• Title/Summary/Keyword: fast ion

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Capillary Electrophoresis Detection of Hydrogen Peroxide by Using Titanium Ion and 4-(2-thiazolylazo)resorcinol

  • Vu Phuong, Dong;Yoo, Hoon
    • International Journal of Oral Biology
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    • v.42 no.4
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    • pp.197-201
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    • 2017
  • A novel method for the detection of hydrogen peroxide in aqueous solution was developed via reaction between $H_2O_2$, trivalent titanium ion ($Ti^{3+}$) and 4-(2-thiazolylazo) resorcinol (TAR), resulting in a ternary complex with a maximum UV absorbance at 530 nm. The CE detection of $H_2O_2$ was fast, sensitive and cost-effective without pretreatment procedures. $H_2O_2$ was detected within 15 min at 1 to $100{\mu}M$ range with the lowest detection limit at $1.0{\mu}M$. Under the optimized CE conditions, the concentration of $H_2O_2$ in coffee or tea extract was quantitatively determined. Our results show that CE detection of the ternary complex of $H_2O_2-Ti^{3+}$-TAR has potential applications for the detection of $H_2O_2$ in aqueous sources.

Design and development of less than 1Kw Lithium rechargeable battery pack

  • Kim, Sang-Bum;Lee, Sang-Hyun
    • International Journal of Internet, Broadcasting and Communication
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    • v.10 no.3
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    • pp.104-108
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    • 2018
  • Lithium-ion batteries have been used in energy storage systems (ESS), electric vehicles (EVs), etc. due to their high safety, fast charging and long lifecycle. This paper aims to improve the convenience of users by changing the wired battery stack used in the battery pack, wirelessly using RFID, reducing the internal volume of the battery pack, reducing the size of the battery pack. In this paper, we propose a battery management system which can provide the flexibility of battery pack expansion and maintenance by using lithium ion battery, battery management system (BMS) and wireless communication for light weight of 1Kw small battery pack. Also, by flexibly arranging the cell layout inside the battery pack and designing to reduce the size of the outer shape of the battery pack.

Removal of Cs and Sr Ions by Absorbent Immobilized Zeolite with PVA (제올라이트를 PVA로 고정화한 흡착제에 의한 Cs과 Sr 이온 제거)

  • Lee, Chang-Han;Lee, Min-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.8
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    • pp.450-457
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    • 2015
  • In this research a adsorbent, PVA-Zeolite bead, was prepared by immobilizing zeolite with PVA. The results of XRD and SEM analysis showed that the prepared PVA-Zeolite beads had porous structure and the zeolite particles were in mobilized within the internal matrix of the beads. The adsorption properties of Sr ion and Cs ion with the adsorbent were studied by different parameters such as effect of pH, adsorption rate, and adsorption isotherm. The adsorption of Sr ion and Cs ion reached equilibrium after 540 minutes. The adsorption kinetics of both ions by the PVA-Zeolite beads were fitted well by the pseudo-second-order model more than pseudo-first-order model. The equilibrium data fitted well with Langmuir isotherm model. The maximum adsorption capacities of Sr ion and Cs ion calculated from Langmuir isotherm model were 52.08 mg/g and 58.14 mg/g, respectively. The external mass transfer step was very fast compared to the intra-particle diffusion step in the adsorption process of Cs ion and Sr ion by the PVA-Zeolite beads. This result implied that the rate controlling step was the intra-particle diffusion step.

Development and Testing of a Prototype Long Pulse Ion Source for the KSTAR Neutral Beam System

  • Chang Doo-Hee;Oh Byung-Hoon;Seo Chang-Seog
    • Nuclear Engineering and Technology
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    • v.36 no.4
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    • pp.357-363
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    • 2004
  • A prototype long pulse ion source was developed, and the beam extraction experiments of the ion source were carried out at the Neutral Beam Test Stand (NBTS) of the Korea Superconducting Tokamak Advanced Research (KSTAR). The ion source consists of a magnetic bucket plasma generator, with multi-pole cusp fields, and a set of tetrode accelerators with circular apertures. Design requirements for the ion source were a 120kV/65A deuterium beam and a 300 s pulse length. Arc discharges of the plasma generator were controlled by using the emission-limited mode, in turn controlled by the applied heating voltage of the cathode filaments. Stable and efficient arc plasmas with a maximum arc power of 100 kW were produced using the constant power mode operation of an arc power supply. A maximum ion density of $8.3{\times}10^{11}\;cm^{-3}$ was obtained by using electrostatic probes, and an optimum arc efficiency of 0.46 A/kW was estimated. The accelerating and decelerating voltages were applied repeatedly, using the re-triggering mode operation of the high voltage switches during a beam pulse, when beam disruptions occurred. The decelerating voltage was always applied prior to the accelerating voltage, to suppress effectively the back-streaming electrons produced at the time of an initial beam formation, by the pre-programmed fast-switch control system. A maximum beam power of 0.9 MW (i.e. $70\;kV{\times}12.5\;A$) with hydrogen was measured for a pulse duration of 0.8 s. Optimum beam perveance, deduced from the ratio of the gradient grid current to the total beam current, was $0.7\;{\mu}perv$. Stable beams for a long pulse duration of $5{\sim}10\;s$ were tested at low accelerating voltages.

