• Fire Science and Engineering
• /
• v.29 no.6
• /
• pp.45-50
• /
• 2015

The flash point is one of the most important properties for characterizing the fire and explosion hazard of liquid solutions. In this study, a Tag open-cup apparatus was used to measure the flash points of two flammable binary mixtures, n-decane + n-octanol and acetic acid + n-butanol. The flash point temperature was estimated using the UNIFAC (Universal Functional Activity Coefficient) group contribution model and optimization method. The experimentally derived flash point was also compared with the predicted flash point. The two methods can estimate the flash point fairly well for the n-decane + n-octanol and acetic acid + n-butanol systems.

• Proceedings of the KIEE Conference
• /
• 2006.07a
• /
• pp.436-437
• /
• 2006

Porcelain insulators have generally been used in Korea but polymer insulators which are superior in that they are light weight, explosion proof, impact proof, economical with construction characteristics, have been in use for the 154kV transmission line since 1999 following a worldwide trend towards the reduced weight, simplification and compact usage of new material insulators. However there have been approximately 500 cases of forest fires in Korea, so the transmission lines that for the most part pass through mountainous areas have been highly effected and the highly polymerized compound polymer insulator has raised concern about reliability in cases of exposure to forest fires. Therefore for the reliability assessment of the effect of forest fires on polymer insulators, mechanical and electrical characteristics are analyzed by an artificial flare test device and transmission facility surrounding conditions along with forest fire characteristics are surveyed. In addition to this, actual 90kV energized transmission line was tested with an artificial forest fire and the expanded usage of polymer insulators is presented through the analysis of mechanical and electrical characteristics and physical properties, and a study on the influence of forest fires on polymer insulators.

• Fire Science and Engineering
• /
• v.27 no.5
• /
• pp.70-74
• /
• 2013

The flash point is one of the most important physical properties to charaterize fire and explosion hazard of liquid solutions. The maximum flash point of liquid mixture is larger than those of the individual components. In this study, the flash points of 2-pentanol+acetic acid system were measured by Seta flash closed cup tester. This system exhibited the maximum flash point behavior. The flash points were estimated by the Raoult's law and the optimization methods using the van Laar and Wilson equations. The calculated values by optimization methods were found to be better than those based on the Raoult's law.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.61 no.8
• /
• pp.1148-1152
• /
• 2012

The vegetable-based insulating oils are substitutes for mineral oils in oil-filled transformer. The important properties of vegetable insulating oil is their higher flash/fire point and biodegradability than conventional mineral oils. The large oil-filled transformer eliminate the risk of explosion and fire should the transformer fail and oil ignite owing to high flash/fire point of vegetable insulating oil. In addition, higher biodegradability of vegetable insulating oils can let the oil spill damage reduced. In this experiment, the real oil-filled transformers using mineral oil and vegetable oil have accelerated aging. After working on the 100% accelerated aging experiment were conducted comparing the transformer. The hottest-spot temperature using thermal coefficients were calculated to determin the degree of accelerated aging. As a result, apply mineral oil transformer in accordance with the accelerated aging life come to an end. In contrast, vegetable insulating oils showed the opposite characteristics. Vegetable insulating oil compared to the mineral oil are found to be an long life. As a result, the vegetable oil has a long-term stability.

• Structural Engineering and Mechanics
• /
• v.80 no.6
• /
• pp.701-709
• /
• 2021

The paper aims at improving the understanding and mitigating the effects of tunnel fires that may breakout due to the burning fuel and/or explosion within the tunnel. This study particularly focuses on the behavior of the commonly used horse shoe geometry of tunnel systems. The problem has been obtained using an adequate well-established program incorporating the Lagrangian approach. A transient-thermo-coupled static structural analysis is carried out. The effects of radiation and convection to the outer walls of the tunnel is studied. The paper also presents the impact of the hazard on the structural integrity of the tunnel. A methodology is proposed to study the tunnel fire using a model which uses equivalent steel sheet to represent the presence of reinforcements to improve the computational efficiency with adequate validation. A parametric study has been carried out and the effect of suitable lining property for mitigating the fire hazard is arrived at. Detailed analysis is done for the threshold limits of the properties of the lining material to check if it is acceptable in all aspects for the integrity of the tunnel. The study may prove useful for developing insights for ensuring tunnel fire safety. To conduct such studies experimentally are tremendously costly but are required to gain confidence. But, scaled models, as well as loading and testing conditions, cannot be studied by many trials experimentally as the cost will shoot up sharply. In this context, the results obtained from such computational studies with a feasible variation of various combinations of parameters may act as a set of guidelines to freeze the adequate combination of various parameters to conduct one or two costly experiments for confidence building.

