• Title/Summary/Keyword: ferrous p/m

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Fundamental Properties of MxP (M = Ti, V, Fe: x = 2, 3) Binary and Ternary Compounds

  • Yun, Won-Seok;Lee, Jee-Yong;Kim, In-Gee
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2012년도 임시총회 및 하계학술연구발표회
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    • pp.36-37
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    • 2012
  • In this study, the fundamental properties of $M_xP$ (M = Ti, V, Fe; x = 2, 3) binary compounds were investigated in terms of the FLAPW method within GGA. The calculated lattice parameters are well consistent with experimental values. Among considered systems, only the FM state of $Fe_xP$ compounds found to be more stable compared to the NM one. Discussion on the fundamental properties of $M_xP$ ternary compounds also will be given.

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기화성방청제 Dialkylamine (di-)nitrobenzoates 합성 및 방청성능 (Synthesis and Performance of Dialkylamine (di-)nitrobenzoates for Vapor Corrosion Inhibitor)

  • 전용진;박용성;소순영
    • 공업화학
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    • 제10권1호
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    • pp.6-11
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    • 1999
  • 방청제로 dialkylaminc (di-)nitrobenzoates 14개 화합물을 합성하고 첨가제 효과와 함께 방청성능을 조사하였다. 합성화합물은 원소분석, FT-IR, $^1H$-NMR 분석으로 확인하였으며, 합성한 화합물과 첨가제 [$(NH_4)_2CO_3$, $NaHCO_3$]의 방청성능은 방청제를 1 M $Na_2SO_4$ 용액에 1% (w/v) 용해시켜 potentiostatic method로 분극실험하여 조사하였다. 철에 대해 dialkylamine 3, 5-dinitrobenzoates보다 dialkylamine 4-nitrobenzoates 부동태화 전류밀도 ($i_p$)가 작았으며, diethylamine 4-nitrobenzoate 용액에서 낮은 값 ($i_p$; $4.78mA/cm^2$)을 나타내었다. 비철에 대한 $i_p$값은 dialkylamine 3, 5-dinitrobenzoates가 작았고 dipropylamine 3, 5-dinitrobenzoate와 hexamethyleneimine 3, 5-dinitrobenzoate가 낮은 값 ($i_p$; 36, $37mA/cm^2$)을 나타냈다. 방청제에 $(NH_4)_2CO_3$$NaHCO_3$ 첨가효과는 철에 대해 높은 부식억제 효과를 나타냈으나, 비철에서는 좋은 결과를 얻지 못하였다. 철용 방청제 diethylamine 4-nitrobenzoate와 $(NH_4)_2CO_3$, $NaHCO_3$의 최적 혼합비율은 4 : 6과 5 : 5이며, 부동태화 전류밀도 ($i_p$)는 0.26, $0.85mA/cm^2$의 최소값을 각각 나타내었다.

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돼지동결정액의 체외수정능력에 있어서 Ascorbic Acid 와 Ferrous Sulfate 의 영향 (Effects of Ascorbic Acid and Ferrous Sulfate on In-Vitro Fertility of Frozen-Thawed Spermatozoa in Porcine)

  • 남희선;박춘근;정희태;이상찬;김종흥;양부근;김정익
    • 한국가축번식학회지
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    • 제23권3호
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    • pp.229-237
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    • 1999
  • 본 연구는 돼지 동결-융해 정자의 전배양시 aseorbie acid (Ase)와 ferrous sulfate (Fe$^{2+}$)가 정자의 수정능력획득, 첨체반응 및 난자내 침입능력에 미치는 영향을 검토하였다. 정자의 전배양시 0~1.0 mM의 Fe$^{2+}$의 첨가는 비전배양에 비해 높은 첨체반응 (P<0.05) 및 정자침입율을 얻었다. 이와 같은 결과는 0~0.5mM의 Ase 첨가 시 첨체반응율에서는 같은 결과를 나타냈지만 정자침입율은 오히려 정자의 전배양 보다는 비전배양시 높은 비율을 나타냈다. 한편, Fe$^{2+}$가 함유 되어있는 배양액내에서 2시간동안 정자의 전배양시 0.1 mM Asc의 첨가는 0.5 mM Ase의 첨가에 비해 유의적으로 높은 첨체반응율을 나타냈으나 (P<0.05), Ase의 농도사이에서 정자침입율에는 차이가 없었다. 또한, Ase가 함유된 배양액내에서 정자의 전배양시 0.1 mM Fe$^{2+}$를 첨가했을 때 첨체반응율은 Fe$^{2+}$ 무첨가시 유의적으로 높았으나 (P<0.05), 오히려 가장 낮은 정자침입율을 나타냈다. 이와 같은 결과는 체외에서 돼지정자의 처리시 Fe$^{2+}$ 또는 Ase의 첨가와 정자의 전배양에 의해 첨체반응과 정자침입에 효과적인 작용을 하는 것으로 생각된다.

