• Title/Summary/Keyword: fiber spinning

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Effect of Stabilization Conditions on the Microstructure and Electrochemical Properties of Melt-blown Graphite Fibers Prepared from NMP (NMP로부터 제조된 Melt-blown흑연섬유의 안정화조건에 따른 미세구조와 전기화학적 특성)

  • Kim Chan;Yang Kap Seung;Ko Jang Myoun;Park Sang Hee;Park Ho Chul;Kim Young-Min
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.104-108
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    • 2001
  • Naphthalene derived mesophase pitch WP) was spun into short fibers by using melt-blown technology. The pitch fibers oxidative stabilization were carried out heating rates of $2^{\circ}C/min,\;5^{\circ}C/min\;and\; 10^{\circ}/min$. The heating rate was a key factor to maximate the capacity of the Li-ion secondary battery through controlling the morphology of the graphitized fiber. The diameters of the melt-blown fibers prepared were in the range of $4{\mu}m\~16{\mu}m$ with functions of air jet speed, air temperature and the temperature of the nozzle. The graphitized fibers of $10{\mu}m$ diameters showed various morphological structure with heating rate of the stabilization. Radial, radial-random and skin-core cross-sectional structure of the fibers were observed at the respective heating rate of $2^{\circ}C/min\;5^{\circ}C/min\;and\;10^{\circ}C/min$. Most crystalline structure of graphite was obtained from the fiber stabilized at heating rate of $10^{\circ}C/min$ exhibiting the best anode performance with 400 mAh/g of capacitance and $96.8\%$ of charge/discharge efficiency.

Study of silk lousiness (I) (견사 Lousiness에 대한 연구 (I))

  • 최병희;김낙정;박광의;남중희
    • Journal of Sericultural and Entomological Science
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    • v.3
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    • pp.1-11
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    • 1963
  • This treatise is to set up a fundamental condition of checking silk lousiness and to set up a new improving method of cocoon bave lousiness after super refining treatment. It is also studied whether silk lousiness can be eliminated through the observation of the silk gland, or the lousiness can be able to improve through such a study. The conclusions obtained in this paper are as follows. 1. Silk lousiness is able to be observed most properly when the light direction and the fiber direction are parallel in plan view of the silk cloth and the greater the angle between them is, the less the lousiness is observed. When, however, the angle is greater than some specific angle(30$^{\circ}$), no more lousiness is observed. This specific angle is named by the author as Lousiness Horizontal Critical Angle. 2. Silk lousiness can be observed when the angle of light incidence against the silk cloth is six degrees, while the larger the angle is, the less the lousiness is observed. When, however, the angle is greater than same specific angle(45$^{\circ}$) the lousiness disappears. Such a specific angle is named by the author as Lousiness Vertical Critical Angle. 3. The best textile composition to decrease lousiness defect is plan weave, while twill and satin weave show more lousiness with the same silk fiber. 4. Lousiness was classified as Lousiness A, B, ana C of which A was the general lousiness, B was the group type, and C was the glucose type and the standard photographs for the lousiness grading of these types were prepared. 5. The proper soap-refining hours of silk for lousiness test was eight hours. 6. The greater the difference of fiber diameter between the cocoon single bave and the splitend was, the more lousiness was composed. The normal splitends were measured as 1/4-1/5 of the main fiber. 7. The lousiness was found at the cocoon shape ends more than other parts, and found at the middle cocoon layer than other layer which was imagined to be as a result of poor uniform bave spinning of silk worm. 8. Female cocoon had more lousiness than the male cocoon. 9. It was found that there was a great possibility to have the splitends through the observation of the anatomical silkgland, and the author reached a conclusion that the lousiness can be improved to a certain degree only by the elimination of abnormal silk gland from the breeding aspects. 10. The cocoon bave of the offspring after super refining lousiness test and selection showed more improved lousiness defect than that of the parents.