• Korean Chemical Engineering Research
• /
• v.55 no.2
• /
• pp.190-194
• /
• 2017

The combustion properties for the prevention of the fire and explosion in the work place are flash point, explosion limit, autoignition temperature (AIT) etc.. The using of the corrective combustion properties of the MSDS (Material Safety Data Sheet) of the handling substance for the chemical process safety is very important. For the safe handling of benzyl alcohol which is widely used in the chemical industry, the flash point and the AIT were measured. And, the lower explosion limit (LEL) of benzyl alcohol was calculated by using the lower flash point which obtained in the experiment. The flash points of benzyl alcohol by using the Setaflash and Pensky-Martens closed-cup testers measured $90^{\circ}C$ and $93^{\circ}C$, respectively. The flash points of benzyl alcohol by using the Tag and Cleveland open cup testers are measured $97^{\circ}C$ and $100^{\circ}C$. The experimental AIT of benzyl alcohol by ASTM 659E tester was measured as $408^{\circ}C$. The LEL of benzyl alcohol measured by Setaflash closed-cup apparatus was calculated as 1.17 vol% at $90^{\circ}C$. In this study, it was to possible predict the LEL by using the lower flash point of benzyl alcohol which measured by Setaflash closed-cup tester.

• Journal of the Korean Institute of Gas
• /
• v.9 no.2 s.27
• /
• pp.1-7
• /
• 2005

The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.35 no.4
• /
• pp.439-445
• /
• 2011

Forensic Engineering is the art and science of professionals qualified to serve as engineering experts in courts of law or in arbitration proceedings. Buses using compressed natural gas (CNG) trend to be extended in use internationally as optimal counterplan for reducing discharge gas of light oil due to high concern about environment. However, CNG buses have to be equipped with composite pressure vessels (CPVs); since the CPVs contain compressed natural gas, the risks in the case of accident is very high. Hence, the investigation of such accidents is usually associated with engineering analysis. Among the possible reasons for such CNG explosion accidents is vehicle fire and vessel fracture. By conducting formal inspection and engineering tests, in this study, the cause of vessel explosion is investigated by analyzing the failure mechanism by fractography and by comparing the material properties of a reference part with those of a problem part by adopting instrumented indentation technique.

• Korean Chemical Engineering Research
• /
• v.43 no.1
• /
• pp.181-185
• /
• 2005

The flash point is one of the most important combustible properties used to determine the potential for fire and explosion hazards of industrial material. An accurate knowledge of the flash point is important in developing appropriate preventive and control measures in industrial fire protection. The flash points for the n-butanol+n-propionic acid and n-propanol+n-propionic acid systems were measured by using Tag open-cup apparatus(ASTM D 1310-86). The experimental data were compared with the values calculated by the laws of Raoult and van Laar equation. The calculated values based on the van Laar equation were found to be better than those based on the Raoult's law.

• Journal of Ocean Engineering and Technology
• /
• v.25 no.3
• /
• pp.66-72
• /
• 2011

This is the fourth of a series of companion papers dealing with the mechanical property reductions of various marine structural steels. Even though a reduction of the elastic modulus according to temperature increases has not been obtained from experiments, high temperature experiments from room temperature to $900^{\circ}C$ revealed that initial the yield strength and tensile strength are both seriously degraded. The mechanical properties obtained from high temperature experiments are compared with those from EC3 (Eurocode 3). It is found that the high temperature test results generally comply with the prediction values by EC3. Based on the prediction of EC3, time domain nonlinear finite element analyses were carried out for a blast wall installed on a real FPSO. After applying the reduced mechanical properties, corresponding to $600^{\circ}C$ to the FE model of the blast wall, more than three times the deflections were observed and it was observed that most structural parts experience plastic deformations exceeding the reduced yield strength at the high temperature. It is noted that a protection facility such as PFP (passive fire protection) should be required for structures likely to be directly exposed to fire and explosion accident.