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Altered APP Carboxyl-Terminal Processing Under Ferrous Iron Treatment in PC12 Cells

  • Kim, Chi Hyun;Yoo, Yeong-Min
    • The Korean Journal of Physiology and Pharmacology
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    • 제17권3호
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    • pp.189-195
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    • 2013
  • Amyloid-${\beta}$ peptide ($A{\beta}$), generated by proteolytic cleavage of the amyloid precursor protein (APP), plays a pivotal role in the pathogenesis of Alzheimer's disease (AD). The key step in the generation of $A{\beta}$ is cleavage of APP by beta-site APP-cleaving enzyme 1 (BACE1). Levels of BACE1 are increased in vulnerable regions of the AD brain, but the underlying mechanism is unknown. In the present study, we reported the effects of ferrous ions at subtoxic concentrations on the mRNA levels of BACE1 and a-disintegrin-and-metalloproteinase 10 (ADAM10) in PC12 cells and the cell responses to ferrous ions. The cell survival in PC12 cells significantly decreased with 0 to 0.3 mM $FeCl_2$, with 0.6 mM $FeCl_2$ treatment resulting in significant reductions by about 75%. 4,6-diamidino-2-phenylindole (DAPI) staining showed that the nuclei appeared fragmented in 0.2 and 0.3 mM $FeCl_2$. APP-${\alpha}$-carboxyl terminal fragment (APP-${\alpha}$-CTF) associations with ADAM10 and APP-${\beta}$-CTF with BACE1 were increased. Levels of ADAM10 and BACE1 mRNA increased in response to the concentrations of 0.25 mM, respectively. In addition, p-ERK and p-Bad (S112, S155) expressions were increased, suggesting that APP-CTF formation is related to ADAM10/ BACE1 expression. Levels of Bcl-2 protein were increased, but significant changes were not observed in the expression of Bax. These data suggest that ion-induced enhanced expression of AMDA10/BACE1 could be one of the causes for APP-${\alpha}/{\beta}$-CTF activation.

Sinter-hardening Process of P/M Steels and its Recent Developments

  • Yi, Jianhong;Ye, Tuming;Peng, Yuandong;Xia, Qinglin;Wang, Hongzhong
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.303-304
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    • 2006
  • The mechanical properties of ferrous powder metallurgy (P/M) materials are directly related to their microstructure. Ferrous P/M materials with sufficient hardenability will develop microstructures containing significant percentages of martensite in the as-sintered condition. Recently, sinter-hardening has developed into a highly cost effective production method through hardened P/M parts without the need for additional heat-treatments. This paper reviews the advances of sinter-hardening as well as some key processing parameters such as sintering temperature, cooling rate, tempering required to produce high quality sinter-hardened components. Specific topics including effect of alloying elements, alloying methods, and the Characterization and observation of microstructure are discussed.

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납으로 오염된 철성분 함유토의 동전기 정화 특성에 세척제가 미치는 영향 (The Effect of Flushing Solutions on ElectroKinetic Remediation of Ferrous Soil Contaminated by Lead)

  • 김수삼;김병일;한상재;김정환
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제9권1호
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    • pp.54-62
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    • 2004
  • 본 연구에서는 납으로 오염된 유기물과 철성분이 다량 함유된 철성분 함유토에 대한 정화 효율을 향상시키기 위해 세척제로 산, 킬레이트제 및 계면활성제를 사용하여 동전기 정화실험을 실시하였다. 실험결과 주입되는 세척제의 pH가 낮을수록 양극(兩極)저수조의 pH는 더 빠른 시간에 정상상태 값에 도달하였으며, 전압 분포의 경우 세척제 종류에 따른 차이는 크게 나타나지 않았고, 주입용액의 농도가 증가함에 따라 (+)극으로부터 정규화된 거리인 0.9지점에서의 전압은 더 크게 나타나는 경향을 보였다. 또한, 음이온성 계면활성제인 SDS가 가장 높은 잔류 납농도 분포를 보였다. 세척제 농도의 경우 1 mM의 Acetic acid에서 가장 양호한 정화효율을 보였지만, 아세트산의 농도 변화는 철성분 함유토(Ferrous soil)의 동전기 정화 효율에 큰 영향을 미치지 않는 것으로 나타났다.

