• Food Science and Preservation
• /
• v.18 no.3
• /
• pp.423-428
• /
• 2011

Inactivation kinetic data of Escherichia coli O157:H7, Listeria monocytogenes, Staphylococcus aureus, Salmonella Typhimurium, and Salmonella Enteritidis via treatment with aqueous chlorine dioxide treatment at a specific concentration were evaluated using the first-order kinetic and Weibull models. The Weibull model showed a better fit with the kinetic data than the first-order kinetic model. The survival curves after the aqueous chlorine dioxide treatment showed $t_R$ values(time required to reduce microbial populations by 90%) of 2.49 min for E. coli O157:H7 at 5 ppm, 1.47 min for L. monocytogenes at 5 ppm, 0.94 min for S. aureus at 5 ppm, 0.87 min for S. Typhimurium at 1 ppm, and 0.08 min for S. Enteritidis at 1 ppm, according to the Weibull model.

• The Korean Journal of Pesticide Science
• /
• v.9 no.3
• /
• pp.231-236
• /
• 2005

This study was conducted to determine the amounts of pesticide residues after treatment of criterion dose with 4 pesticides(tolclofos-m, folpet, procymidone, and triflumizole) under cultivated period and to compare the biological half-life of pesticides with 6 kinetic models(first, zero and second order kinetics, power function, elovich and parabolic model) and to establish proposed field tolerance using biological half-lives. Recovery of 4 pesticides form strawberry was ranged from 85.1 to 105.5%. For all of 4 pesticides, dissipation rate was over 73% at 5 days after application. Among 6 kinetic models, first order kinetic model (FO) was best fit to describe the relationship between residual pattern of pesticides and time. Therefore, half-lives were calculated by FO for establishing the field tolerance. These results showed that half-life should be calculated by comparative best fit kinetic model and field tolerance can help to prevent unacceptable agricultural products from marketing. It is good for both consumers and farmers having safe agricultural products and financial benefits, respectively.

• Journal of Korean Society of Water and Wastewater
• /
• v.25 no.6
• /
• pp.971-979
• /
• 2011

Palm Oil Mill Effluent (POME) is the mixed organic wastewater generated from palm oil industry. In this study, kinetic analysis with treating POME in an anaerobic hybrid reactor (AHR) was performed. Therefore, the AHR was monitored for its performances with respect to the changes of COD concentrations and hydraulic retention time (HRT). Batch tests were performed to find out the substrate removal kinetics by granular sludge from POME. Modified Stover Kincannon, First-order, Monod, Grau second-order kinetic models were used to analyze the performance of reactor. The results from the batch test indicate that the substrate removal kinetics of granular sludge is corresponds to follow Monod's theory. However, Grau second-order model were the most appropriate models for the continuous test in the AHR. The second order kinetic constant, saturation value constant, maximum substrate removal rate, and first-order kinetic constant were 2.60/day, 41.905 g/L-day, 39.683 g/L-day, and 1.25/day respectively. And the most appropriate model was Grau second-order kinetic model comparing the model prediction values and measured COD concentrations of effluent, whereas modified Stover-Kincannon model showed the lowest correlation.

• Journal of Environmental Science International
• /
• v.23 no.9
• /
• pp.1609-1618
• /
• 2014

In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.

• Korean Journal of Soil Science and Fertilizer
• /
• v.48 no.5
• /
• pp.413-420
• /
• 2015

