• Title/Summary/Keyword: fine particle components

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Major factors determining the size distributions of atmospheric water-soluble aerosol particles at an urban site during winter (겨울철 도시지역 대기 수용성 에어로졸 입자의 크기 분포를 결정하는 주요 인자)

  • Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.3
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    • pp.43-54
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    • 2021
  • Size distributions of atmospheric particulate matter (PM) and its water-soluble organic and inorganic components were measured between January and February 2021 at an urban site in Gwangju in order to identify the major factors that determine their size distributions. Their size distributions during the study period were mainly divided into two groups. In the first group, PM, NO3-, SO42-, NH4+ and water-soluble organic carbon (WSOC) exhibited bi-modal size distributions with a dominant condensation mode at a particle size of 0.32 ㎛. This group was dominated by local production of secondary water-soluble components under atmospheric stagnation and low relative humidity (RH) conditions, rather than long-range transportation of aerosol particles from China. On the other hand, in the second group, they showed tri-modal size distributions with a very pronounced droplet mode at a diameter of 1.0 ㎛. These size distributions were attributable to the local generation and accumulation of secondary aerosol particles under atmospheric conditions such as atmospheric stagnation and high RH, and an increase in the influx of atmospheric aerosol particles by long-distance transportation abroad. Contributions of droplet mode NO3-, SO42-, NH4+ and WSOC to fine particles in the second group were significantly higher than those in the first group period. However, their condensation mode contributions were about two-fold higher in the first group than in the second group. The significant difference in the size distribution of the accumulation mode of the WSOC and secondary ionic components between the two groups was due to the influx of aerosol particles with a long residence time by long-distance transport from China and local weather conditions (e.g., RH).

Dry Coated Particle for Plasma Spraying

  • Briones-Rodriguez, C.;Mayagoitia-Barragan, V.;Cuenca-Alvarez, R
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.156-157
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    • 2006
  • The preparation of composite powders for plasma spraying by an in-house designed mechanofusion process is investigated. Results show that dry particle coating depends on the chemical and mechanical properties of powders. In metal/oxide and metal/oxide/carbide powder mixtures, fine ceramic particles coat the surface of the metallic coarser particles. A nearly rounded shape of the final composite particles is induced by the mechanical energy input with no formation of new phases. However with the carbide/metal powdered system, only an intimate mixture of components is achieved. It is suggested that the coating mechanism is governed by agglomeration and rolling phenomena.

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The influences of coating components and structures on ink absorbency (도공층 조성 및 구조의 잉크흡수성에 대한 영향)

  • 곽상효;김진현
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.7-16
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    • 1999
  • The aim of this research was to evaluate the influences of coating components and structures on ink absorbency. The ink absorbency was measured as porosity, K&N ink absorption, gloss and ink set-off. In order to obtain the relationship between the coating structure and the ink absorbency, the binder level was adjusted and two types of pigments were examined. One of the pigments was known to make the porous coating structure and the other one had strong ink affinity. The effects of coating components were studied by applying six different types of latex and various additives . In this research, CLC(cylindrical laboratory coater) and Prufbau printability tester were used. It was found that the decreasing latex dosage and introducing porous pigment were effective solutions to increase ink absorbency. However, the ink absorbency could not be improved by applying the fine pigment even though it had strong ink affinity. Among the characters of the latex, particle size and surface tension were found to have the strong effect on ink absorbency. The ink absorbency increased with large particle size and low surface tension latex. The additives were varied and it was found that applying to the top coating was effective.

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Size Distribution of Water-Soluble Ionic Components in the Atmospheric Aerosols Collected in Jeju City, Korea (제주시 대기부유부진 중 수용성 이온성분의 입경별 분포특성)

  • Hu Chul-Goo;Song Jeong-Hwa;Lee Ki-Ho
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1067-1078
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    • 2004
  • Atmospheric particulate matters were collected by 8-stage non viable cascade impactor from October 2002 to August at Jeju City. Eight water-soluble ionic components $(Na^+,\;NH_{4}_{+},\;K^+,\;Ca{2+},\;Mg^{2+},\;CI^-,\;NO_{3}^-\;and\;SO_{4}^{2-})$ were analyzed by Ion Chromatography. The concentration of particulate matters and eight water-soluble ionic components were determined to investigate their size distributions. Particulate matters exhibited a tri-modal distribution with peak value around $0.9,\;4.0{\mu}m\;and\;9.5{\mu}m.$ In summer, the last peak value was lower than other season values likely due to particulate matter scavenged by rain water. Four ionic components $(Na^+,\;Ca^{2+},\;Mg^{2+}\;and\;CI^-)$ exhibited a bi-modal distribution in the coarse mode whereas three ionic components $(NH_{4}^+,\;K^+\;and\;SO_{4}^{2-})$ in the fine mode, with maximum peak value around $0.9{\mu}m.\;NO_{3}^-$ was found in both the coarse and the fine mode. The enrichment factor (E.F.) of each ionic components was calculated. Based upon E.F., it is considered that $Na^+,\;CI^-,\;and\;K^+$ in coarse paricle mode were delivered form oceanic source, but other components might have other source origins.

