• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.503-508
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• 2004

Optimal remediation design using the pump and treat(P&T) method and natural attenuation was accomplished in consideration for degradation processes, such as sorption and first-order decay rate. Variation of both sorption and first-order decay rate has influence on design of optimal remediation application. When sorption effect increases, the more pumping rate and pumping wells are required. The location of operated wells is on the centerline of contaminant plume and wells near hot spot are mainly operated when sorption effect increases. The higher of first-order decay rate, the less pumping rate is required. These results show that the degradation processes have to be considered as one of the essential factors for optimal remediation design.

• 상하수도학회지
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• 제19권4호
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• pp.487-496
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• 2005

Chlorine bulk decay tests were carried out by bottle test under controlled conditions in a laboratory. Experiments were performed at different temperatures: $5^{\circ}C$, $15^{\circ}C$, $25^{\circ}C$, and the water temperatures when samples were taken from the effluent just before entering to its distribution system. 38 bulk tests were performed for water of Al (water treatment plant), 4 bulk tests for A2 (large service reservoir), and A3(pumping station). Residual chlorine concentrations in the amber bottles were measured over time till about 100 hours and bulk decay coefficients were evaluated by assuming first-order, parallel first-order, second-order. and $n^{th}-order$ reaction. The $n^{th}-order$ coefficients were obtained using Fourth-order Runge-Kutta Method. A good-fit by the average coefficient of determination ($R^2$) was first-order ($R^2=0.90$) < parallel first-order ($R^2{_{fast}}=0.92$, $R^2{_{slow}}=0.95$) < second-order ($R^2=0.95$) < $n^{th}-order$ ($R^2=0.99$). But if fast reaction of parallel first-order bulk decay were applied to the effluent of large service reservoir with ca. 20 hours of travel time and slow reaction in the water distribution system following the first 20 hours, parallel first-order bulk decay would be best and easy for application of water quality modeling technique.

• 상하수도학회지
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• 제26권6호
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• pp.861-869
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• 2012

The chlorine's residual concentration prevents the regrowth of microorganism in water transport along the pipeline system. Precise prediction of chlorine concentration is important in determining disinfectant injection for the water distribution system. In this study, a pilot scale water distribution system was designed and fabricated to measure the temporal variation of chlorine concentration for three flow conditions (V = 0.88, 1.33, 1.95 m/s). Various kinetic models were applied to identify the relationship between hydraulic condition and chlorine decay. Genetic Algorithm (GA) was integrated into five kinetic models and time series of chlorine were used to calibrate parameters. Model fitness was compared by Root Mean Square Error (RMSE) between measurement and prediction. Limited first order model and Parallel first order showed good fitness for prediction of chlorine concentration.

• 상하수도학회지
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• 제28권3호
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• pp.287-297
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• 2014

It is important to predict chlorine decay with different water purification processes and distribution pipeline materials, especially because chlorine decay is in direct relationship with the stability of water quality. The degree of chlorine decay may affect the water quality at the end of the pipeline: it may produce disinfection by-products or cause unpleasant odor and taste. Sand filtrate and dual media filtrate were used as influents in this study, and cast iron (CI), polyvinyl chloride (PVC), and stainless steel (SS) were used as pipeline materials. The results were analyzed via chlorine decay models by comparing the experimental and model parameters. The models were then used to estimate rechlorination time and chlorine decay time. The results indicated that water quality (e.g. organic matter and alkalinity) and pipeline materials were important factors influencing bulk decay and sand filtrate exhibited greater chlorine decay than dual media filtrate. The two-component second-order model was more applicable than the first decay model, and it enabled the estimation of chlorine decay time. These results are expected to provide the basis for modeling chlorine decay of different water purification processes and pipeline materials.

• Environmental Engineering Research
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• 제23권1호
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• pp.99-106
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• 2018

Lack of information on the Biochemical Oxygen Demand (BOD) decay rates of river water under the tropical environment has triggered this study with an aim to fill the gap. Raw sewage, treated sewage, river water and tap water were mixed in different proportions to represent river water receiving varying amounts and types of wastewater and fed in a laboratory flume in batch mode. Water samples were recirculated in the flume for 30 h and BOD and Carbonaceous BOD (CBOD) concentrations were measured at least six times. Decay rates were obtained by fitting the measured data in the first order kinetic equation. After conducting 12 experiments, the range of BOD and CBOD decay rates were found to be 0.191 to 0.92 per day and 0.107 to 0.875 per day, respectively. Median decay rates were 0.344 and 0.258 per day for BOD and CBOD, respectively, which are slightly higher than the reported values in literatures. A relationship between CBOD decay rate and BOD decay rate is proposed as $k_{CBOD}=0.8642_{k_{BOD}}-0.0349$ where, $k_{CBOD}$ is CBOD decay rate and $k_{BOD}$ is BOD decay rate. The equation can be useful to extrapolate either of the decay rates when any of the rates is unknown.

