• Title/Summary/Keyword: fiber materials

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Grafting of Casein onto Polyacrylonitrile Fiber for Surface Modification

  • Jia Zhao;Du Shanyi
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.235-240
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    • 2006
  • Polyacrylonitrile (PAN) fiber was grafted with casein after alkaline hydrolysis and chlorination reactions of the original fiber. The structures and morphologies of the casein grafted fiber were characterized by Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), and scanning electron microscope (SEM). Moisture absorption, specific electric resistance, water retention value, and mechanical properties were also investigated. The results showed that casein was grafted onto the surface of the PAN fiber and the grafted PAN fiber presented better hygroscopicity compared with the untreated fiber. With proper tensile strength, the modified fiber could still meet the requirement for wearing. A mechanism was proposed to explain the deposit of casein on the synthetic acrylic fiber.

A Study on Fabrication of Ti Matrix Composites by Liquid Phase Diffusion Bonding (액상확산접합법을 이용한 Ti 금속기복합재료 제조에 관한 연구)

  • Kim, Gyeong-Mi;U, In-Su;Gang, Jeong-Yun;Lee, Sang-Rae
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.210-220
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    • 1996
  • The purpose of this study is to develop the processing techniques of Fiber Reinforced Metal by Liquid Phase Diffusion Bonding method with SiC fiber as a reinforcing material and CP Ti(Commercial Pure) as a matrix. The microstructure and the distribution of elements in reaction and CP Ti(Commercial Pure) as a matrix. The microstructure and the distribution of elements is reaction zone among CP Ti/Ti-15wt%Cu-20wt%Ni(TCN20)/SiC long fiber were investigated by Optical Microscope, SEM/EDX, EPMA, X-ray and AES. The results obtained in this study are as follows. 1) When Ti matrix composite materials are fabricated under the bonding condition of 1273Kx1200sec, the SiC long fiber was the most suitable reinforcing material for Ti matrix composite materials. 2) With SiC long fiber under same condition, a TiC layer(1.0-1.6$\mu\textrm{m}$) was observed on the surface of SiC long fiber. 3) Liquid Phase Diffusion Bonding has shown the feasibility of production of Ti matrix composite materials.

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Permeability Measurement of a Circular Braided Preform for Resin Transfer Molding

  • Cho, Yun Kyoung;Song, Young Seok;Kang, Tae Jin;Chung, Kwansoo;Youn, Jae Ryoun
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.135-144
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    • 2003
  • Permeability of the preform is one of key factors in design of RTM (Resin Transfer Molding) mold, determination of processing conditions, and modeling of flow in the mold. According to previous studies, permeability measured in the unsaturated fiber mats are higher than that in the saturated fiber mats by about 20% because of the capillary pressure. In this study, permeabilities of several fiber preforms are measured for both saturated and unsaturated flows. A saturated experiment of radial flow has been adopted to measure the permeability of anisotropic fiber preforms with high fiber content, i.e., circular braided preforms. In this method, four pressure transducers are used to measure the pressure distribution. Permeabilities in different directions are determined and the experimental results show a good agreement with the theory. Since permeability is affected by the capillary effect, permeability should be measured in the unsaturated condition for the textile composites to be manufactured under lower pressure as in the Vacuum Assisted Resin Transfer Molding (VARTM).

Characteristics of Glass/Carbon Fiber Hybrid Composite Using by VARTM (VARTM 공정을 이용한 유리/탄소섬유 하이브리드 복합체의 특성)

  • Han, In-Sub;Kim, Se-Young;Woo, Sang-Kuk;Hong, Ki-Seok;Soe, Doo-Won
    • Journal of the Korean Ceramic Society
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    • v.43 no.10 s.293
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    • pp.607-612
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    • 2006
  • In VARTM (Vacuum Assisted Resin Transfer Molding) process, the permeability generally controls the filling time of the resin and it also affects the void characteristics of the fiber composite. In this study, carbon and glass fiber inter-layered hybrid composites (carbon fiber centered stack) with an epoxy matrix were fabricated by VARTM process and evaluated the resin flow and macro void characteristics. The permeability of glass fiber was higher than that of carbon fiber used in this study. Using Darcy's equation, the permeability of hybrid composites could be predicted and experimentally confirmed. After curing, the macro void content of hybrid composites was investigated using image analyzer. The calculated filling time was well agreed with experimental result and the void content was significantly changed in hybrid composites.

Study on the Development of Steam Boiler using Carbon-fiber Heater (탄소섬유 발열체를 이용한 증기 보일러 개발에 관한 연구)

  • Kim, Bu-Ahn;Kang, Suk-Jun;Choi, Young-Min;Moon, Chang-Kown
    • Journal of Power System Engineering
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    • v.21 no.3
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    • pp.30-36
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    • 2017
  • Carbon fiber shows excellent heat generation value and thermal efficiency comparing with the metallic materials because of its far infrared-rays and radiant heat. So, high performance and economic steam boiler system for the industry can be manufactured by using the carbon fiber heater. The far infrared ray radiation rate was more than 90 % of carbon fiber. Steam boiler system with carbon fiber heater in this study is made up of heating section. In the proof test of steam boiler, the aimed temperature and dwelling time were at $500^{\circ}C$ for 8,000 hours, $600^{\circ}C$-3,000 hours, and $700^{\circ}C$-1,000 hours. The temperature rise rate of steam boiler with carbon fiber heater was about 40% faster than that of the conventional boiler.

