• 제목/요약/키워드: extinction coefficient

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화학적 환원법으로 제작한 은나노유체의 흡광계수 (Extinction Coefficient of Ag Nanofluids Manufactured by Chemical Reduction Method)

  • 이승현;김현진;최태종;김수빈;강예준;김동진;장석필
    • 한국분무공학회지
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    • 제20권1호
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    • pp.53-58
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    • 2015
  • In this study, we prepare the Ag nanofluids synthesized by the chemical reduction method and measure the extinction coefficient of those nanofluids at a wavelength of 632.8 nm. The Ag nanofluids are synthesized by the chemical reduction method using silver nitrate ($AgNO_3$) and sodium borohydride ($NaBH_4$) in water and ethylene glycol (EG). For stable dispersion of Ag particles in the base liquids, polyvinyl pyrrolidone (PVP) is added as a surfactant. The extinction coefficient of manufactured Ag nanofluids is measured by an in-house developed measurement system at the wavelength of 632.8 nm. The results show that the extinction coefficient of water-based and EG-based Ag nanofluids is linearly increased with respect to the particle loadings. Moreover, it is shown that the extinction coefficient of EG-based Ag nanofludis is higher than that of water-based Ag nanofluids. Finally we compare the experimental results with both the Maxwell-Garnett model and Rayleigh scattering approximation model, and they demonstrate that the Rayleigh scattering approximation model is reasonably predict the extinction coefficient of Ag nanofluids using hydraulic diameter of silver nanoparticle.

Aerosol Measurement and Property Analysis Based on Data Collected by a Micro-pulse LIDAR over Shanghai, China

  • Huang, Xingyou;Yang, Xiaowu;Geng, Fuhai;Zhang, Hua;He, Qianshan;Bu, Lingbing
    • Journal of the Optical Society of Korea
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    • 제14권3호
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    • pp.185-189
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    • 2010
  • A micro-pulse LIDAR system (MPL) was employed to measure the aerosol over Pudong, Shanghai from July 2008 to January 2009. Based on Fernald method, aerosol optical variables such as extinction coefficient were retrieved and analyzed. Results show that aerosol exists mainly in low layers; aerosol loading reaches its maximum in the afternoon, and then decreases with time until its minimum at night. Most of the aerosol concentrates in the layer below 3 km, and optical extinction coefficient in the layer below 2 km contributes 84.25% of that below 6 km. Two extinction coefficient peaks appear in the near surface layer up to 500 m and in the level around 1000 m. Aerosol extinction coefficient shows a seasonal downward trend from summer to winter.

Effects of Aerosol Hygroscopicity on Fine Particle Mass Concentration and Light Extinction Coefficient at Seoul and Gosan in Korea

  • Choi, Eun-Kyung;Kim, Yong-Pyo
    • Asian Journal of Atmospheric Environment
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    • 제4권1호
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    • pp.55-61
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    • 2010
  • The sensitivity of aerosol light extinction coefficient to the aerosol chemical composition change is estimated by (1) calculating the aerosol water content and chemical concentrations by a gas/particle equilibrium model and (2) calculating the aerosol light extinction coefficient by a Mie theory based optical model. The major chemical species are total (gas and particle phase) sulfuric acid, total nitric acid, and total ammonia which are based on the measurement data at Seoul and Gosan. At Seoul, since there were enough ammonia to neutralize both total sulfuric acid and total nitric acid, the dry ionic concentration is most sensitive to the variation of the total nitric acid level, while the total mass concentration (ionic concentration plus water content) and thus, the aerosol light extinction coefficient are primarily determined by the total sulfuric acid. At Gosan, since the concentration of ambient sulfuric acid was the highest among the inorganic species, sulfate salts determined aerosol hygroscopicity. Thus, both ionic and total mass concentration, and resultant aerosol light extinction coefficient are primarily determined by the sulfuric acid level.

