• 제목/요약/키워드: fiber migration

검색결과 32건 처리시간 0.019초

DEHP Migration Behavior from Excessively Plasticized PVC Sheets

  • Kim, Jung-Hwan;Kim, Seong-Hun;Lee, Chang-Hyung;Nah, Jae-Woon;Hahn, Airan
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권3호
    • /
    • pp.345-349
    • /
    • 2003
  • The quantity, process and kinetics of di-(2-ethylhexyl)phthalate (DEHP) migration in the 30/70 and 40/60 poly(vinylchloride) (PVC)/DEHP blends were investigated using gas chromatograph. A thin and flexible PVC sheet was soaked in surrounding medium (SM) of water/ethanol mixture and acetonitrile with constant stirring to release DEHP. By observed concentration of DEHP in the SM, it is found that acetonitrile is more intense in DEHP migration than water/ethanol mixture. In addition the amount of extracted DEHP is proportional to the leaching temperature and added ratio of DEHP. The behavior of DEHP migration from flexible PVC sheets was described by the Ficks's law with $2.72-10.1\;{times}\;10^{-10}$ cm²/s of the diffusion coefficients.

RESIN TRANSFER MOLDING 공정에서의 기공 형성에 관한 3차원 모델링 (Three-Dimensional Modeling of Void Formation During Resin Transfer Molding)

  • 배준호;강문구;임성택;이우일
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2001년도 춘계학술대회논문집C
    • /
    • pp.246-250
    • /
    • 2001
  • In resin transfer molding (RTM), resin is forced to flow through the fiber perform of inhomogeneous permeability. This inhomogeneity is responsible for the mismatch of resin velocity within and between the fiber tows. The capillary pressure of the fiber tows exacerbates the spatial variation of the resin velocity. The resulting microscopic perturbations of resin velocity at the flow front allow numerous air voids to form. In this study, a mathematical model was developed to predict the formation and migration of micro-voids during resin transfer molding. A transport equation was employed to account for the migration of voids between fiber tows. Incorporating the proposed model into a resin flow simulator, the volumetric content of micro-voids in the preform could be obtained during the simulation of resin impregnation.

  • PDF

키토산 전처리를 통한 과불화탄소 무함유 합성 스웨이드의 이염성 견뢰도 향상 (Improvement of Migration Fastness of Perfluorocarbons-free Synthetic Suede by Chitosan Pretreatment)

  • 이혜미;김아롱;김대근
    • 한국염색가공학회지
    • /
    • 제31권4호
    • /
    • pp.258-267
    • /
    • 2019
  • Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.

기능성 폴리에스터 이중 편성물의 염색 특성 (Dyeing Properties of Functional PET Double Knit Fabric)

  • 이범훈
    • 한국염색가공학회지
    • /
    • 제34권3호
    • /
    • pp.146-156
    • /
    • 2022
  • In this study, the dyeing properties of double knit fabric composed of PET/PTT bi-component fiber and quick dry fiber were examined with disperse dyes. In addition, the shrinkage characteristics were investigated during the dyeing process. The K/S values and shrinkage rate of PET/PTT bi-component fiber were higher than those of PET/co-PET bi-component fiber and quick dry fiber. In the dye bath, dye migration of exhausted on PET/PTT bi-component fiber to quick dry fiber was found at high dyeing temperature. It was not found that there was a significant difference in K/S value on dyeing temperature between 115℃ and 130℃. But the slight color difference of two sides of a double knit fabric was found.

강섬유 혼입량이 철근 부식저항성능에 미치는 영향 (Influence of steel fiber contents on corrosion resistance of steel reinforcement)

  • 김성도;문도영;이규필
    • 한국터널지하공간학회 논문집
    • /
    • 제17권3호
    • /
    • pp.283-293
    • /
    • 2015
  • 본 연구에서는 강섬유보강콘크리트의 부식저항성능을 규명하기 위한 촉진염소이온확산시험과 표면전기저항시험을 수행하였다. 또한 배합평가를 위한 기초시험으로서 굳지 않은 콘크리트 공기량, 일축압축강도, 굳은 콘크리트의 흡습시험을 수행하였다. 실험변수는 두 종류의 물-시멘트비(0.44, 0.50)와 세 개의 강섬유 혼입량(0.25%, 0.5%, 1%)으로 선정하였다. 주목할 것은 모든 타설시 콘크리트의 다짐량은 동일하게 하였다. 시험결과, 동일한 작업량으로 다짐이 되었을 때, 물-시멘트비에 상관없이 두배합 모두에서 강섬유 혼입률이 증가함에 따라 부식저항성능이 감소하는 것으로 확인되었다. 그러나, 동일한 강섬유 혼입비에 대하여 배합의 물-시멘트비가 낮은 콘크리트의 부식저항성능이 우수한 것으로 나타났다. 따라서, 강섬유보강콘크리트의 타설시 유동성의 확보와 충분한 다짐이 염소이온침투저항성능을 확보하기 위하여 매우 중요하다고 판단된다.

