• Title/Summary/Keyword: fire-retardant chemical

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Study on Property Modification with Fire Retardant Content in the Manufacture of Compounds for Cable Sheath (전선피복용 컴파운드의 제조에서 난연제의 첨가량에 따른 물성 변화 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.47-51
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    • 2019
  • The three different polymer compounds were manufactured with the three different fire retardant (silane coated magnesium dihydroxide) contents, 180, 200, 220 phr, for making cable sheath for ship industry. In the research, ethylene-vinylacetate, polyethylene as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, plasticizer, and other additives. In the evaluation. ΔT, Mooney viscosity, and tensile strength increased with the content of fire retardant. But it was found that too much fire retardant damaged aging resistance and cold resistance of the polymer compound.

Combustion and Mechanical Properties of Fire Retardant Treated Waste Paper-Waste Acrylic Raw Fiber Composite Board

  • Eom, Young Geun;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.3
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    • pp.1-10
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    • 2003
  • Shredded waste newspapers, waste acrylic raw fibers, and urea-formaldehyde (UF) adhesives, at 10% by weight on raw material, were used to produce recycled waste paper-waste acrylic raw fiber composite boards in laboratory scale experiments. The physical and mechanical properties of fire retardant treated recycled waste paper-waste acrylic raw fiber composite boards were examined to investigate the possibility of using the composites as internal finishing materials with specific gravities of 0.8 and 1.0, containing 5, 10, 20, and 30(wt.%) of waste acrylic raw fiber and 10, 15, 20, and 25(wt.%) of fire retardant (inorganic chemical, FR-7®) using the fabricating method used by commercial fiberboard manufacturers. The bending modulus of rupture increased as board density increased, decreased as waste acrylic raw fiber content increased, and also decreased as the fire retardant content increased. Mechanical properties were a little inferior to medium density fiberboard (MDF) or hardboard (HB), but significantly superior to gypsum board (GB) and insulation board (IB). The incombustibility of the fire retardant treated composite board increased on increasing the fire retardant content. The study shows that there is a possibility that composites made of recycled waste paper and waste acrylic raw fiber can be use as fire retardant internal finishing materials.

An Experimental Study on the Development of Fire-retardant Treated Wood for Construction (건축용 난연 목재 개발에 대한 실험 연구)

  • Seo, Hyun Jeong;Kim, Nam Kyun;Jo, Jeong Min;Lee, Min Chul
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.149-156
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    • 2017
  • This study investigates fire-retardant performances and combustion/thermal characteristics of fire-retardant treated wood by comparing them with those of fire-retardant untreated wood from the expreimental resutls of cone calorimeter and thermo-gravimetric(TG) analyzer. Hazardousness of combustion product gases for fire-retardant treated wood and untreasted wood were also observed from the results of internal finish material incombustibility test according to the Korea standard code of KS F 2271. In this study, we also tried to improve the fire retardant performance of wood by applying fire-retardant chemical composites, and to secure the fire safety performance in buildings. Red pine (Pinus densiflora) was selected as a test specimen because it is mostly used as a building material in Korea. Fire retardant chemical composites (FRCs) were prepared by mixing boron, phosphorous, and nitrogen species and treated by press-impregnation method. Water-based FRCs were composed of 3% boric acid($H_3BO_3$), 3% borax decahydrate($Na_2B_4O_7$), 8% ammonium carbonate($(NH_4)_2CO_3$), diammonium phosphate ($(NH_4)_2HPO_4$) varied from 10-30% and potassium carbonate($K_2CO_3$) varied from 10-30%. From the test results of cone calorimeter, TG analysis and gas hazard assessments, newly proposed were the optimal composition and production methods of FRCs which can sufficiently meet fire-retardant level 3 based on Korea law of construction. Thus, the FRCs, developed in this study, are anticipated to contribute to the improvement of fire safety and widespread of usage in wood as building materials.

Study on Property Change with a Fire Retardant Content in the Manufacture of Polymer Composites for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.118-122
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    • 2019
  • Four different polymer compounds were manufactured to make cable sheaths for the shipping industry. Two kinds of ethylene vinyl acetate (EVA) as the main matrix polymers and EVA-grafted maleic anhydride (EVA-g-MAH) as the coupling agent were selected for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with different contents of the fire retardant, silanecoated magnesium dihydroxide (S-MDH). In the rheology evaluation, the $t_{60}$ and ${\Delta}T$ values increased with increasing S-MDH contents. On the other hand, the tensile strength decreased with increasing S-MDH content due to a relative decrease in binder polymers. With increasing S-MDH content, fire resistance increased, but cold resistance showed no obvious enhancement due to the polar effect of vinyl acetate in EVA.

Study on Manufacture and Properties of Polymer Compounds for Cable Sheath (전선피복용 고분자 컴파운드의 제조 및 물성 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.1
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    • pp.42-47
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    • 2019
  • The four different polymer compounds were manufactured to make cable sheath for ship industry. Two kinds of ethylene-vinyl acetate (EVA) were selected as main matrix polymers for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with the contents of fire retardant, silane coated aluminum hydroxide (S-ATH). Rheology, Mooney viscosity, and tensile strength increased with S-ATH contents by reinforcing effect. With increasing fire retardant amount, fire resistance increased, but cold resistance didn't show an obvious enhancement due to polar effect of vinyl acetate in EVA.

