• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.435-443
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• 2006

The objective of this paper is to provide fundamental information on the subject of high explosives not only to the explosive scientist but also to the chemical engineer. Technologies for the development of high explosives are divided into 5 areas: (1) synthesis of new energetics, (2) preparation of functional explosives, (3) formulation study of plastic bonded explosives, (4) application of high explosives to munitions, (5) demilitarization process. This paper outlines the basic technologies need to understand the high explosives.

• Explosives and Blasting
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• v.12 no.1
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• pp.39-45
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• 1994

• Explosives and Blasting
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• v.13 no.2
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• pp.5-9
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• 1995

• Explosives and Blasting
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• v.9 no.4
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• pp.35-56
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• 1991

• The Journal of the Korea Contents Association
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• v.13 no.11
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• pp.396-403
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• 2013

Explosive substances requires much effort for safety management because of the basically risk. The risk of explosives is increasing actually explosives accidents and crimes have been occured repeatedly and explosives used IED(Improvised explosive device) or roadside bomb recently. South Korea's basic legislation on the management of explosives is "guns, swords, explosives control Act" was enacted in 1961 as many amendments have been made. However, the Act has increased complexity gradually because of the technical expertise of explosives such as the development of new techniques. This study examines the historical background of Korea's explosives management and considers enactment amendments and propose measures to improve of explosives management Act.

• Tunnel and Underground Space
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• v.20 no.4
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• pp.252-259
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• 2010

In urban tunnels, namely, in case there are residents in the near distance, we normally use non-vibration and ambient vibration which are not blasting methods because it’ impossible to meet the blasting vibration regulation with only normal explosives. However, non-vibration methods not only cause increase of excavating cost, but need much time than explosives. Generally, the lower velocity explosives with 2,000 m/s VOD have been applied to ambient vibration blasting in open cut area, but difficult in tunneling in its use. However, by charging the hole together with lower velocity explosives and normal explosives, we have got the result which shows 20~30% vibration decrease compared with using only normal explosives. Therefore, I’ like to suggest the blasting method which is able to do as ambient vibration using lower velocity explosives mixed with normal explosives in urban tunnel and the area which is adjacent to security facilities within the vibration regulation.

• Explosives and Blasting
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• v.13 no.4
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• pp.73-81
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• 1995

Explosives demolition mothod is allowed for more efficient time-saving and safer demolitioni operations as compared to conventional / mechanical demolition methods. CDI has to minimize the effects of noise, dust and various demolition hazards to the public areas, and residences that are located adjacent to the project site. CDI's explosives demolition work on the Nam san Foreigner's Apartment Complex and chosun trading Co's factory are backed by over 45 years of explosives experience in the demolition of over 6,000 structures worldwide, many of these structures are similar to the Nam san Foreigner's Apt. and Chosun trading's factory in construction and proximity to sensitive adjacent exposures. Recoginized worldwide as the founder of the leader in explosives demolitioni technology, CDI always will applied "State-of-the-Art" explosives techniques to safely and successfully achieve the desired demolition results on these project. CDI has never injured, much less caused any fatality, to either a worker on one of our sites or to a third party during the implosion of high-rise structure.

• Journal of Integrative Natural Science
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• v.5 no.3
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• pp.175-181
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• 2012

Oxepane high explosives substituted to explosive group such as azido, nitrato and hydrazino are investigated theoretically the acid catalyzed reaction using the semiempirical MINDO/3, MNDO and AM1 methods to use as the guidelines of high explosives. The nucleophilicity and basicity of oxepane high explosives can be explained by the value of negative charge on oxygen atom of oxepane and the reactivity in propagation step can be represented by the value of positive charge on carbon atom and low electrophile LUMO energy. It was known that carbenium ion was favorable due to the stable energy (19.507~32.101 Kcal/mol) between oxonium ion and carbenium ion in the process of cyclic oxonium ion of oxepane high explosives being converted to open carbenium ion in oxepane high explosives. The value of concentration of cyclic oxonium ion and open carbenium ion in equilibrium status was found to be a major determinant of mechanism, it was expected to react faster in the prepolymer propagation step in SN1 mechanism than in that of $S_N2$.

• Explosives and Blasting
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• v.19 no.4
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• pp.31-36
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• 2001

This article was presented by the author at the ISEE\`s 27th Annual Conference on Explosives and Blasting Technique in January, 2001 in Orlando, Florida. This article has been updated from tits original version. The opinions and ideas expressed are not necessarily those of the International Society of Explosives Engineers or the editorial/publishing staff of the Journal of Explosives Engineering. Your esponse in form of letters to editor is encouraged.

• Explosives and Blasting
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• v.17 no.3
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• pp.29-34
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• 1999