Objective of this study was to investigate adsorption characteristics and kinetic models of $NH_4-N$ to biochar produced from rice hull in respective to mitigation of greenhouse gases. $NH_4-N$ concentration was analyzed by UV Spectrophotometer. For the experiment, the soil texture used in this study was sandy loam soil, and application rates of chemical fertilizer and pig compost were $420-200-370kgha^{-1}$ (N-P-K) and $5,500kgha^{-1}$ as recommended amount after soil test for corn cultivation. Biochar treatments were 0.2-5% to soil weight. Its adsorption characteristic was investigated with application of Langmuir isotherm, and pseudo-first order kinetic model and pseudo-second order kinetic model were used as kinetic models. Adsorption amount and removal rates of $NH_4-N$ were $39.3mg^{-1}$ and 28.0% in 0.2% biochar treatment, respectively. The sorption of $NH_4-N$ to biochar was fitted well by Langmiur model because it was observed that dimensionless constant ($R_L$) was 0.48. The maximum adsorption amount ($q_m$) and binding strength constant (b) were calculated as $4.1mgg^{-1}$ and $0.01Lmg^{-1}$ in Langmuir isotherm, respectively. The pseudo-second order kinetic model was more appropriate than pseudo-first order kinetic model for high correlation coefficient ($r^2$) of pseudo-second order kinetic model. Therefore, biochar produced from rice hull could reduce $N_2O$ by adsorbing $NH_4-N$ to biochar cooperated in sandy loam soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2004.09a
• /
• pp.219-222
• /
• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• Korean Journal of Food Science and Technology
• /
• v.33 no.1
• /
• pp.66-71
• /
• 2001

Kinetic parameters for the texture degradation of three varieties of sweet potato during heating were determined using two alternative methods, the biphasic model and the fractional conversion method. The texture degradation of sweet potatoes during heating could be expressed by two simultaneous first order reactions using the biphasic method, whose activation energies were ranged $71.0{\sim}75.1\;kJ/mol\;and\;48.4{\sim}59.6\;kJ/mol$ for the initial fast texture degradation reaction and the slow texture degradation reaction at a prolonged heating period, respectively. However, the whole texture degradation phenomena of sweet potatoes during heating could also be explained by a single first order reaction using the fractional conversion method. The activation energies were $67.5{\sim}75.3\;kJ/mol$, which were comparable with those of the first phase reaction for the texture degradation determined by the biphasic model. A kinetic compensation effect shown between the kinetic parameters determined by both methods indicates that both methods can be conveniently used to determine kinetic parameters for the texture degradation of sweet potatoes by heating.

• Bulletin of the Korean Chemical Society
• /
• v.18 no.11
• /
• pp.1199-1203
• /
• 1997

The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

• Membrane and Water Treatment
• /
• v.8 no.1
• /
• pp.73-88
• /
• 2017

Adsorption kinetics of aqueous ferric ion ($Fe^{3+}$) onto bio-natural rice grains (BRG) have been studied in a batch system. The influence of contact time (0-180 minutes), the dosage of BRG adsorbent (10, 20, 40, and $60gL^{-1}$), and ambient temperature (27, 37, 47, and $57^{\circ}C$) for the adsorption system have been reported. The equilibrium time achieved after 20 minutes of adsorption contact time. The maximum removal of ferric ion is 99% by using $60gL^{-1}$ of BRG, $T=37^{\circ}C$, and $50mgL^{-1}$ ferric ion solution. Adsorption kinetic and diffusion models, such as pseudo-first order, pseudo-second order, and Weber-Morris intra-particle diffusion model, have been used to describe the adsorption rate and mechanism of the ferric ion onto BRG surface. The sorption data results are fitted by Lagergren pseudo-second order model ($R^2=1.0$). The kinetic parameters, rate constant, and sorption capacities have been calculated. The new information in this study suggests that BRG could adsorb ferric ion from water physiosorption during the first 5 minutes. Afterward, the electrostatic interaction between ferric ion and BGR-surface could take place as a very weak chemisorptions process. Thus, there is no significant change could be noticed in the FTIR spectra after adsorption. I recommend producing BGR as a bio-natural filtering material for removing the ferric ion from water.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.24 no.11
• /
• pp.929-934
• /
• 2011

The adsorption kinetic study of ruthenium complex, N3, onto nanoporous titanium dioxide ($TiO_2$) photoanodes has been carried out by measuring dye uptake in-situ. Three simplified kinetic models including a pseudo first-order equation, pseudo second-order equation and intraparticle diffusion equation were chosen to follow the adsorption process. Kinetic parameters, rate constant, equilibrium adsorption capacities and related coefficient coefficients for each kinetic model were calculated and discussed. It was shown that the adsorption kinetics of N3 dye molecules onto porous $TiO_2$ obeys pseudo second-order kinetics with chemisorption being the rate determining step. Additionally the heterogeneous surface and the pore size distribution of porous $TiO_2$ adsorbents were also discussed.