• Journal of Photoscience
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• 제4권1호
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• pp.11-16
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• 1997

We measured, using femtosecond pump-probe experiment, the time evolution of transient absorption in aqueous CdS colloids. The signal rises within the time resolution (= 0.5 ps) of the experiment and decays with two exponential time constants, 4.8 ps and 132 ps. The ultrafast rise of the transient absorption is considered to be for shallowly trapped conduction band electrons after photoexcitation. The amplitude ratio of the two decaying components varies with the pump intensity and the decay times increase in the presence of hole scavengers. Even though a biexponential function fits the decay well, we object hat two independent first order processes (geminate and nongeminate recombinations) are responsible for the decay. A function with an integrated rate equation for second order nongeminate recombination plus a long background fits the decay well. The long background is considered to be for deeply trapped charges at the CdS particle.

• 상하수도학회지
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• 제30권1호
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• pp.9-17
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• 2016

Disinfectant/oxidation process is a crucial process in water treatment for supplying safe drinking water. Chlorination is still widely used for water treatment area due to its effectiveness on microbial inactivation and economic feasibility. Recently, disinfection concern in marine environment is increasing, for example, movement of hazardous marine organism due to ballast water, marine environmental degradation due to power plant cooling water discharge, and increase of the amount of disinfectant in the offshore plant. It is needed to conduct the assessment of disinfectant behavior and the development of disinfectant prediction model in seawater. The appropriate prediction model for disinfectant behavior is not yet provided. The objective of the study is to develop chlorine decay model in seawater. Various model types were applied to develop the seawater chlorine decay model, such as first order decay model, EPA model, and two-phase model. The model simulation indicated that chlorine decay in seawater is influenced by both organic and inorganic matter in seawater. While inorganic matter has a negative correlation with the chlorine decay, organic matter has a positive correlation with the chlorine decay.

• Korean Chemical Engineering Research
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• 제52권1호
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• pp.75-80
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• 2014

The convective flow structures in the vapor phase on earth are shown to be single unicellular, indicating the solutally dominant convection is important. These findings reflect that the total molar fluxes show asymmetrical patterns in a viewpoint of interfacial distributions. With decreasing the gravitational level form $1g_0$ down to $1.0{\times}10^{-4}g_0$, the total molar fluxes decay first order exponentially. It is also found that the total molar fluxes decay first order exponentially with increasing the partial pressure of component B, PB (Torr) form 5 Torr up to 400 Torr. Under microgravity environments less than $1g_0$, a diffusive-convection mode is dominant and, results in much uniformity in front of the crystal regions in comparisons with a normal gravity acceleration of $1g_0$.

• Environmental Engineering Research
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• 제25권3호
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• pp.374-383
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• 2020

Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH₄) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH₄ generation rate constant (k) for bulk waste was 0.24 y-1. The the CH₄ generation potential (L0) values ranged 33.7-46.7 m3-CH₄ Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

• 대한환경공학회지
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• 제29권6호
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• pp.706-714
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• 2007

본 연구에서는 배급수계통에서 잔류염소와 THMs의 분포를 예측하는 방안을 제시하였다. 잔류염소와 THMs의 등의 수질변화에 대해 현장조사를 실시하였고, 수체와 관벽에 대한 잔류염소 감소계수와 THMs의 생성계수를 산출하여 관망해석에 의한 수질모델링에 적용하였다. 병실험을 통해 잔류염소 병렬 1차 수체 반응계수를 구하고, 5개 관벽 감소 모델을 비교 평가하여 1차 관벽 감소계수 산출하고 적용했을 때 잔류염소 현장 측정값과 관망 수질모델링에 의한 예측간의 평균절대오차 및 평균제곱근오차가 각각 0.03, 0.037 mg/L로 가장 작았다. 또한 병실험에 의한 THMs생성량을 비선형 회귀분석으로 1차 생성계수를 구하고 현장 측정값과 비교하였다. 그 결과, 9월의 현장 측정값과 예측값의 결정계수 $R^2$는 0.98, 11월에는 0.82로 예측이 가능하였다.