• 제목/요약/키워드: filler content ratio

검색결과 85건 처리시간 0.03초

흑연과 탄소나노튜브 함유 아크릴 복합체 박막의 방열 특성 (Thermal Dissipation Property of Acrylic Composite Films Containing Graphite and Carbon Nanotube)

  • 김준영;강찬형
    • 한국표면공학회지
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    • 제50권3호
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    • pp.198-205
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    • 2017
  • Thermal dissipation was investigated for poly methyl methacrylate (PMMA) composite films containing graphite and multi wall carbon nanotube(CNT) powders as filler materials. After mixing PMMA with fillers, solvent, and dispersant, the pastes were prepared by passing through a three roll mill for three times. The prepared pastes were coated $15{\sim}40{\mu}m$ thick on a side of 0.4 mm thick aluminium alloy plate and dried for 30 min at $150^{\circ}C$ in an oven. The content of fillers in dried films was varied as 1, 2, and 5 weight % maintaining the ratio of graphite and CNT as 1:1. Raman spectra from three different samples exhibited D, G and 2D peaks, as commonly observed in graphite and multi wall CNT. Among those peaks, D peak was prominent, which manifested the presence of defects in carbon materials. Thermal emissivity values of three samples were measured as 0.916, 0.934, and 0.930 with increasing filler content, which were the highest ever reported for the similar composite films. The thermal conductivities of three films were measured as 0.461, 0.523, and $0.852W/m{\cdot}K$, respectively. After placing bare Al plate and film coated samples over an opening of a polystyrene box maintained for 1 h at $92^{\circ}C$, the temperatures inside and outside of the box were measured. Outside temperatures were lower by $5.4^{\circ}C$ in the case of film coated plates than the bare one, and inside temperatures of the former were lower by $3.6^{\circ}C$ than the latter. It can be interpreted that the PMMA composite film coated Al plates dissipate heat quicker than the bare Al plate.

음이온교환막 연료전지를 위한 TiO2 함량 조절에 따른 QPAE/TiO2-x 복합막의 치수안정성 및 이온전도도 동시 개선 연구 (Simultaneous Improvement of Dimensional Stability and Ionic Conductivity of QPAE/TiO2-x Composite Membranes According to TiO2 Content Control for Anion Exchange Membrane Fuel Cells)

  • 김상희;유동진
    • 한국수소및신에너지학회논문집
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    • 제33권1호
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    • pp.19-27
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    • 2022
  • A series of QPAE/TiO2-x (x = 1, 4, 7 and 10 wt%) organic/inorganic composite membranes were prepared as electrolyte membranes for alkaline anion exchange membrane fuel cells by controlling the content of inorganic filler with quaternized poly(arylene ether) (QPAE) random copolymer. Among the prepared QPAE/TiO2-x organic/inorganic composite membranes, the highest ionic conductivity was 26.6 mS cm-1 at 30℃ in QPAE/TiO2-7 composite membrane, which was improvement over the ionic conductivity value of 6.4 mS cm-1 (at 30℃) of the pristine QPAE membrane. Furthermore, the water uptake, swelling ratio, ionic exchange capacity, and thermal property of QPAE/TiO2-x composite membranes were improved compared to the pristine QPAE membrane. The results of these studies suggest that the fabricated QPAE/TiO2-x composite membranes have good prospects for alkaline anion exchange membrane fuel cell applications.

고무 복합재료의 압저항 효과 (Rubber Composites with Piezoresistive Effects)

  • 정준호;윤주호;김일;심상은
    • Elastomers and Composites
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    • 제48권1호
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    • pp.76-84
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    • 2013
  • 압저항 효과(piezoresistive effect)는 가해진 외부 압력이나 힘에 의해 전기적 저항이 변하는 것을 말한다. 이러한 압저항 효과는 압력, 진동, 가속 등을 탐지하는 센서에 많이 이용되고 있다. 압저항 효과를 갖는 재료가 많지만 그 중에서도 특히, 전도성 충전제를 첨가한 고무 복합체는 충전제의 종류, 입자 크기, 입자 모양, 입자 종횡비(aspect ratio), 그리고 입자의 양 등을 조절하여 다양한 압력 범위에서의 압저항 효과를 발현할 수 있고, 고무를 기질로 사용함으로써 복합체에 탄성과 유연성을 줄 수 있기 때문에 많은 관심을 받고 있다. 본 논문에서는 압저항 효과의 기본원리 및 다양한 고무 복합체의 압저항 효과에 대해 알아본다.