Comparative Analysis of Flame Retardant Performance of Japanese Cypress Plywood Based on the Main Ingredients of Fire Retardant Paint (도료의 주성분에 따른 편백 합판의 방염성능 비교 분석)

  • Soo-Hee Lim;Ha-Sung Kong
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.61-66
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    • 2023
  • The purpose of this study is to compare and analyze the flame retardant performance of Japanese cypress(Chamaecyparis obtusa) plywood, commonly used in indoor decoration, furniture, and tableware, by treating it with three different fire retardants with different primary ingredients. The experiment was conducted in compliance with Article 31, Paragraph 2 of the Enforcement Decree of the Fire Facilities Installation and Management Act and Articles 4 and 7-2 of the Flame Retardant Performance Standards. After flame time, after glow time, char length, and char area were measured. As a result, first, after flame time was measured at 0 seconds regardless of whether the flame retardant treatment was applied. Second, after glow time was relatively long, measuring 22.7 seconds without treatment, which is likely due to the weak fire resistance and high concentration of carbon monoxide generated by the chemical characteristics of the Japanese cypress itself. Third, it was confirmed that the effects of the primary ingredient, phosphorus, in the flame retardant treatment varied depending on the technological development of the manufacturers of the same species of Japanese cypress plywood. In the future, it is expected that the results of this study will provide fundamental data to select flame retardant treatments that show high flame retardant performance according to the botanical characteristics of the wood.

An Experimental Study on the Fire Risk Assessment & Calculation Breakthrough Time through Permeation Test of Chemical Protective Clothing (화학보호복의 화재위험성 및 화학적 투과시험을 통한 파과시간산정에 관한 실험적 연구)

  • Ko, Jae-Sun;Park, Pyoung-Kyu
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.21-30
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    • 2010
  • We have test chemical resistance and flame retardant properties of chemical protective clothing Fabrics by the ASTM and ISO standard methods. The flame retardant test results show that polyethylene is poor in flame resistance but fluoroelastomer add to decabrom is excellent in flame resistance. Especially, nowadays heat protective clothing for firefighters, which is aluminized film layers laminated to aramid fabric, show the excellent flame resistance. However, the chemical resistance test results show that aluminium is high corrosive in 4M NaOH solution alone. The problem of corrosion can be overcome by employing multiple barrier film. Also, based on the result of flame retardant test, duel skin of polymer barrier film add to aluminum film and single skin of fluorinated rubber with flame retardant materials seems to be fit for the chemical protective clothing. Also the thermal protection and heat transfer test results show that TPP and HTI is increased assured that the continued study on fire risk assessment & chemical resistance of chemical protective clothing fabrics will contribute to the upgrade the performances of chemical protective clothing fabrics.

Fire Performance of the Wood Treated with Inorganic Fire Retardants

  • Son, Dong-Won;Kang, Mee-Ran;Kim, Jong-In;Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.5
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    • pp.335-342
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    • 2012
  • To prepare the eco-friendly fire retardant wood, Japanese red pine (Pinus densiflora), Hemlock (Tsuga heterophylla), and Radiata pine (Pinus radiata) were treated with inorganic chemicals, such as sodium silicate, boric acid, ammonium phosphate, and ammonium borate. Different combination and concentration of those chemicals were impregnated by vacuum/pressure treatment methods. The electron-beam treatment was used to increase the chemical penetration into the wood. The fire performance of the fire retardant treated wood was investigated. The penetration of chemicals into the wood was enhanced after electron beam treatment. Ignition time of the treated wood was the most effectively retarded by sodium silicate, ammonium phosphate, and ammonium borate. The most effective chemical combination was found at 50% sodium silicate and 3% ammonium borate, which satisfied flammability criteria for a fire retardant material in the KS F ISO 5660-1 standards.

A Study on the Flame Resistance and Combustion Characteristics of MDF Plywood (MDF합판의 방염 및 연소특성에 관한 연구)

  • Kim, In-Beom
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.256-260
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    • 2014
  • Interior of the building is used as a MDF plywood if there is a fire in order to delay the ignition, flame retardant paint, flame retardant solution and flame retardant film are being handled by the flame retardant. Combustion characteristics anf flame retardant performance results can be summarized as follows: General film with a sample showed that short of the criteria in terms of carbonation area, and the results of flame retardant paint, flame retardant solution and flame retardant film products satisfied the criteria. Toxic gases generated in the combustion process results in a film samples using a high incidence of carbon monoxide and the creation of a smoke could be seen. This confirm that is estimated that result from incomplete combustion of PVC film that attach, and displays high toxicity index and hazard class relatively.

An Evaluation of Flame and Fire Retardant Performance for Welding Blanket (용접 불티 차단막의 방염 및 난연성능 평가)

  • 이근원;권오승;하동명
    • Fire Science and Engineering
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    • v.15 no.2
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    • pp.53-58
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    • 2001
  • This study was undertaken to evaluate the performance of flame retardant for fire precaution from sparks at welding-cutting process in industry sites such as shipbuilding yard and chemical factory. As the results of the performance experiment, six kinds of welding blanket in samples that are used commercially had enough in the performance of flame retardant. Nevertheless, the performance to fire precaution un welding blanket shows that the coaling product of two kinds with fiber glass is not sufficient. The lower oxygen index to welding blanket is considered that it is more than 30 in domestic standard. We suggested that the performance improvement of flame retardant for welding blanket need continuously, and the guideline of the flame retardant to welding blanket should be considered and established.

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