전처리제에 따른 디지털프린팅 소재의 개발에 관한 연구 (Developing Digital Printing Textiles Media with Anti-migration Agents)

  • 손은종;김효석
    • 한국섬유공학회:학술대회논문집
    • /
    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
    • /
    • pp.210-213
    • /
    • 2003
  • 최근 들어 사회가 고도화ㆍ다양화됨으로 인해 관련 산업 전분야로 컴퓨터 시스템의 보급은 급속도로 확산되고 있다. 특히, 섬유 날염 분야에도 다품종ㆍ소롯트 추세에 대응하기 위한 컴퓨터 시스템을 응용한 디지털 날염시스템의 다양한 기계 장치와 관련 소재 개발[1-3]이 구미 선진국을 중심으로 활발히 진행되고 있는 것이 세계적인 현상이다. 이에 본 연구에서는 수년전부터 국내 날염 업계와 제품 디자인 업계에 상당수 보급되어 운영되고 있는 디지털 날염머신에 필요한 천연섬유소재와 합성섬유소재 등 디지털 날염전용 섬유소재원단을 개발하고자 한다. (중략)

  • PDF

Solo spun 방적에서 섬유의 거동과 사의 물리적 성질(2) (The Fiber Behavior in Solo-spun Yarn Formation and the Physical Properties of Solo-spun Yarn(2))

  • 박수현;김승진
    • 한국염색가공학회지
    • /
    • 제13권6호
    • /
    • pp.70-70
    • /
    • 2001
  • This study surveys the fiber behavior in yarn formation and the Physical properties of Solo-spun yarn. The specimens were made by six types of Solo-spun rollers with fixed twist multiplier In the previous part, the physical properties such as yarn count, evenness, strength, and breaking elongation of these yarns were compared with the properties of ring spun yarns and analysed with the mechanism of Solo-spun yarn formation. In the second part of this report, the abrasion resistance and hairiness were discussed with respect to the micro yarn structures. The narrower the groove width of Solo-spun roller is, the more active the bulk fiber migration is. The Solo-spun yarn structure has two groups. One is shorter than the other one in longitudinal direction of yarn and has the same structure as ring-spun yarn, which is derived from the smooth zone on the surface of Solo-spun roller. The other one is longer than the former and there are the wrapping fibers. This part is derived from the conflicted grooves on the surface of Solo-spun roller.

폴리에스테르 섬유의 염색성에 미치는 캐리어의 영향 (The Effect of Carriers on Dyeing Properties of PET Fiber)

  • 최희
    • 한국의류산업학회지
    • /
    • 제5권5호
    • /
    • pp.545-549
    • /
    • 2003
  • Dyeing properties such as migration of disperse dye and color fastness of 4 types of the carrier[Carrier-I(methyl napthalene). Carrier-II(chloro benzene). Carrier-III(aromatic ether) and Carrier-IV(o-phenyl phenol)] were evaluated for the study. For the results, the optimum dyeing time and concentration of the carrier was 30min at $110^{\circ}C$ and 2g/l, respectively. The redyeing ratio of the fabric samples treated with Carrier-II and III was higher than that treated with Carrier-I and IV, thus, if was conclude that the redyeing ratio of the samples treated with Carrier-II and III was excellent. The light fastness of the samples treated with Carrier-III and IV was higher than that of Carrier-I and II in order of 2-4 grades. However, there were little changes in terms of washing and sublimation and rubbing fastness for the samples.

혈액·수액용 PVC 백에서 용출된 DEHP의 검출 분석 방법 비교; 기체 크로마토그래프와 분광 광도계 (Comparison of Analytical Methods for DEHP Migration from PVC Bags for Blood Storage and Infusion; By Gas Chromatography and UV-vis Spectrophotometry)

  • 김정환;김성훈;최형기;이창형
    • 분석과학
    • /
    • 제15권1호
    • /
    • pp.72-79
    • /
    • 2002
  • Di-(2-ethylhexyl)phthalate (DEHP) 가 가소제로 첨가되 있는 poly(vinylchloride) (PVC) 제품의 사용중에는 DEHP가 방출되어 나올 가능성이 있다. 이때 추출되는 DEHP의 정량적인 측정법에는 여러가지가 있으나 그 방법에 따라 용출량에 많은 차이가 발생하기 때문에 측정방법과 결과에 대한 비교분석은 시급한 과제라 할 수 있다. 이를 평가하기 위하여 PVC를 주원료로 하는 혈액백과 수액백에서의 DEHP 용출에 관한 연구를 기체 크로마토그래프와 분광광도계를 이용한 두 가지 방법으로 수행하였다. 5종류의 PVC 백을 실험 재료로 선택하여 $40{\times}10{\times}0.4mm$ 크기의 시편을 제조하고 이를 용출액에 담가 1시간동안 DEHP를 용출하였다. 기체 크로마토그래프로 DEHP 를 검출한 결과 시료에 따라 $23.2{\sim}70.9{\mu}g/mL$ 의 DEHP가 용출되는 것을 알 수 있었다. 반면 PVC백 안에 용출액을 주입하여 1시간 동안 DEHP를 용출시키고 분광 광도계를 이용하여 DEHP를 검출한 결과 $24.8{\sim}41.3{\mu}g/mL$의 DEHP가 용출되었다. 용출 조건과 실험방법에 따라 서로 다른 수치를 보임을 알 수 있었고 단위 시간 단위 면적 당 용출되는 DEHP의 양은 일정하다는 전제 하에 두 실험의 결과를 비교하고 환산하는 식을 구하여 적용한 결과 두 측정방법에서 얻어진 용출량이 거의 일치하였다.