현무암 석분슬러지를 채움재로 활용한 개질재생아스팔트혼합물과 일반아스팔트혼합물의 공용성 평가 (Evaluation of Performance of Modified Recycling Asphalt Mixture and Normal Asphalt Mixture Using Basalt Powder Sludge as Filler)

  • 김승현;이동욱
    • 대한토목학회논문집
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    • 제38권4호
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    • pp.611-619
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    • 2018
  • 현무암 석분슬러지는 석재가공 과정에서 필연적으로 발생하는 산업부산물이다. 최근 건축 및 조경분야에서 천연자재에 대한 수요가 증가하고 있어 석분슬러지 발생량도 증가하고 있다. 현무암 석분슬러지는 현재 발생량의 대부분이 단순 매립과 복토용으로 처리되고 있어 활용성 제고를 위한 노력이 필요하다. 이에 본 연구에서는 제주지역의 강우특성을 고려해 현무암 석분슬러지를 시멘트와 섞어 아스팔트혼합물의 채움재로 활용하기 위한 검토를 수행하였다. 검토결과 현무암 석분슬러지는 KS F 3501에서 요구하는 품질기준을 만족하였다. 마샬 배합설계를 실시하여 개질재생아스팔트혼합물(순환골재 27%)과 일반아스팔트혼합물에 대한 최적 아스팔트 함량(OAC)을 결정하였다. 두 종의 아스팔트혼합물에 채움재의 혼합비(3 수준) 및 현무암 석분슬러지와 시멘트의 구성비(3 수준)를 변화시켜 마샬안정도 시험으로 현무암 석분슬러지의 활용 범위를 파악하였다. 채움재의 혼합비와 구성비가 안정적인 활용성을 보이는 아스팔트혼합물들에 대한 공용성을 평가한 결과 두 종의 아스팔트혼합물 모두 국토교통부(2015)의 품질기준을 만족하였다. 따라서 현무암 석분슬러지는 아스팔트혼합물의 채움재로 활용이 가능한 것으로 판단된다.

반응표면 분석방법에 의한 궐련지 제조 주요인자의 최적화 연구 (Optimization of some major factors in cigarette paper manufacturing using response surface analysis)

  • 김영호;이근회
    • 한국연초학회지
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    • 제11권2호
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    • pp.211-224
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    • 1989
  • 10. Three major factors, freeness, filler and blend ratio that exercised considerable influence on physical properties of cigarette papers were chosen for the sake of their optimization at this experiment. An optimization of those above factors in paper manufacturing was investigated using response surface analysis. Optimum beating degree for Kenaf, Flax and NBKP showed around 72。SR, 68。SR and 85 SR, respectively, in considering of five quality index such as porosity, tensile strength, stretch, whiteness and opacity. The best blending ration of reciprocal pulps treated under optimum beating degree were diversified and combination scope of the bast fiber (Kenaf, Flax) to the NBKP was range from 30% to 65% in case of the Kenaf, from 25 to 40% in Flax at the same receipe. The optimum range of calcium carbonate content revealed 25%~30% in Kenaf mixed NBKP and 24%~31% in Flax mixed NBKP.

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흡수열화에 따른 에폭시 복합체의 임펄스 절연파괴특성에 관한 연구 (A Study on the Impulse Breakdown Characteristics of Epoxy Composites due to Water Absorption Aging)

  • 이덕진;손인환;신성권;김명호;김경환;홍진웅;김재환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.156-159
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    • 2000
  • In this paper, the physical and electrical properties of epoxy composites are investigated at boiling absorption condition to observe the influences of moisture. Also, in order to improve water resistance of matrix resin, IPN method was introduced and the influence was investigated. In order to analyze the basic physical properties of samples, scanning electron microscopy method was utilized, and impulse voltage dielectric strength was measured. As a result, it was verified that, in case of IPN samples, the ratio of moisture absorption was decreased due to the improvement of adhesion strength, and impulse voltage dielectric strength of SN sample was degraded abruptly as boiling time and filler content were increasing, while IPN samples were slowly degraded due to the improvement of adhesion strength.

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Creq/Nieq비에 따른 AISI 304L 및 AISI 316L 스테인리스강 용접부의 미세조직 및 전기화학적 양극분극 평가 (Evaluations of Microstructure and Electrochemical Anodic Polarization of AISI 304L and AISI 316L Stainless Steel Weld Metals with Creq/Nieq Ratio)