A Study on Utility for Fine Aggregates and Engineering Characteristics by Mineralogical Composition of Sands on the Coast of Jeju Island (제주 해안지역 모래의 광물성분에 기인한 공학적 특성 및 잔골재 활용방안 연구)

  • Kim, Seung Hyun;Lee, Dong Wook
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.4
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    • pp.57-68
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    • 2014
  • This study categorizes the distributed sand around coastal area of Jeju volcanic Island into three groups according to their components, and arranges their characteristics. In the case of basic physical properties, the silicate sand has slightly greater specific gravity than general sand, and the carbonate sand with widespread distribution has a lower specific gravity. In the gross, the carbonate sand has poor particle classifying and low uniformity coefficient because carbonate minerals of relatively large grain size are mixed. The relation between compressive strength and components shows conflicting tendency that silicate and carbonate components have positive correlation and negative correlation with compressive strength, respectively. Based on the components ratio of one to one, the sand having low carbonate component ratio is expected to be able to utilize in construction fine aggregate. To compare between square root (ACI 308) and cube root (KCI 2012) of compressive strength at computation of elastic modulus, it is considered to non-dimensional elastic modulus.

Sampling and Analysis of Acidic Air Pollutants Using an Annular Denuder System during the Summer Season in Chongju City (디누더 측정기를 이용한 여름철 청주시의 산성오염물질 측정과 분석)

  • 이학성;강병욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.441-448
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    • 1996
  • The cyclone/annular denuder system/filter pack sampling system (ADS) was used to collect the acidic air pollutants in Chongju city. The data set was collected on nine different days with 24 hour sampling period from July 27 through August 27, 1995. The chemical species measured were $HNO_3, HNO_2, SO_2 and NH_3$ in the gas phase, and $PM_{2.5}(d_P<2.5 \mum), SO_4^{2-}, NO_3^- and NH_4^+$ in the particulate phase. Mean concentrations measured from this study were: $0.90 \mug/m^3 for HNO_3, 1.27 \mug/m^3 for HNO_2, 10.9 \mug/m^3 for SO_2, 4.82 \mug/m^3 for NH_3, 27.5 \mug/m^3 for PM_{2.5}, 5.24 \mug/m^3 for SO_4^{2-}, 1.22 \mug/m^3 for NO_3^-, and 1.64 \mug/m^3 for NH_4^+$. The fine particle $(PM_{2.5})$ mass measured for the ADS samples was slightly higher than the fine particle mass measured for the corresponding dichotomous sampler. For the wind coming from Chongju industrial complex the concentrations of acidic air pollutants measured were higher when compared with other directions. Specially, $SO_2 and PM_{2.5}$ concentrations for the wind coming from Chongju industrial complex were 3.6 and about 2 times, respectively, higher than those of other wind directions. High correlations were observed between $PM_{2.5} and fine particle's ion components $(r=0.82 with SO_4^{2-}, r=0.76 with NO_3^- and r=0.89 with NH_4^+). NH_4^+ and SO_4^{2-}$ was also highly correlated (r=0.97).

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Characterization of Wintertime Atmospheric Aerosols in Seoul Using PIXE and Supplementary Analyzers