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Determination of Adequate Method for Protein Extraction from Rice Bran and the Substitution of Dried Skim Milk with Protein Concentrate from Rice Bran in Early Weaned Pigs

  • Phipek, W.;Nagasinha, C.;Vallisuth, S.;Nongyao, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.9
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    • pp.1268-1273
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    • 2011
  • The present study was conducted to determine a feasible method of protein concentrate extraction from rice bran (RBPC) and its effect as a substitution for skim milk in early weaning pig diets. An investigation to extract protein concentrate from full fat rice bran was undertaken to determine the best ratio of water and rice bran, the amount of NaOH and a HCl solvent to use in a simple paddle-type mixer with modified spinning to produce RBPC. The results stated that the best ratio for water mixing in the RBPC extraction process was 1:5 with 20 g NaOH and 30 min in a paddle-type mixer at 300 rpm. A mix of 250 ml 0.2 N HCl was optimum for neutralization and protein precipitation. After the fluid was spun out with a washing machine, the sediment was left for 12-14 hours to complete the filtration. One kilogram of rice bran could produce an average of 324.5 gram RBPC and it contained 3.40% ash, 496.48 kcal of GE/100 gram, 1.94% crude fiber, 28.20% ether extract, 7.64% moisture and 16.66% crude protein, respectively. A total of 45 crossbred piglets, weaned at 3 weeks of age were allotted into control diet (A) and dietary treatments formulated with a four different rates of RBPC substitution for skim milk at a percentage of 25 (B), 50 (C), 77 (D) and 100 (E) respectively, in a randomized complete block (RCB) design. All piglets had free access to feed and water until 8 week of age when the experiment ended. Feed intake, average daily gain, growth rate and feed efficiency were not affected by dietary treatments. Blood test parameters after completion of the growth trial indicated normal health. Even though the mean of cell hemoglobin concentration was significantly different between treatments (p<0.05) it was still within the normal range. The cost difference for BW gain of 100% RBPC substituted for skim milk in the weaning diet was approximately 35% lower than that of the control and the relative cost of production was 96.67, 92.85, 70.75 and 64.48% lower for the replacement of 25, 50, 75 and 100% of skim milk respectively. These results implied that this technology is feasible for use by small scale farmers to improve their self-reliance.

Studies of Raw Silk Size Nonuniformity. (생사비균일섬도발생 원인에 관한 연구)

  • 최병희
    • Journal of Sericultural and Entomological Science
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    • v.7
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    • pp.65-74
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    • 1967
  • This work has been carried out to find the fundamental reasons of raw silk size nonuniformity by studying with the physical nature and its bave formation through the worm spinnerate with anatomical device. Mean time, the uniformity improving method is also attached to this paper after throughfall theoretical study. 1. According to the anatomical study of the silkworm spinnerate, the physical form decides the fiber cross section and also spinns more finner size as the spinning is continued collaborating with the muscle pressure and decrease of liquid silk in the silk gland. 2. The bave size deviation of the Korean cocoons have shown a little difference among the varieties, but, they are conclued as 0.58 denier in average which caused some size deviation of the raw silk inevitably. 3. The raw silk nonuniformity increases when the cocoon have size is not suitable with the proposed raw silk size. 4. The nonuniformity is also increased very much during the filature process in case of poor technical work, but even if we do our best, the best result is found as 30 percent improvement which is still worser than the natural cocoon size deviation. 5. It is required to be careful for the selection of silkworm variety in order to improve the nonuniformity of raw silk so that the bave size be suitable for the proposed silk. 6. The definite size silk reeling method could made better uniform silk, 20 percent at least, than the definite cocoon number silk reeling method. 7. A newly developed denier(21d) gauge was applied for the multiends type silk reeling machine which is widely used in Korea, and the result of the method showed 1.30 denier size deviation, but, in case of no use of it was 1.57 denier size deviation, that is, it could improve two grades more than the normal reeling method.