Potential valorisation of ferrous slag in the treatment of water and wastewater: A review

  • Anjali, M.S.;Shrihari, S.;Sunil, B.M.
    • Advances in environmental research
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    • 제8권1호
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    • pp.55-69
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    • 2019
  • The generation of ferrous slag, an industrial by-product from the iron ore industry, results in serious environmental problems. The chemical compositions indicate 30-34% SiO2, 30-34% CaO, 18-22% Al2O3 and 0.5-0.6% Fe2O3. The specific gravity, moisture content and pH are in the range of 1.3-1.65, 9.1-10% and 8.5-9.0 respectively. The major part of the slag is composed of sand-size particles. The problems of disposal of slag could be minimized by considering its use in various environmental engineering applications providing additional value to the by-product. This paper mainly focuses on the potential utilization and valorisation of ferrous slag in both water and wastewater treatments. It is effective for the treatment of water and wastewater containing nutrients, heavy metals and polluted river/stormwater.

버섯중 철이온에 활성화된 광감응성 Mitochondrial ATPase에 관한 연구 (Study on the Light-Induced Mitochondrial ATPase$(F_1-ATPase)$ Activated by Iron ion in Mushroom)

  • 민태진;이미애;박상신
    • 한국균학회지
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    • 제21권3호
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    • pp.157-164
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    • 1993
  • 1. 표고버섯중 광감응성 mitochondrial $F_1-ATPase$$Fe^{3+},\;Fe^{2-}$$Mg^{2+}$ 이온에 의하여 각각 활성화 되었으나 5.0 mM $Fe^{3+}$ 이온에 의한 상대활성도는 대조구에 비하여 107% 증가시켰다. 2 $Mg^{2+}$ 존재하에서 $Fe^{3+}$$Fe^{2-}$ 각 이온 농도효과는 모두 효소의 활성을 증가시켰으나 0.1 mM $Mg^{2+}$과 5.0 mM $Fe^{3+}$ 이온의 공존하에서 170%를 증가시켜 $Mg^{2+}$ 이온에 의한 상승작용을 보였다. 3. 0.1 mM $Mg^{2+}$와 0.1 mM $Fe^{2+}$ 존재하에서 $Fe^{3+}$ 이온농도효과는 그 농도가 5.0 mM일 때 168%의 활성도 증가를 보여 $Fe^{2-}$ 이온공존효과는 없었다. 4. 이 효소는 $Mg^{2+}$$Fe^{3+}$ 이온에 의하여 활성화되는 특성을 가지고 있으며 활성금속이온 존재하에서 측정한 최적 pH 빛 온도는 각각 7.5 및 $66^{\circ}C$였다.

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화학적산화 및 생물학적처리법에 의한 사진폐액의 처리 (Treatment of Photographic Wastewater by Chemical Oxidation and Biological Treatment process)

  • 정경훈;최형일
    • 한국환경보건학회지
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    • 제23권1호
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    • pp.34-42
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    • 1997
  • A laboratory experiments were performed to investigate the treatment of photographic processing wastewater by chemical oxidation and biological treatment system. The effect of reaction conditions such as hydrogen peroxide dosage, ferrous sulfate dosage and pH on the COD removal in Fenton oxidation were investigated. The optimal dosage of hydrogen peroxide was 2.58 M and 3.87 M for the developing and fixing process wastewater, respectively. The Fenton oxidation was most efficient in the pH range of 3-5 and the optimal condition for initial reaction pH was 5 for a developing process wastewater. With iron powder catalyst, the COD for a developing process wastewater was removed in lower pH than with ferrous sulfate catalyst. The removal efficiency of COD for refractory compounds such as Diethyleneglycol, Benzylalcohol, Hydroxylamine Sulfate, Ammonium Thiosulfate, Ammonium Ferric EDTA and Disodium EDTA in the photogaphic wastewater was found than 90% except Potassium Carbonate. When the photographic processing wastewater after pretreatment by Fenton oxidation was treated with batch activated sludge process, the addition of $KH_2PO_4$ as a phosphorous compound improved the removal efficiency of COD. During the continuous biological treatment of developing and fixing process wastewater after pretreatment by Fenton oxidation, the effluent COD concentration less than 100 mg/l was obtained at 0.425 and 0.25 kgCOD/m$^3$.d, respectively.

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