• Title/Summary/Keyword: fast ion

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Fast liquid crystal switching performance on indium zinc oxide films with low curing temperature via ion-beam irradiation (이온빔 조사된 저온 소성 인듐 아연 산화막을 이용한 액정의 고속 스위칭 특성 연구)

  • Oh, Byeong-Yun
    • Journal of IKEEE
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    • v.23 no.3
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    • pp.904-909
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    • 2019
  • Using the ion-beam irradiated indium zinc oxide (IZO) films which was cured at $100^{\circ}C$, uniform LC and homogeneous alignment of liquid crystal (LC) molecules was achieved. The IZO film was deposited on the glass substrate at the curing temperature of $100^{\circ}C$ and irradiated by the ion-beam which is an LC alignment method. To verify the LC alignment characteristics, polarizing optical microscope and the crystal rotation method were used. Additionally, it was confirmed that the LC cell with the IZO films had an enough thermal budget for high-quality LC applications. Field emission scanning electron microscope was conducted as a surface analysis to evaluate the effect of the ion-beam irradiation on the IZO films. Through this, it was revealed that the ion-beam irradiation induced rough surface with anisotropic characteristics. Finally, electro-optical (EO) performances of the twisted-nematic cells with the IZO films were collected and it was confirmed that this cell had better EO performances than the conventional rubbed polyimide. Furthermore, the polar anchoring energy was measured and a suitable value for stable LC device operation was achieved.

Etch Characteristics of CoTb and CoZrNb Thin Films by High Density Plasma Etching (고밀도 플라즈마 식각에 의한 CoTb과 CoZrNb 박막의 식각 특성)

  • Shin, Byul;Park, Ik Hyun;Chung, Chee Won
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.531-536
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    • 2005
  • Inductively coupled plasma reactive ion etching of CoTb and CoZrNb magnetic materials with the photoresist mask was performed using $Cl_2/Ar$ and $C_2F_6/Ar$ gas mixtures and characterized in terms of etch rate and etch profile. As the concentrations of $Cl_2$ and $C_2F_6$ gases increased, the etch rates of magnetic films decreased and the etch slopes became slanted. The $Cl_2/Ar$ gas was more effective in obtaining fast etch rate and steep sidewall slope than the $C_2F_6/Ar$ gas. As the coil rf power and dc bias increased, fast etch rate and steep etch slope were obtained but the redeposition on the sidewall was observed. This is due to the increase of ion and radical densities in plasma with increasing the coil rf power and the increase of incident ion energy to the substrate with increasing the dc bias voltage. By applying high density reactive ion etching to magnetic tunnel junction stack containing various magnetic films and metal oxide, steep etch slope and clean etch profile without redeposition were obtained.

Inhibitory Effects of Toxic Materials on Activation of Microorganisms in Coke Plant Wastewater (코크스폐수에 함유된 $S^{-2}$$SCN^-$이 미생물 활성에 미치는 영향)

  • Kim, Sang-Sik;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.423-427
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    • 2013
  • This research was carried out to identify the characteristics of the wastewater from coke oven gas (COG) purification process of the coke plant, and derive optimal operating conditions for the treatment of wastewater. The coke plant wastewater contains highly concentrated $S^{-2}$ and $SCN^-$ that are harmful to microorganisms, and their concentrations were 6.8~11.2 mg/L and 190~320 mg/L, respectively. When the $S^{-2}$ ion concentration was lower than 10 mg/L, $SV_{30}$ of active sludge was 280~ 340 mL and the sludge sedimentation velocity was very fast. But, when the $S^{-2}$ ion concentration was higher than 15 mg/L, $SV_{30}$ of the active sludge was 560~680 mL and the sludge sedimentation velocity was very slow. Also when the $SCN^-$ ion concentration was lower than 300 mg/L, $SV_{30}$ of the active sludge was 245~320 mL and the sludge sedimentation velocity was very fast. But, when the $SCN^-$ ion concentration was higher than 400 mg/L, $SV_{30}$ of the active sludge was 470~ 567 mL and the sludge sedimentation velocity was slow. To treat the wastewater generated by COG purification process of the coke plant effectively and to maintain microorganism activities in good conditions, the ion concentration of $S^{-2}$ and $SCN^-$ should be lower than 15 mg/L and 400 mg/L, respectively.

Enhanced Performance in a Lithium-ion Battery via the Crystal-aligned LiNi0.6Mn0.2Co0.2O2 and the Relevant Electrochemical Interpretation (결정배향 LiNi0.6Mn0.2Co0.2O2 전극활물질을 통한 리튬이차전지 성능 향상 및 이의 전기화학적 해석)

  • Cham, Kim
    • Journal of the Korean Chemical Society
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    • v.66 no.6
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    • pp.451-458
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    • 2022
  • Through the crystal alignment research based on the magnetic properties of LiNixMnyCo1-(x+y)O2 such as magnetic susceptibility and related anisotropy, a crystal aligned LiNi0.6Mn0.2Co0.2O2 electrode is obtained, in which the (00l) plane is frequently oriented perpendicular to the surface of a current collector. The crystal aligned LiNi0.6Mn0.2Co0.2O2 electrode steadily exhibits low electrode polarization properties during the charge/discharge process in a lithium-ion battery, thus affording an improved capacity compared to a pristine LiNi0.6Mn0.2Co0.2O2 electrode. The aligned LiNi0.6Mn0.2Co0.2O2 electrode may have an appropriate structural nature for fast lithium-ion transport due to the oriented (00l) plane, and thus it contributes to enhancing the battery performance. This enhancement is analyzed in terms of various electrochemical theories and experiment results; thus, it is verified to occur because of the considerably fast lithium-ion transport in the aligned LiNi0.6Mn0.2Co0.2O2 electrode.