서울 대기 에어로솔의 농도와 광소산에 관한 연구 (A Study on the Concentration and Light Extinction of Atmospheric Aerosol in Seoul)

  • 김필수;오미석;김의훈
    • 한국대기환경학회지
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    • 제7권3호
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    • pp.227-234
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    • 1991
  • This study deals with concentration and light extinction of atmospheric aerosol in Seoul. From the measured aerosol size distribution for particle diameter ranging from 0.01 $\mum \sim 1.0 \mum$, extinction coefficient is calculated using the Mie theory. The results show that the diurnal variation of aerosol concentration, in general, reveals the lowest concentration in early morning and afternoon, while the highest at about 8 O'clock owing to the heavy traffic and accumulation of air pollution in the low atmosphere. However, aerosol concentration and extinction coefficient on April 7 give low values due to the advective wind. On the other hand, high aerosol concentration and extinction coefficenat are recorded on April 10 although solar radiation is weak. From the distribution of extinction coefficient we can find that aerosol particles of 0.1 $\mum \sim 1.0 \mum$ in diameter are highly effective on light extinction.

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Optical Constants and Dispersion Parameters of CdS Thin Film Prepared by Chemical Bath Deposition

  • Park, Wug-Dong
    • Transactions on Electrical and Electronic Materials
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    • 제13권4호
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    • pp.196-199
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    • 2012
  • CdS thin film was prepared on glass substrate by chemical bath deposition in an alkaline solution. The optical properties of CdS thin film were investigated using spectroscopic ellipsometry. The real (${\varepsilon}_1$) and imaginary (${\varepsilon}_2$) parts of the complex dielectric function ${\varepsilon}(E)={\varepsilon}_1(E)+i{\varepsilon}_2(E)$, the refractive index n(E), and the extinction coefficient k(E) of CdS thin film were obtained from spectroscopic ellipsometry. The normal-incidence reflectivity R(E) and absorption coefficient ${\alpha}(E)$ of CdS thin film were obtained using the refractive index and extinction coefficient. The critical points $E_0$ and $E_1$ of CdS thin film were shown in spectra of the dielectric function and optical constants of refractive index, extinction coefficient, normal-incidence reflectivity, and absorption coefficient. The dispersion of refractive index was analyzed by the Wemple-DiDomenico single-oscillator model.

종류식 도로터널내에서의 환기 거동에 관한 연구 (A Study on the Ventilation in a Long Road Tunnel)

  • 양판석;조영진;이재헌
    • 대한기계학회논문집B
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    • 제22권8호
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    • pp.1091-1100
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    • 1998
  • Longitudinal distributions of the extinction coefficient and concentrations of hazardous gases in a long tunnel located in urban area haute been predicted theoretically. The results are compared with design criteria. It is found that the maximum concentrations of both CO and $NO_X$ in the tunnel are lower than the design criteria. However, the maximum extinction coefficient, generally considered to be a governing factor for ventilating flow rate, is shown lower than the design criterion. Therefore, it is suggested that the design criterion of the extinction coefficient should be increased to a slightly larger value.

Improvement of Field Calibration of a Transmissometer for Visibility Measurement

  • Kim Kyung W.;Kim Young J.
    • Journal of Korean Society for Atmospheric Environment
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    • 제21권E2호
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    • pp.49-56
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    • 2005
  • A long-path transmissometer is one of the optical instruments widely used to measure atmospheric light extinction coefficient without enclosing a light beam and perturbing aerosols. Over the past two decades, a number of measurements have been carried out using the long-path transmissometer manufactured by OPTEC, Inc. Calibration of the transmissometer should be performed when any component of the transmissometer system is interchanged or installation condition is changed. For a better calibration of the transmissometer, application of a modified calibration method for the existing neutral density (ND)-filter method was recommended for the computation of the atmospheric transmittance using model MODTRAN 4 in this study. It was revealed that the measured light extinction coefficient from the transmissometer which was calibrated using the existing ND-filter method could be overestimated due to the assumption of the atmospheric transmittance suggested by OPTEC, Inc. The uncertainty of the measured light extinction coefficient from the transmissometer calibrated based on the modified ND-filter method was calculated to be approximately $13Mm^{-1}$.

에어로졸의 광학 및 화학 특성 준실시간 모니터링을 통한 서울지역 시정 감쇄 분석 (Characteristics of Visibility Impairment by Semi-Continuous Optical and Chemical Property Monitoring of Aerosols in Seoul)

