• Title/Summary/Keyword: fiber migration

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DEHP Migration Behavior from Excessively Plasticized PVC Sheets

  • Kim, Jung-Hwan;Kim, Seong-Hun;Lee, Chang-Hyung;Nah, Jae-Woon;Hahn, Airan
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.345-349
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    • 2003
  • The quantity, process and kinetics of di-(2-ethylhexyl)phthalate (DEHP) migration in the 30/70 and 40/60 poly(vinylchloride) (PVC)/DEHP blends were investigated using gas chromatograph. A thin and flexible PVC sheet was soaked in surrounding medium (SM) of water/ethanol mixture and acetonitrile with constant stirring to release DEHP. By observed concentration of DEHP in the SM, it is found that acetonitrile is more intense in DEHP migration than water/ethanol mixture. In addition the amount of extracted DEHP is proportional to the leaching temperature and added ratio of DEHP. The behavior of DEHP migration from flexible PVC sheets was described by the Ficks's law with $2.72-10.1\;{times}\;10^{-10}$ cm²/s of the diffusion coefficients.

Three-Dimensional Modeling of Void Formation During Resin Transfer Molding (RESIN TRANSFER MOLDING 공정에서의 기공 형성에 관한 3차원 모델링)

  • Bae, Jun-Ho;Kang, Moon-Koo;Lim, Seoug-Taek;Lee, Woo-Il
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.246-250
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    • 2001
  • In resin transfer molding (RTM), resin is forced to flow through the fiber perform of inhomogeneous permeability. This inhomogeneity is responsible for the mismatch of resin velocity within and between the fiber tows. The capillary pressure of the fiber tows exacerbates the spatial variation of the resin velocity. The resulting microscopic perturbations of resin velocity at the flow front allow numerous air voids to form. In this study, a mathematical model was developed to predict the formation and migration of micro-voids during resin transfer molding. A transport equation was employed to account for the migration of voids between fiber tows. Incorporating the proposed model into a resin flow simulator, the volumetric content of micro-voids in the preform could be obtained during the simulation of resin impregnation.

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Improvement of Migration Fastness of Perfluorocarbons-free Synthetic Suede by Chitosan Pretreatment (키토산 전처리를 통한 과불화탄소 무함유 합성 스웨이드의 이염성 견뢰도 향상)

  • Lee, Hye Mi;Kim, Ah Rong;Kim, Dae Geun
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.258-267
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    • 2019
  • Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.

Dyeing Properties of Functional PET Double Knit Fabric (기능성 폴리에스터 이중 편성물의 염색 특성)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.34 no.3
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    • pp.146-156
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    • 2022
  • In this study, the dyeing properties of double knit fabric composed of PET/PTT bi-component fiber and quick dry fiber were examined with disperse dyes. In addition, the shrinkage characteristics were investigated during the dyeing process. The K/S values and shrinkage rate of PET/PTT bi-component fiber were higher than those of PET/co-PET bi-component fiber and quick dry fiber. In the dye bath, dye migration of exhausted on PET/PTT bi-component fiber to quick dry fiber was found at high dyeing temperature. It was not found that there was a significant difference in K/S value on dyeing temperature between 115℃ and 130℃. But the slight color difference of two sides of a double knit fabric was found.

Influence of steel fiber contents on corrosion resistance of steel reinforcement (강섬유 혼입량이 철근 부식저항성능에 미치는 영향)

  • Kim, Seong-Do;Moon, Do-Young;Lee, Gyu-Phil
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.3
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    • pp.283-293
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    • 2015
  • In order to evaluate corrosion resistance of steel fiber-reinforced concrete, accelerated chloride migration and surface resistivity tests were conducted. In addition air content of fresh concrete, compressive strength and water absorption were measured for investigating fundamental characteristics of concrete. Two different water-cement ratios(0.44, 0.5) and three steel fiber contents(0.25%, 0.5%, 1%) were considered as variables. Note that all specimens cast with same compaction work. As a results, corrosion resistance decreased as steel fiber contents increased regardless of water-cement ratio when the concrete was compacted with same amount of work done. However, for concrete with same steel fiber content, the lower water-cement ratio showed the better corrosion resistance. It is found that enhancement of fluidity and enough compaction should be done for corrosion resistance of SFRC.

