• 한국분말재료학회지
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• 제24권1호
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• pp.24-28
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• 2017

Silicon alloys are considered promising anode active materials to replace Li-ion batteries by graphite powder, because they have a relatively high capacity of up to 4200 mAh/g, and are environmentally friendly and inexpensive ECO-materials. However, its poor charge/discharge properties, induced by cracking during cycles, constitute their most serious problem as anode electrode. In order to solve these problems, Si-Ge-Al alloys with porous structure are designed as anode alloy powders, to improve cycling stability. The alloys are melt-spun to obtain the rapidly solidified ribbons, and then ball-milled to make fine powders. The powders are etched using 1 M HCl solution, which gives the powders a porous structure by removing the element Al. Subsequently, in this study, the microstructures and the characteristics of the etched powders are evaluated for application as anode materials. As a result, the etched porous powder shows better electrochemical properties than as-milled Si-Ge-Al powder.

• 한국재료학회지
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• 제30권2호
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• pp.74-80
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• 2020

Synthesis of composite powders for the Fe₂O₃-Zn system by mechanical alloying (MA) has been investigated at room temperature. Optimal milling and heat treatment conditions to obtain soft magnetic composite with fine microstructure were investigated by X-ray diffraction, differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM) measurement. It is found that α-Fe/ZnO composite powders in which ZnO is dispersed in α-Fe matrix can be obtained by MA of Fe₂O₃ with Zn for 4 hours. The change in magnetization and coercivity also reflects the details of the solid-state reduction process of hematite by pure metal of Zn during MA. Densification of the MA powders was performed in a spark plasma sintering (SPS) machine at 900 ~ 1,000 ℃ under 60 MPa. Shrinkage change after SPS of sample MA'ed for 5 hrs was significant above 300 ℃ and gradually increased with increasing temperature up to 800 ℃. X-ray diffraction results show that the average grain size of α-Fe in the α-Fe/ZnO composite sintered at 900 ℃ is in the range of 110 nm.

• 한국재료학회지
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• 제16권10호
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• pp.633-638
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• 2006

Silica powders with spherical shape and narrow size distribution were prepared by large-scale ultrasonic spray pyrolysis applying the droplet classification apparatus. On the other hand, silica powders prepared by large-scale ultrasonic spray pyrolysis without droplet classification apparatus had broad size distribution. Droplet classification apparatus used in this paper applied the principles of cyclone and dispersion plate with small holes. The droplets formed from the ultrasonic spray generator applying the droplet classification apparatus had narrow size distribution. The droplets with fine and large sizes were eliminated by droplet classification apparatus. The optimum flow rate of the carrier gas and diameter of the hole of the dispersion plate were studied to reduce the size distribution of the silica powders prepared by large-scale ultrasonic spray pyrolysis. The size distribution of the silica powders prepared by large-scale ultrasonic spray pyrolysis at the optimum preparation conditions was 0.76.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.794-795
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• 2006

Metal powder for dust core application was developed. The powder can be produced improved high-pressure water atomization process. The process has produced powder of spherical shape and lower coercivity. The dust core obta ined shows lower core loss.

• Korean Chemical Engineering Research
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• 제48권1호
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• pp.75-79
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• 2010

에틸렌디아민테트라아세트산, 구연산 및 $NH_4Cl$ 융제가 첨가된 분무용액으로부터 분무열분해법에 의해 얇은 막 구조의 전구체 분말들을 합성하였다. $1,200^{\circ}C$에서 소성 과정을 거친 유기 첨가제와 융제를 사용하지 않은 $BaMgAl_{10}O_{17}:Eu$ 형광체는 $1{\sim}5{\mu}m$ 크기의 구형이며, 두꺼운 막 형태의 속이 빈 구조를 가졌다. 반면에 에틸렌디아민아세트산과 구연산을 첨가하여 합성된 BAM:Eu 형광체는 판상 구조의 미세한 크기를 가졌다.$NH_4Cl$ 융제의 첨가량이 0, 6, 35 wt%일때 합성된 미세 형광체들의 결정자 크기는 각각 23, 35, 33 nm였다. 최대의 발광 세기를 나타내는 최적의 융제 첨가량은 형광체의 35 wt%였으며, 융제를 첨가하지 않은 분무용액으로부터 합성된 형광체의 발광 세기의 215%였다.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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• pp.151-163
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• 2000