Nondestructive Damage Sensitivity for Functionalized Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Acoustic Emission (전기저항 측정과 음향방출을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.42-45
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    • 2003
  • Nondestructive damage sensing and mechanical properties for acid-treated carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites were investigated using electro-micromechanical technique and acoustic emission (AE). Carbon black (CB) was used to compare to CNT and CNF. The results were compared to the untreated case. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity under double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. For surface treatment case, the damage sensitivity and reinforcing effect were higher than those of the untreated case. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Nondestructive Damage Sensitivity of Carbon Nanotube and Nanofiber/Epoxy Composites Using Electro-Micromechanical Technique and Acoustic Emission (Electro-Micromechanical 시험법과 음향방출을 이용한 탄소 나노튜브와 나노섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능)

  • Kim, Dae-Sik;Park, Joung-Man;Lee, Jae-Rock;Kim, Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.117-120
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    • 2003
  • Electro-micromechanical techniques were applied using four-probe method for carbon nanotube (CNT) or nanofiber (CNF)/epoxy composites with their content. Carbon black (CB) was used to compare with CNT and CNF. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity for double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites, and in CB case they were the lowest compared with CNT and CNF. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Spatting Resistance of High Strength RC Column Covering Spray-on Materials of Fiber Composite Spray Mortar(FCSM) (섬유복합모르터의 뿜칠마감에 의한 고강도콘크리트 기둥부재의 폭렬방지)

  • Song Yong-Won;Han Dong-Yeob;Lee Gun-Cheol;Goh Kyoung-Taek;Kim Jin-Soo;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.5-8
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    • 2006
  • High strength concrete has been increasingly used in high rue building and it is very obvious re consider fire resistance performance of that. Unlike the normal strength concrete, high strength concrete in sudden elevating temperature at fire is susceptible to spalling with severe explosion and surface split, due to high density of concrete. In order to endure the spalling, inner space temperature of concrete should be control less than certain point. Therefore this study investigated the influence of covering materials on high strength concrete finishing spray-on materials of fiber composite spray mortar(FCSM). Both polypropylene(PP) and polyvinyl alcohol(PVA) fiber were used in this test. Test showed that concrete, covering 18mm mortar containing PVA fiber and confining metal lath 2.3mm thickness, decreased 50% of main bar ambient temperature. compared with control concrete. In addition, concrete covering 18mm mortar without fiber caused falling of covering materials and then it was exposed in elevating temperature. As a result, spatting of the concrete occurred same as control concrete. However, concrete covering spray-on mortar containing PVA or PP fiber resisted spatting occurrence.

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potential of Noncircular Fiber as Reinforcing Material l. C-type carbon fiber

  • Boh, Shim-Hwan;Rhee Bo sung
    • Korean Journal of Materials Research
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    • v.4 no.7
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    • pp.817-822
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    • 1994
  • The reinforcing effect of C-shape carbon fiber was investigated as comparing to typical round-shape fiber with similar properties. The results show that C-shape fiber reinforced materials have better in almost all aspects of mechanical properties, or 218% in flexural strength, 223% flexural modulus, 157% interlamina shear strength, 227% impact strength, 184% transverse flexural strength and so on. Also in damping characteristics considerably concerned with fatigue life, friction/wear coefficient of a material, C-CF/EP had about 185% greater. In this research, we present the potential of non-circular fiber reinforcing materials by C-shape carbon fiber.

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Polyacrylonitrile based Copolymer Synthesis and Precursor Fiber Spinning for Manufacturing High-performance Carbon Fiber (고성능 탄소섬유 제조를 위한 폴리아크릴로니트릴 기반 공중합 고분자 합성 및 전구체 섬유 방사)

  • Ju, Hyejin;Han, Minjung;Song, Kyunghyun;Jeon, Changbeom;Jeong, Hwakyung;Kim, Min Jeong;Chae, Han Gi
    • Composites Research
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    • v.35 no.2
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    • pp.115-119
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    • 2022
  • The performance of carbon fiber is important for the production of these high-quality polymer composite materials such as CFRP (Carbon Fiber Reinforced Plastic). For this purpose, it is essential to use an optimized spinning process for improving the mechanical, physical, and structural properties of the precursor fiber, which greatly affects the properties of the carbon fiber, and the use of a suitable precursor polymer. In this study, the content of MAA (Methacrylic Acid), MAA injection time, and concentration of AIBN (2,2'-Azobis(2-methylpropionitrile)) were set as parameters for the polymer synthesis process, and Poly(AN-co-MAA) (poly(acrylonitrile-co-methacrylic acid)) was polymerized by solution polymerization. Poly(AN-co-MAA) with a molecular weight of 305,138 g/mol and an MAA ratio of 4.2% was dissolved in DMF (N,N-dimethylformamide) at a concentration of 16.0 wt%, and then a precursor fiber was prepared through dry-jet-wet spinning. The precursor fiber had a tensile strength of ~1.06 GPa and a tensile modulus of ~22.01 GPa, and no voids and structural defects were observed on the fiber.