Solubilities of Salen Derivatives and Their Cobalt Complex in Liquid and Supercritical CO2

  • Koh, Seung-Hyun;Jeon, Byung-Wan;Kim, Ha-Kwon;Park, Kwang-Heon;Kim, Hong-Doo
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.471-475
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    • 2004
  • The solubility of N,N'-Bis(salicylidene) ethylenediamine (n-salen) and N,N'-bis(3,5-di-tert-butylsalicylidene) ethylenediamine (t-butyl-salen) was studied with in-situ UV-VIS spectrometer. n-Salen is 3-5 times more soluble than t-butyl-salen in liquid or supercritical $CO_2$. This behavior may be attributed to Lewis acid-base interaction between salen and $CO_2$. The chelation of salen with $Co^{++}$ ion in supercritical condition was confirmed to be fast enough above room temperature. However, the metal ion extraction capability of t-butyl salen is relatively poor because of its low solubility and ionic nature of complex.

Adsorption Characteristic and Elution Behavior of Rare Earth Metals by Cryptand 22 Synthetic Resin (Cryptand 22 합성수지에 의한 희토류 금속들의 흡착특성과 용리행동)

  • 노기환;김준태
    • Journal of environmental and Sanitary engineering
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    • v.11 no.1
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    • pp.17-25
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    • 1996
  • Resins with cryptand 22 macrocyclic ligand attached to chloromethylated styrene-1,4-divinylbenzene by substitution reaction were prepared and the effect of pH, metal concentration and cross-linkage of the matrix on the adsorption for $UO_2^{2+}$, $Cd^{2+}$ and $Sm^{3+}$ was investigated. The metal ion was not adsorbed on the resins pH range below 3 but above pH 4 fast adsorption behavior was showed. The resin selectivity determined in ethanol matrix was in increasing order $UO_2^{2+}{\;}>Cd^{2+}{\;}Sm^{3+}$. In addition, these metal ion could be separated on the column packed with 1% crosslinked resin by pH 2.5 $HNO_3$ as an eluent.

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Solution-Derived Amorphous Yttrium Gallium Oxide Thin Films for Liquid Crystal Alignment Layers

  • Oh, Byeong-Yun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.2
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    • pp.109-112
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    • 2016
  • We demonstrated an alternative electrically controlled birefringence liquid crystal (ECB-LC) system with ion beam (IB)-irradiated yttrium gallium oxide (YGaO) alignment films using a sol-gel process. The surface roughness of the films was dependent on the annealing temperature; aggregated particles on surface were observed at lower annealing temperatures, whereas a smooth surface could be obtained with higher annealing temperatures. Higher transmittance in the visible region was observed at higher annealing temperatures. The film had an amorphous crystallographic state irrespective of the annealing temperature. Furthermore, ECB-LC cell with our IB-irradiated YGaO film yielded faster response time when compared to ECB-LC cell with rubbed polyimide. Considering the fast response time and high transmittance, the IB-irradiated YGaO-base LC system is a powerful alternative application for the liquid crystal display industry.

Ion Sensitive Field Effect Transistor (감이온 전양효과 트랜지스트)

  • 손병기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.5
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    • pp.22-29
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    • 1981
  • An ion sensitive field effect transistor employing a special HCI heat treatment for the gate oxide layer along with tungsten metallization and multilayer encapsulation using fumed silica epoxy mixture was fabricated and its performance characteristics have been investigated. A theoretical model for the device operation is discussed, and it is shown that the experimental results are in good agreement with the theory. The fabricated device has excellent performance characteristics showing the fast response, long operation-life, small pH hysteresis, high sensitivity, etc. Especially, its stability has been greatly improved.

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MAGNETIC RECONNECTION IN SHEARED SOLAR MAGNETIC ARCADES

  • CHOE G. S.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.303-305
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    • 1996
  • The evolution of solar magnetic arcades is investigated with the use of MHD simulations imposing resistivity on sheared magnetic fields. It is found that there is a critical amount of shear, over which magnetic reconnection can take place ill an arcade-like field geometry to create a magnetic island. The process leading to reconnect ion cannot. be solely attributed to a tearing instability, but rather to a reactive evolution of the magnetic arcade under resistivity. The natures of the arcade reconnection are governed by the spatial pattern of resistivity. A fast reconnection with a small shock angle can only be achieved when the diffusion region is localized. In this case. a highly collimated reconnect ion outflow can tear the plasmoid into a pair, and most of principal features in solar eruptive processes are reproduced.

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Prebreakdown Avalanche Pulses in Compressed SF6 under Uniform Field (평등전계에서 압축 SF6가스의 절연파괴 선구 애벌렌체의 전류 펄스)

    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.33 no.3
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    • pp.106-111
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    • 1984
  • Prebreakdown current pulses arising from avalanche growth in SF6 were recorded under static uniform field at pressures up to about 400kpa. At pressures less than 100kpa the current pulses consist of the electron component observed as the fast rise of current, the negative ioncomponent which is superimposed, and the positive ion component comprising the tail of the pulse. The values of positive ion drift velocity were measured from the present pulse data. At pressures in excess of about 100 Kpa the pulse shapes becam distorted such that quantitative analysis was no longer possible, and did not indicate the action of any photosecondary process at the cathode. Breakdown appers to result from the seperate development of single avalanche.