  • 김연희;장아영;강동훈;고대은;신용택;이해우
    • 대한금속재료학회지
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    • 제48권12호
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    • pp.1090-1096
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    • 2010
  • This pitting corrosion study of welded joints of austenitic stainless steels (AISI 304L and 316L) has addressed the differentiating solidification mode using three newly introduced filler wires with a flux-cored arc welding process (FCAW). The delta ferrite (${\delta}$-ferrite) content in the welded metals increased with an increasing equivalent weight ratio of chromium/nickel ($Cr_{eq}/Ni_{eq}$). Ductility dip cracking (DDC) was observed in the welded metal containing ferrite with none of AISI 304L and 0.1% of AISI 316L. The potentiodynamic anodic polarization results revealed that the $Cr_{eq}/Ni_{eq}$ ratio in a 3.5% NaCl solution didn't much affect the pitting potential ($E_{pit}$). The AISI 316L welded metals with ${\ddot{a}}$-ferrite content of over 10% had a superior $E_{pit}$ value. Though the AISI 316L welded metal with 0.1% ferrite had larger molybdenum contents than AISI 304L specimens, it showed a similar $E_{pit}$ value because the concentration of chloride ions and the corrosion product induced severe damage near the DDC.

수직 밀폐형 지중 열교환기용 뒤채움재의 물리적 특성 연구 (Study on physical characteristics of grouts for backfilling ground heat exchanger)

  • 이철호;길후정;최항석;최효범;우상백
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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    • pp.533-544
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    • 2008
  • To obtain the physical properties of grout materials, that is the thermal conductivity and viscosity, which are used for backfilling ground heat exchangers, nine bentonite grouts and cement grouts being adapted in the United State have been considered in this study. The bentonite grouts show that the thermal conductivity and viscosity increase with the content of bentonite or filler (silica sand). The saturated cement grouts appear to possess much higher thermal conductivity than the saturated bentonite grouts, and the reduction of thermal conductivity in the cement grouts after drying specimens is less than the case of the bentonite grouts. To investigate the performance of cement grouts, fifteen samples were prepared by varying the water/cement ratio and the amount of sand and bentonite added into the cement mortar. Maintaining the moisture content of grouts is a crucial factor in enhancing the efficiency of ground heat exchangers.

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아스팔트 혼합물의 박리방지제의 종류 및 함량에 따른 박리저항성 분석 (Moisture Damage Evaluation of Asphalt Mixtures depending on the Types of Anti-Stripping Agent)

  • 최성호;김원재;르반푹;이현종;황성도
    • 한국도로학회논문집
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    • 제16권4호
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    • pp.45-50
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    • 2014
  • PURPOSES : The objective of this study is to analyze the performance of anti-stripping agent depending on its type and content to reduce pothole, an increasing pavement distress due to abnormal climate intensity. METHODS : In the past years, U.S and many countries in Europe use hydrated lime and liquid anti-stripping agent in asphalt mixtures. Hydrated lime or liquid anti-stripping agent is substituted for filler and binder, respectively, to improve the anti-stripping property of asphalt mixtures. To investigate this, indirect tensile strength test was performed and TSR values were compared for different content of hydrated lime and types of liquid anti-stripping agent in asphalt mixture. RESULTS : Test results indicate that hydrated lime remarkably increased the asphalt mixture performance on anti-stripping denoted by the increased in TSR values from 55% to 100%. Liquid anti-stripping agent also increased the value of TSR but not significant. In addition, depending on the types of aggregate, TSR values and effect of liquid anti-stripping were different. CONCLUSIONS : Using anti-stripping agents improve the anti-stripping property of asphalt mixture especially hydrated lime; however, more experiments should be conducted to improve the reliability about the effect of liquid anti-stripping agent.

Durability properties of concrete containing metakaolin

  • Nas, Memduh;Kurbetci, Sirin
    • Advances in concrete construction
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    • 제6권2호
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    • pp.159-175
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    • 2018
  • The main aim of this study is to investigate the possible effects of metakaolin on strength and durability properties of concrete. For this purpose, concrete mixtures are produced by substituting cement with metakaolin 0, 5, 10 and 20% by weight. The amount of binder for the concrete mixtures are 300 and $400kg/m^3$ with a constant water to cement ratio of 0.6. Compressive and bending strengths, freeze-thaw and high-temperature resistances, capillary coefficients and rapid chloride permeability properties were determined and compared each other. Because of all the experiments conducted, it has been found that the use of metakaolin as a pozzolanic additive in concrete have positive effects especially on compressive and bending strengths, capillary, rapid chloride permeability, freeze-thaw resistance, and high temperatures, up to $800^{\circ}C$. The results indicated that the performance of concrete can be enhanced by metakaolin. Particularly, compressive strength and durability properties have found to be improved with increasing metakaolin content which is attributed to pozzolanic activity and filler effect. Furthermore, metakaolin has relatively positive impacts under elevated temperatures and freeze-thaw effects. However, almost all the strengths of entire concrete specimens are lost at $800^{\circ}C$. Consequently, the optimum metakaolin substitution ratio can be suggested to be 20% as per this study.