  • 박종성;박승명;송인호;신혜정;홍유덕
    • 한국대기환경학회지
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    • 제31권4호
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    • pp.319-329
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    • 2015
  • The characteristics of aerosol light extinction were investigated by comparing measured and calculated extinction coefficient to understand the contribution of air pollutants on visibility impairment for data during 4 months (Jan~ April), 2014. The integrated nephelometer and aethalometer system were installed to measure the scattering and absorption coefficients of aerosol as well as BAM 1020, MARGA, semi-continuous OCEC analyzer, and online-XRF to calculate the extinction coefficient. The IMPROVE_2005 equation was used to determine the contributions of different chemical components on visibility impairment in $PM_{2.5}$ and $PM_{10}$ due to highest correlation with measured data. Sulfate, nitrate, and organic mass by carbon (OMC) of fine aerosol were the major contributors affecting on visibility impairment. Total contributions to light extinction were calculated as $631.0Mm^{-1}$ for the worst-case and $64.4Mm^{-1}$ for the best-case. The concentrations of aerosol component for the worst-case were 38.4 times and 45.5 times larger than those of the best-case for $(NH_4)_2SO_4$ and $NH_4NO_3$, respectively. At lower visibility condition, in which extinction coefficient was higher than $400Mm^{-1}$, extinction coefficient varied according to the relative humidity variation regardless of $PM_{2.5}$.

상용 디지털 카메라를 이용한 3가지 유효 RGB 파장에서의 미세먼지 소산계수 산출법 (Aerosol-extinction Retrieval Method at Three Effective RGB Wavelengths Using a Commercial Digital Camera)

  • 박선호;김덕현
    • 한국광학회지
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    • 제31권2호
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    • pp.71-80
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    • 2020
  • 본 논문에서는 상용 카메라를 이용하여 미세먼지의 소산계수를 측정하기 위한 새로운 방법을 제안하였다. 하나의 주어진 영상에서 같은 방향에 놓인 동일한 종류의 물체에 대한 3개 이상의 화소점의 밝기를 이용하여 소산계수를 측정하였다. 계산에 사용하기 위해 선택된 화소에 해당하는 물체는 카메라와의 거리를 알고 있는 것으로 선택하였다. 카메라를 이용하여 측정한 미세먼지의 소산계수와의 비교를 위하여 라이다를 이용하여 소산계수를 측정하였다. 최종적으로 카메라를 이용하여 측정한 미세먼지의 소산계수와 라이다를 이용한 그것에는 신뢰할 수 있는 상관관계를 얻었으며, 약 0.86 정도의 값을 보였다. 같은 방법으로 카메라의 R, G, B 3센서의 유효파장에서 소산계수를 얻을 수 있다는 것을 보였으며, 이러한 3파장에서의 소산계수를 통하여 하루 동안의 옹스트롱 지수(Angstrom exponent) 변화를 얻었는데, 이 값은 0.7~1.6 범위에 존재한다는 것을 알 수 있었다. 이러한 지수는 입자의 크기와 관련된 중요한 정보로 사용할 수 있다.

Modelling of Aerosol Vertical Distribution during a Spring Season at Gwangju, Korea

  • Shin, Sung-Kyun;Lee, Kwon-Ho
    • Asian Journal of Atmospheric Environment
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    • 제10권1호
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    • pp.13-21
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    • 2016
  • The vertical distributions of aerosol extinction coefficient were estimated using the scaling height retrieved at Gwangju, Korea ($35.23^{\circ}N$, $126.84^{\circ}E$) during a spring season (March to May) of 2009. The aerosol scaling heights were calculated on a basis of the aerosol optical depth (AOD) and the surface visibilities. During the observation period, the scaling heights varied between 3.55 km and 0.39 km. The retrieved vertical profiles of extinction coefficient from these scaling heights were compared with extinction profile derived from the Light Detection and Ranging (LIDAR) observation. The retrieve vertical profiles of aerosol extinction coefficient were categorized into three classes according to the values of AODs and the surface visibilities: (Case I) the AODs and the surface visibilities are measured as both high, (Case II) the AODs and the surface visibilities are both lower, and (Others) the others. The averaged scaling heights for the three cases were $3.09{\pm}0.46km$, $0.82{\pm}0.27km$, and $1.46{\pm}0.57km$, respectively. For Case I, differences between the vertical profile retrieved from the scaling height and the LIDAR observation was highest. Because aerosols in Case I are considered as dust-dominant, uplifted dust above planetary boundary layer (PBL) was influenced this discrepancy. However, for the Case II and other cases, the modelled vertical aerosol extinction profiles from the scaling heights are in good agreement with the results from the LIDAR observation. Although limitation in the current modelling of vertical structure of aerosols exists for aerosol layers above PBL, the results are promising to assess aerosol profile without high-cost instruments.