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A Study on the Physical Property and Cover Factor of Spun Yarn using Aramid Fiber (II) (아라미드 섬유의 방적조건에 따른 물성 및 피복도 변화에 관한 연구 (II))

  • Hong, Sang-Ki;Park, Seong-Woo;Oh, Sang-Yeop;Kim, Gyu-Ho;Sim, Jae-Hyeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.89-89
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    • 2012
  • 선행 연구에서는 m-Aramid와 p-Aramid의 Ring 방적사/Core 방적사 조건에 따른 방적사 물성에 대해서 연구하였는데, Ring 방적사의 혼용율, 스핀들 속도에 따른 물성 변화, Core 방적사의 공정특성에 따른 방적성, 피복성에 대해 연구를 하였다. 그 결과 Ring 방적사의 경우 m-Aramid의 혼용율이 증가할수록 사 강도는 증가하는 경향을 확인할 수 있었고, 스핀들 속도가 증가함에 따라서 불균제도 및 사결점이 다소 증가하였다. Core 방적사의 경우 Core에 p-Aramid를 사용했을 때 방적성과 피복성은 양호 하였지만, 강한 p-Aramid에 의해 톱 롤러코트의 마모가 되는 경향을 볼 수 있었다. 본 연구에서는 Ring 방적사/Core 방적사에 대해 좀더 구체적인 제조공정조건에 의한 물성 변화를 알아보았고, 좀더 다양한 섬유소재를 적용해서 제조하였다. Ring 방적사의 경우 p-Aramid 혼용율에 따른 실험을 하였는데, m-Aramid에 대한 p-Aramid의 혼용율을 0%, 5%, 10%, 20% 로 하여 Ne30을 제조하였으며, Core 방적사는 Core를 p-Aramid 200D로 하고 Sheath를 Cotton으로 하여 Core 공급속도비 (1.06, 1.10, 1.14), 연계수(T/M, 3.8, 4.0, 4.2), Sheath/Core 혼섬율(70/30, 60/40, 50/50)에 따라 제조하였다. 추가로 Core 방적사는 Sheath에 Cotton 대신 FR-Rayon과 선염 Cotton을 사용하여 각각 Sheath/Core 혼섬율 70/30의 비율로 방적사를 제조하여 다양한 소재에 따른 방적사의 물성을 측정하였다. 제조된 시험 원사들의 측정 물성은 번수(Ne), 균제도(U%), 사결점(IPI), 강력(cN), 신도(%), 비강도(cN/Tex) 등이며, 편직을 통해 편성물의 외관을 확인하였다. Ring 방적사의 경우 p-Aramid의 혼용율이 증가할수록 강도는 완만하게 증가한 반면, 신도는 급격하게 감소하였다. Cotton Core 방적사의 경우는 공급속도비가 높아질수록 균제도가 높아지는 것을 볼수 있었고, Core 공급속도비가 높아질수록 외관상 피복도는 높아진 것을 볼 수 있었다. 이렇게 연구된 Aramid 소재를 이용한 방적사 제조 공정조건변화에 따른 물성 및 피복도 결과는 기존 방적업체에서 Aramid를 이용한 방적사 제조시에 공정조건을 확보하는데 도움이 될 것이라 생각되며, 방적사 시제품 생산시에 발생할 수 있는 시행착오를 줄임으로써 시제품 제조를 위한 생산비용의 Loss를 절감할 수 있을 것으로 예상된다.

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Functional Properties of Soy Protein Isolates Prepared from Defatted Soybean Meal (탈지대두박(脫脂大豆粕)에서 추출(抽出)한 분리대두단백(分離大豆蛋白)의 식품학적(食品學的) 성질(性質))

