• 제목/요약/키워드: ferromagnetic shape memory alloys

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자성 Co-Ni 계 형상기억합금의 특성 (Characterization of Co-Ni Based Ferromagnetic Shape Memory Alloy)

  • 한지원;박성범
    • 한국안전학회지
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    • 제30권4호
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    • pp.8-13
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    • 2015
  • The magnetic shape memory alloys have recently received a lot of attention due to the considerable progress achieved in understanding the particular importance and the development of the factors. Among these alloys, the ferromagnetic Co-Ni- alloys have been concerned specially because of the thermoelastic character of the fcc (g) - bct (a) martensitic transformation which exhibits under the action of the temperature (shape memory effect), the stress (superelasticity) and the magnetic field (magnetoelasticity). The morphological, the crystallographical, and the thermal characteristics of thermally induced martensite in Co-35.3Ni-11.3Al(wt.%) and Co-28.1Ni-47.4Fe-3.3Ti (wt.%) alloy have been investigated by the scanning electron microscope (SEM), the X-ray Diffraction (XRD), and the differential scanning calorimeter (DSC).

Ni-Mn-Ga-Fe 강자성 형상기억합금의 미세파괴기구 및 파괴성질 (Microfracture Mechanism and Fracture Properties of Ni-Mn-Ga-Fe Ferromagnetic Shape Memory Alloys)

  • 어광준;이정무;남덕현;이성학
    • 대한금속재료학회지
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    • 제47권12호
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    • pp.787-796
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    • 2009
  • The fracture toughness improvement of Ni-Mn-Ga-Fe ferromagnetic shape memory alloys containing ductile particles was explained by direct observation of microfracture processes using an in situ loading stage installed inside a scanning electron microscope (SEM) chamber. The Ni-Mn-Ga-Fe alloys contained a considerable amount of ductile particles in the grains after the homogenization treatment at $800{\sim}1100^{\circ}C$. ${\gamma}$ particles were coarsened and distributed homogeneously along {$\beta}$ grain boundaries as well as inside {$\beta}$ grains as the homogenization temperature increased. The in situ microfracture observation results indicated that ${\gamma}$ particles effectively acted as blocking sites of crack propagation, and provided stable crack growth that could be confirmed by the R-curve analysis. This increase in fracture resistance with increasing crack length improved overall fracture properties of the alloys containing ${\gamma}$ particles.

강자성 $Ni_{2}MnGa$형상기억합금에서의 자장유기 변형 (Magnetic field-induced deformation in ferromagnetic $Ni_{2}MnGa$)

  • 정순종;민복기;양권승
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.323-326
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    • 2001
  • NI$_2$MnGa-based ferromagnetic shape memory alloys (FSMA) are hoped to be used as robust actuators with high performance and power density, as a replacement of other actuation materials such as thermo-mechanical SMAs and mechanical-electric piezoelectrics. Recently, we have observed significant shape changes under magnetic field application when single- and poly-crystalline forms are used. In the present study, two mechanisms have been proposed to predict the magnetic field-induced shape change as a function of external magnetic field at temperatures below Mr and above Ar. In the case of the field-induced shape change at temperature below M$_{f}$, paired martensite variants are assumed to form by application of magnetic field. The direction of magnetization in martensites formed in austenite matrix is assumed to be parallel to the applied magnetic field in the case of shape change by application at temperature above Af. Various energies has been considered in the shape change under two mechanisms.s.

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Ferromagnetic Resonance Observation of Martensitic Phase Transformation in Ni-Mn-Ga Ferromagnetic Shape Memory Films

  • Dubowik, J.;Kudryavtsev, Y.V.;Lee, Y.P
    • Journal of Magnetics
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    • 제9권2호
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    • pp.37-39
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    • 2004
  • Polycrystalline Ni-Mn-Ga films have been deposited onto mica substrates held at 720 K by flash-evaporation method. At room temperature the films have a tetragonal structure with a = b = 0.598 and c = 0.576 nm typical for bulk $Ni_2MnGa$ below a martensitic transformation. Temperature measurements of ferromagnetic resonance reveal a martensitic phase transformation at 310 K. The transformation brings about a substantial decrease in the effective magnetization and a drastic increase in the ferromagnetic resonance linewidth due to a strong increase in the magnetic anisotropy in the martensitic phase.

Effects of Ni Addition on the Microstructures and Magnetic Properties of Fe70-xPd30Nix High-Temperature Ferromagnetic Shape Memory Alloys

  • Lin, Chien-Feng;Yang, Jin-Bin
    • Journal of Magnetics
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    • 제17권2호
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    • pp.86-95
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    • 2012
  • This study investigated the effects of adding a third alloying element, Ni, to create $Fe_{70-x}Pd_{30}Ni_x$ (x = 2, 4, 6, 8 at.% Ni) ferromagnetic shape memory alloys (FSMAs). The Ni replaced a portion of the Fe. The $Fe_{70-x}Pd_{30}Ni_x$ alloys were homogenized through hot and cold forging to gain a ~38% reduction in thickness, next they were solution-treated (ST) with annealing recrystallization at $1100^{\circ}C$ for 8 h and quenched in ice brine, and then aged at $500^{\circ}C$ for 100 h. Investigation of the microstructures and magnetostriction indicated that the greater Ni amount in the $Fe_{70-x}Pd_{30}Ni_x$ alloys reduced saturation magnetostriction at room temperature (RT). It was also observed that it was more difficult to generate annealed recrystallization. However, with greater Ni addition into the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys, the $L1_0+L1_m$ twin phase decomposition into stoichiometric $L1_0+L1_m+{\alpha}_{bct}$ structures was suppressed after the $500^{\circ}C$/100 h aging treatment. The result was that the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys maintained a high magnetostriction and magnetostrictive susceptibility (${\Delta}{\lambda}{_\parallel}{^s}/{\Delta}H$) after the alloys were aged at $500^{\circ}C$ for 100 h. This magnetic property of the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys make it suitable for application in a high temperature (T > $500^{\circ}C$) and high frequency environments.