ga and In doped samples (x=0.3) are found to be 2.41 and $2.43\;{\AA}$, respectively. We interpret that the larger covalence effect from the smaller bond length induces a large asymmetric charge distribution. Finally, it gives a large quadrupole interaction.