  • Byun, Si-Myung;Kim, Chul-Jin
    • Korean Journal of Food Science and Technology
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    • v.9 no.2
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    • pp.123-130
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    • 1977
  • A laboratory study was made to develop a simple and economic model method for the systematic determination of functional properties of 'Soy Protein Isolates (SPI)' prepared from defatted soybean meal. These are required to evaluate and to predict how SPI may behave in specific systems and such proteins can be used to simulate or replace conventional proteins. Data concerning the effects of pH, salt concentration, temperature, and protein concentration on the functional properties which include solubility, heat denaturation, gel forming capacity, emulsifying capacity, and foaming capacity are presented. The results are as follows: 1) The yield of SPI from defatted soybean meal increased to 83.9 % as the soybean meal was extracted with 0.02 N NaOH. 2) The suitable viscocity of a dope solution for spinning fiber was found to be 60 Poises by using syringe needle (0.3 mm) with 15 % SPI in 0.6 % NaOH. 3) Heat caused thickening and gelation in concentration of 8 % with a temperature threshold of $70^{\circ}C$. At $8{\sim}12\;%$ protein concentration, gel was formed within $10{\sim}30\;min$ at $70{\sim}100\;^{\circ}C$. It was, however, disrupted rapidly at $125\;^{\circ}C$ of overheat treatment. The gel was firm, resilient and self-supporting at protein concentration of 14 % and less susceptible to disruption of overheating. 4) The emulsifying capacity (EC) of SPI was correlated positively to the solubility of protein at ${\mu}=0$. At pH of the isoelectric point of SPI (pH 4.6), EC increased as concentration of sodium chloride increased. Using model system$(mixing\;speed:\;12,000\;r.p.m.,\;oil\;addition\;rate:\;0.9\;ml/sec,\;and\;temperature\;:\;20{\pm}1\;^{\circ}C)$, the maximum EC of SPI was found to be 47.2 ml of oil/100 mg protein, at the condition of pH 8.7 and ${\mu}=0.6$. The milk casein had greater EC than SPI at lower ionic strength while the EC of SPI was the same as milk casein at higher ionic strength. 5) The shaking test was used in determining the foam-ability of proteins. Progressively increasing SPI concentration up to 5 % indicated that the maximum protein concentration for foaming capacity was 2 %. Sucrose reduced foam expansion slightly but enhanced foam stability. The results of comparing milk casein and egg albumin were that foaming properties of SPI were the same as egg albumin, and better than milk casein, particularly in foam stability.

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Studies on Electrostatic Propensity of Fabrics (직물대전성에 관한 연구)

  • 최병희;배도규
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.54-63
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    • 1985
  • This studies has been carried out how to effect on electrostafic propensity of synthetic fabrics by coating with 0.5% acrylic polymer solution which was previously developed by the author to improve anticrease nature of silk. The work conditions are: (A) Applied synthetic polymer was acrylic polymer 525, developed by the author. (B) Electrostatic voltage for various fabrics were carried out by Korea standard abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (C) Applied fabrics for the investigations were carried out by using abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (D) Electrostatic propensity investigations were carried out by use of sample as silk, nylon, polyester and acrylic fabrics, seperating before finish or after finish. (E) Washing after the finish or the original fabric was carried out by Korea standard method, KS K 0465. Through the investigations, he happened to find many interesting matters and the obtained results are as followings. 1. Electrostatic voltage for the finished fabrics increased more than their original silk, nylon, acrylic fabrics except polyester fabric. (See Table 5) 2. Electrostatic voltage for the finished polyester against K.S. polyester decreased remarkably than the original fabric test. 3. In spite of no problem on electrostatic propensity of silk, it showed high electrostatic voltage between the same nature fabric abrasion, because silk is very weak against abrasion and because the test method had been developed to be useful for only synthetic fabrics. 4. Electrostatic voltage increased more in case of abrasion between different nature of fabrics than the same nature of fabrics. 5. Electrostatic voltage of each fabric increased by repeat of wash. 6. Many investigation data were followed with Contact Electrification Series Principle, another word, the farther each other located fabric on the series abrasion was, the higher electrostatic voltage. (See Fig. 6) 7. Such investigation gives warning of use on the mix fiber spinning service as far as concern with electrification. 8. It may also call attention for such increase of electrification in case any finishing of silk textile.

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