A polymerized organic-inorganic complexation route is introduced for the synthesis of oxide ceramic powders. Polyvinyl alcohol was used as the organic carrier for precursor ceramic gel. Porous and soft powders, which have a high specific surface area, were obtained after calcinating the aerated precursors. The PVA content and its degree of polymerization had a significant influence on the homogeneity of the final powder. In particular, attrition milling process with the porous powder resulted in ultra-fine particles. In the case of the preparation of cordierite powder, nano-size powder, which has a high specific surface area of 181 ㎡/g, was obtained by the milling process. The complexation route was also applied to the synthesis of unstable phase in room temperature like beta-cristobalite, high temperature form of silica.

• 한국세라믹학회지
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• 제26권5호
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• pp.691-697
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• 1989

Fine TiO2 and BaTiO3 powders having spherical particles were synthesized by ultrasonic spray pyrolysis of alcoholic solution of metal alkoxide in an electric furnace heated at 400-90$0^{\circ}C$. Microstructure and composition of particles synthesized were observed by TEM and XRD respectively. Spectific surface area of powders synthesized was examined through BET specific surface area measurement. TEM observation revealed that the particle size did not change irrespective of pyrolysis temperature but decreased according to the increase of concentration and spherical particle was consisted of primary particles of about 0.02${\mu}{\textrm}{m}$. As for BaTiO3 powder, the ratio of Ti/Ba was 0.987 by EDX analysis.

• 한국세라믹학회지
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• 제25권4호
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• pp.357-363
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• 1988

Ccompaction and sintering behavior of highly pure PSZ powders were investigated by laying the stress on the granulation processes. The particle size of coprecipitated PSZ powder was so fine that the agglomeration was severely formed during drying and calcing step and by this agglomeration differential sinering was occurred. The methanol dispersion of precipitates was the good method of avoiding severe agglomeration formed during drying process because of small surface tension than water. But perfect deagglomeraton was not possible due to high surface area of powders. So homogenization by granulation was needed, and among the method spray granulation was the most desirable to obtain homogeneous compacts and subsequent flaw-free ceramics.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.93-93
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• 2003

Tungsten and tungsten heavy alloys have widespread application as radiation shielding devices and heavy duty electrical contacts. High density and good room temperature mechanical properties have generated interest in evaluating tungsten and tungsten alloys as kinetic energy penetrators against armor. Nowdays ultra fine-grained tungsten powders are in great interest because higly dense structures can be obtained at low temperature, pressure and lower sintering time. Several physical md chemical methods are available for the synthesis of nanometric metal Powders: ball milling, laser abalation, vapor condensation, chemical precipitation, metallic wire explosion i.e. However production rates of the above mentioned methods are low and further efforts are needed to find out large-scale synthesis methods. From this point of view solid state combustion method ( known as SHS) represents undoubted interest.

• 한국세라믹학회지
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• 제30권3호
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• pp.215-221
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• 1993

The Hydroxyapatite powders were prepared by Wet-direct and Hydrothermal synthesis using Ca(NO3)2.4H2O and (NH4)2.HPO4.Stoichiometric and good cristalline HAp powders were obtained 9$0^{\circ}C$ by wet-direct process. The aspect ratio of HAp powders prepared by hydrothermal synthesis was increased with increasing synthetic temperature. The HAp particles obtained at 20$0^{\circ}C$ for 10hr were needle shaped ultra fine crystals, about 100nm in size. Small amount of TCP was obtained above 80$0^{\circ}C$ after heat-treatment of hydrothermally synthesized HAp but good crystalline HAp phase was maintained up to 120$0^{\circ}C$ as the primary phase.