  • Ma, Chang-Jin;Mikio Kasahara;Hwang, Kyung-Chul;Yeo, Hyun-Gu;Park, Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.E
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    • pp.19-27
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    • 2000
  • Particle Induced X-ray Emission (PIXE) and Elemental Analysis Syztem (EAS) were applied to the investiga-tion of the Characteristics and sources of wintertime atmospheric aerosols in Seoul. Atmospheric aerosols were collected by both fine and coarse fractions using a two-stage filter pack sampler from Kon-Kuk university during the winter season of 1999. PIXE was applied to the analysis of the middle and heavy elements with atomic numbers greater than 14(Si) and EAS was applied to the measurement of the light elements such as H, C and N. The fact that 64.2% of mass of fine particles in Seoul consists of the light elements (N, C , and H) suggests that the measurement of light elements is extremely important. The average mass concentration is Seoul was 38.6$\mu\textrm{g}$m(sup)-3. Elements such as Ca, Fe, Mg, and Ti appeared to have very low Fine/Coarse ratios(0.1∼0.4), whereas che-mical components related to anthropogenic sources such as Br, V, Pb, and Zn were observed to accumulate in the fine fraction. In the Asian Dust Storm(ADS) event, the concentation of soil components increased dramatically. Reconstruction of the fine mass concentrations estimated by a newly revised simple model was fairly in good agreement with the measured ones. Source identification was attempted using the enrichment factor and Pearsons coefficient of correlation. The typical elements derived from each source could be classified by this method.

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Effect of Ball milling Time on Graphite Dispersion and Mechanical Properties in Rapidly Solidified 6061 Al Composite (급속응고 6061Al/Graphite 복합재료의 볼밀링 시간에 따른 흑연 분산거동 및 기계적 특성)

  • Son, Hyeon-Taek;Lee, Jae-Seol;Hong, Soon-Jik;Chun, Byong-Sun
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.209-216
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    • 2009
  • A composite of rapidly solidified Al-6061 alloy powder with graphite particle reinforcements was prepared by ball milling and subsequent hot extrusion. The microstructure and mechanical properties of these composites were investigated as a function of milling time. With increasing milling time, the gas atomized initially and spherical powders became elongated with a maximum aspect ratio after milling for 30 h. Then, refinement and spheroidization were achieved by further milling to 70 h with a homogeneous and fine dispersion of graphite particles forming between the matrix alloy layers. The best compression and wear properties were obtained in the powder milled for 70 h, associated with the increased fine and homogeneous distribution of graphite particles in the aluminum alloy matrix.

Size-segregated mass and ion concentrations of atmospheric aerosols in Cheonan City between 2006 and 2007 (2006~2007년 천안시 대기 에어로졸의 입경별 농도 및 이온성분 특성)

  • Lee, Hyung-Bae;Oh, Se-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1349-1353
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    • 2008
  • Size-segregated mass and ion concentrations of atmospheric aerosols in Cheonan City were measured using a high volume air sampler equipped with a 5-stage cascade impactor and a ion chromatography between March 2006 and April 2007. The mean values of 24-hr average concentrations of TSP, PM10, PM2.5, and PM1 were 61.7, 55.2, 43.7, $33.2{\mu}g/m^3$, respectively. Mass size distributions of atmospheric aerosols were bimodal distributions with a saddle point in $1.5\;{\sim}\;3.0{\mu}m$ range in diameter separating coarse and fine particle modes. Fine particles, PM2.5 were 70.8% of the total mass of aerosols. Major ion components in aerosols were ${NH_{4}}^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$ for cations, and ${SO_{4}}^{2-}$, ${NO_{3}}^-$, $Cl^-$ for anions. ion components occupied 37.4% of coarse particles and 46.2% of fine particles in mass.

Characterization of Chemical Composition and Size Distribution of Atmospheric Aerosols by Low-Pressure Impactor (저압 임팩터를 이용한 대기 에어로졸 입자의 입경분포 측정과 화학조성 자료의 해석)

  • 박정호;최금찬
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.6
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    • pp.475-486
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    • 1997
  • The characteristics of atmospheric aerosols were investigated as a function of particle size and water solubility. The atmospheric aerosols were sampled with classifying into 12 size ranges by the use of Andersen low-pressure impactor. Collected aerosol particles were extracted by ultrapure water and filtered to be separated into water-soluble and insoluble components. The concentrations 12 elements in both components were determined by PIXE analysis. And the concentrations of 8 ions in the soluble component were analyzed by ion chromatography. In general, the mass size distribution of particulate matter was represented as a bimodal distribution. The mass size distributions of S$(SO_4^{2-}), K(K^+), Zn and NH_4^+$ skewed to the smaller size range and those of Si, Ca$(Ca^{2+}), Fe, Na^+ and Mg^{2+}$ skewed to the larger size range. They had roughly one peak in the fine and coarse particle region,respectively. On the other hand, the mass size distribution of Ti, Mn, Ni, Cu, $Cl^- and NO_3^-$ were represented as the bimodal distribution. Fe and Si in the aerosol particles extracted into pure water are existing in high insoluble state. Conversely, almost the whole of S is dissolved in water.

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