Industry safety characteristic of Prismatic EDLCs (각형 전기이중층 커패시터의 산업 안전성)

  • 김경민;장인영;강안수
    • Proceedings of the Safety Management and Science Conference
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    • 2004.05a
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    • pp.247-257
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    • 2004
  • Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

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Purification of Staphylococcal Enterotoxin A (Staphylococcal Enterotoxin A 의 분리 정제)

  • Lee, Jeong-Hee;Shin, Hyun-Kil;Kim, Jong-Bae;Kim, Jae-Jong;Yoon, Hao-Jung
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.780-786
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    • 1988
  • In order to investigate the most efficient and rapid method for the purification of enterotoxin A from Staphylococcus aureus M 7/1, various methods such as ion-exchange chromatography on Amberlite, and CM-cellulose. gel filtration on Sephadex G-50, 75, 100 and Sephacryl, and fast protein liquid chromatography (FPLC) were applied and compared in terms of purity and speed. Although ion-exchange chromatography on Amberlite resin was good enough to remove other materials in culture medium from enterotoxin, and convenient, and fast method, the purity of this method was less than 70%. However. carboxymethyl ion-exchange column showed to be better purity than that of Amberlite method. The yields of these two methods were about 70% and 75%, respectively. When gel filtration methods on Sephadex G-50, 75, 100 and Sephacryl were applied, the purity was about 90%. Fast protein liquid chromatography was found to be the most efficient method in terms of purity (97%) and speed. The combined method, gel filtration after CM-cellulose column (stepwise elution) treatment can be also used as a efficient method particularly for the purification of large volume of sample.

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Characteristics of manganese removal by ozonation: Effect of existing co-ion and optimum dosage (오존을 이용한 용존성 망간 제거 특성: 공존이온의 영향 및 최적주입량)

  • Kwak, Yeonwoo;Lee, Seulki;Lee, Yongsoo;Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.145-152
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    • 2018
  • This study is focused on manganese (Mn(II)) removal by ozonation in surface water. Instant ozone demand for the water was 0.5 mg/L in the study. When 0.5 mg/L of Mn(II) is existed in water, the optimum ozone concentration was 1.25 mg/L with reaction time 10 minutes to meet the drinking water regulation. The ozone concentration to meet the drinking water regulation was much higher than the stoichiometric concentration. The reaction of soluble manganese removal was so fast that the reaction time does not affect the removal dramatically. When Mn(II) is existed with Fe, the removal of Mn(II) was not affected by Fe ion. However As(V) is existed as co-ion the removal of Mn(II) was decreased by 10%. Adding ozone to surface water has limited effect to remove dissolved organic matter. When ozone is used as oxidant to remove Mn(II) in the water, the existing co-ion should be evaluated to determine optimum concentration.

Effects of ion irradiation on microstructure and properties of zirconium alloys-A review

  • Yan, Chunguang;Wang, Rongshan;Wang, Yanli;Wang, Xitao;Bai, Guanghai
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.323-331
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    • 2015
  • Zirconium alloys are widely used in nuclear reactors as structural materials. During the operation, they are exposed to fast neutrons. Ion irradiation is used to simulate the damage introduced by neutron irradiation. In this article, we briefly review the neutron irradiation damage of zirconium alloys, then summarize the effect of ion irradiation on microstructural evolution, mechanical and corrosion properties, and their relationships. The microstructure components consist of dislocation loops, second phase precipitates, and gas bubbles. The microstructure parameters are also included such as domain size and microstrain determined by X-ray diffraction and the S-parameter determined by positron annihilation. Understanding the relationships of microstructure and properties is necessary for developing new advanced materials with higher irradiation tolerance.