Developing Digital Printing Textiles Media with Anti-migration Agents (전처리제에 따른 디지털프린팅 소재의 개발에 관한 연구)

  • 손은종;김효석
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.210-213
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    • 2003
  • 최근 들어 사회가 고도화ㆍ다양화됨으로 인해 관련 산업 전분야로 컴퓨터 시스템의 보급은 급속도로 확산되고 있다. 특히, 섬유 날염 분야에도 다품종ㆍ소롯트 추세에 대응하기 위한 컴퓨터 시스템을 응용한 디지털 날염시스템의 다양한 기계 장치와 관련 소재 개발[1-3]이 구미 선진국을 중심으로 활발히 진행되고 있는 것이 세계적인 현상이다. 이에 본 연구에서는 수년전부터 국내 날염 업계와 제품 디자인 업계에 상당수 보급되어 운영되고 있는 디지털 날염머신에 필요한 천연섬유소재와 합성섬유소재 등 디지털 날염전용 섬유소재원단을 개발하고자 한다. (중략)

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The Fiber Behavior in Solo-spun Yarn Formation and the Physical Properties of Solo-spun Yarn(2) (Solo spun 방적에서 섬유의 거동과 사의 물리적 성질(2))

  • Park, Su Hyeon;Kim, Seung Jin
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.70-70
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    • 2001
  • This study surveys the fiber behavior in yarn formation and the Physical properties of Solo-spun yarn. The specimens were made by six types of Solo-spun rollers with fixed twist multiplier In the previous part, the physical properties such as yarn count, evenness, strength, and breaking elongation of these yarns were compared with the properties of ring spun yarns and analysed with the mechanism of Solo-spun yarn formation. In the second part of this report, the abrasion resistance and hairiness were discussed with respect to the micro yarn structures. The narrower the groove width of Solo-spun roller is, the more active the bulk fiber migration is. The Solo-spun yarn structure has two groups. One is shorter than the other one in longitudinal direction of yarn and has the same structure as ring-spun yarn, which is derived from the smooth zone on the surface of Solo-spun roller. The other one is longer than the former and there are the wrapping fibers. This part is derived from the conflicted grooves on the surface of Solo-spun roller.

The Effect of Carriers on Dyeing Properties of PET Fiber (폴리에스테르 섬유의 염색성에 미치는 캐리어의 영향)

  • Choi, Hee
    • Fashion & Textile Research Journal
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    • v.5 no.5
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    • pp.545-549
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    • 2003
  • Dyeing properties such as migration of disperse dye and color fastness of 4 types of the carrier[Carrier-I(methyl napthalene). Carrier-II(chloro benzene). Carrier-III(aromatic ether) and Carrier-IV(o-phenyl phenol)] were evaluated for the study. For the results, the optimum dyeing time and concentration of the carrier was 30min at $110^{\circ}C$ and 2g/l, respectively. The redyeing ratio of the fabric samples treated with Carrier-II and III was higher than that treated with Carrier-I and IV, thus, if was conclude that the redyeing ratio of the samples treated with Carrier-II and III was excellent. The light fastness of the samples treated with Carrier-III and IV was higher than that of Carrier-I and II in order of 2-4 grades. However, there were little changes in terms of washing and sublimation and rubbing fastness for the samples.

Comparison of Analytical Methods for DEHP Migration from PVC Bags for Blood Storage and Infusion; By Gas Chromatography and UV-vis Spectrophotometry (혈액·수액용 PVC 백에서 용출된 DEHP의 검출 분석 방법 비교; 기체 크로마토그래프와 분광 광도계)

  • Kim, Jung Hwan;Kim, Seong Hun;Choi, Hyeong Ki;Lee, Chang Hyung
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.72-79
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    • 2002
  • Di-(2-ethylhexyl)phthalate (DEHP) may be released from plasticized poly(vinyl chloride) (PVC) articles. In the cases of various methods for the quantitative analysis of migrating DEHP, there are much differences in migrating quantity according to the experimental methods. It is therefore important to make the comparison and analysis between these two results. A study of DEHP migration from blood and infusion bags has been carried out in different methods to evaluate the amount of DEHP migration using gas chromatograph and UV-vis spectrophotometry. Five PVC bags were cut into plane sheets in size of $40{\times}10{\times}0.4mm$, then were immersed in extraction solvent for an hour to release DEHP. It was determined by a gas chromatograph that $23.2{\sim}70.9{\mu}g/mL$ of DEHP was extracted. While extraction solvent was injected into PVC bags which were then placed for an hour to leach DEHP out. It was checked by a UV-vis spectrophotometer that the concentration of DEHP in extraction solvent was $24.8{\sim}41.3{\mu}g/mL$. Two results show different values according to the extraction conditions and experimental methods and the gas chromatographic results were converted into UV-vis spectroscopic results on condition that DEHP would be extracted equally per unit time and unit contact area. It was concluded that DEHP migrating amounts are approximately equal in two analytical methods.