• Title/Summary/Keyword: expansion ratio

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Chemical Devulcanization for the Recycling of Rubber Powder of Waste Tires and Mechanical Properties (폐타이어 고무분말 재활용을 위한 화학적 탈황과 기계적 물성 평가)

  • An, Ju-Young;Park, Jong-Moon;Bang, Daesuk;Kim, Bong-seok;Oh, Myung-Hoon
    • Resources Recycling
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    • v.24 no.3
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    • pp.59-65
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    • 2015
  • Recycling of vulcanized rubber products is a serious problem in the world. A quantity of generated waste tires becomes much more and more because of increasing demands on automobiles, resulted in the cause of serious secondary pollution by sulfur component that is crosslinked to incineration or landfill. In addition, crosslinked surfur is used to interfere with the binding of the raw material rubber. In this study, we analyzed the degree of devulcanization by the chemical devulcanization. Devulcanization ratio of the samples were systematically analysed by variables such as time and temperature. In addition, the effect of swelling method as a pre-treatment process was also measured. A rubber specimen was deepened in a organic 2-buthanol solutions during various times of 1 ~ 5 hrs at 100, 150, $200^{\circ}C$ respectively, then to calculate the crosslink density and the number average molecular weight by using a parallel expansion process, which showed devulcanization degree of analyzed samples quantitatively. Also, the mechanical properties were measured with the samples prepared by using a hot press.

Heat Transfer in Heat Storage System with P.C.M. -Experimental and Numerical Investigation during Inward Melting in a Vertical Tube- (상변화 물질을 사용한 축열조에서의 열전달 -수직원관내에서의 내향용융실험 및 수치해석-)

  • Yim, Chang-Soon;Choi, Guk-Gwang;Lee, Cha-Moon;Kim, Jun-Gun;Shong, Ha-Jin;Cho, Nam-Cheol
    • Solar Energy
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    • v.10 no.1
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    • pp.5-13
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    • 1990
  • In the present investigation, experiments and numerical analysis during melting process of a phase change material were performed to research heat transfer phenomena generated by means of conduction and natural convection in the vertical tube at inward melting. The phase change material used in the experiments is 99 percent pure n-Docosane paraffin($C_{22}H_{46}$). In the results, it is found that the velocity of phase change interface at the top of tube is faster than at the bottom of tube because of the effect of natural convection, and the distribution of velocity at the liquid region is little affected by the initial temperature of phase change material. The velocity of phase change interface is slower as the initial temperature of phase change material is lower, and the effect of natural convection is larger as the aspect ratio of tube is larger. In tendency of heat transfer phenomena, the experimental results were well corresponded with numerical results. But there were a little disagrements between the results of experiment and numerical analysis because of the assumption of the constant volumetric expansion coefficient in numerical analysis.

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Preparation and characterization of La0.8Sr0.2Ga0.8Mg0.1Co0.1O3-δ electrolyte using glycine-nitrate process (Glycine nitrate process로 합성된 La0.8Sr0.2Ga0.8Mg0.1Co0.1O3-δ 전해질의 제조 및 특성평가)

  • Ok, Kyung-Min;Kim, Kyeong-Lok;Kim, Tae-Wan;Kim, Dong-Hyun;Park, Hee-Dae;Sung, Youl-Moon;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.37-43
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    • 2013
  • Conductivity of LSGMC materials were affected by secondary phase segregation, composition and synthetic route. $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.1}Co_{0.1}O_{3-{\delta}}$ (LSGMC) powders were prepared using the glycine nitrate process to produce high surface area and compositionally homogeneous powders. The powders were synthesized with different 0.5, 1, 1.5, 2, 2.5 of glycine/cation molar ratios. A single perovskite phase from the synthesized powders was characterized with X-ray diffraction patterns. The obtained sintered pellets showed the dense grain microstructure. In case of 1.5 molar ratio, its density was higher than the others. The electrical conductivity measured at $800^{\circ}C$ was observed to be 0.131 $Scm^{-1}$. In addition, the linear thermal expansion behavior was indicated between $25^{\circ}C$ and $800^{\circ}C$.

Change of Reproductive and Histological Biomarkers of Ruditapes philippinarum (Bivalvia: Veneridae) Exposed to Nonylphenol (노닐페놀에 노출된 바지락, Ruditapes philippinarum의 생식 및 조직학적 지표 변화)

  • Park, Ji-Seon;Lee, Jung-Sick
    • The Korean Journal of Malacology
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    • v.27 no.3
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    • pp.181-190
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    • 2011
  • This study was investigated to find out the change of reproductive and histological biomarkers of Ruditapes philippinarum exposed to nonylphenol (NP). Experimental period was 16 weeks. Experimental groups were composed of one control condition and three NP exposure conditions (0.05, 0.1, $0.2 mg\;NP\;L^{-1}$). Gonad index was higher in exposure group than control in female and higher in control than exposure group in male. Intersexuality in the NP exposure group was 14.56% with male exhibiting higher ratio than female. Histological analysis of organ system illustrated expansion of hemolymph sinus, loss of striated border of inner epidermis and degeneration of mucous cell in the mantle. In the gill partially disappearance of frontal and lateral cilia, degeneration of mucous cell were observed. Also, hyperplasia of epithelium and disappearance of striated border were observed in the foot. As the concentration of NP increased, the accumulation of lipofuscin increased in the digestive gland. The results of this study suggest that NP induces reduction of survival rate, histopathology and intersex of R. philippinarum. Furthermore, it is indentified that NP functions as an estrogenic effector on the reproduction of R. philippinarum.

Analysis of PLAN Modernization Trend and Prospects for Balance of U.S-China Naval power in the East Asia (중국해군(PLAN)의 현대화 추세와 동아시아 지역의 미·중 해군력 균형 전망)

  • Kwon, Jeong Wook
    • Strategy21
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    • s.43
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    • pp.5-28
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    • 2018
  • The tensions between the U.S and China, which form the two pillars of the G2 era, seem to have persisted even after the Trump administration inaugurated. The strong confrontation between the two in recent foreign security issues may drive to develop an inadvertent military conflict, and it is high likely to occur in the maritime are. The purpose of this study is not only to analyze the balance of modernized naval forces in the PLAN through naval strategy changes and weapons system modernization trend, but also to predict the impact of the geographical proximity difference on the balance of naval forces in the disputed areas. It examined the impact of distance and geography on naval power by assessing the modernization pattern of the PLAN and capabilities in the context of two scenarios at different distances from China by 2020: one centered on Taiwan and the other on the Spratly Islands. The PLAN's strategy had impact on operational concept and forces construction. First, from the viewpoint of operation operational concept, it can be seen that the passive defense is changing into active defense. Second, in terms of power construction, it can threaten the surface and submarines of U.S power from a distance. And they generated follow three features; The ocean is not the focus of Chinese submarines, Horizontal and vertical expansion of Chinese naval vessels, The improvement of the suppression ability as the Chinese naval modernization ratio increases. The strength of the PLAN is dominant over the U.S in terms of reserves, and it can complement the qualitative deterioration by utilizing nearby bases in the vicinity of the mainland, such as the Taiwan Strait. However, due to the shortage of aircraft carriers, there is a possibility that it will take some time to secure the advantage of air and ocean in the amphibious operation. Therefore, as the dispute is prolonged, China may fail to achieve its original goal. In addition, the lack of cutting edge Commanding Ships may bring to weaken the C2 capabilities. At results, it is expected that PLAN will not be able to have a superiority in the short term due to lagging behind U.S advanced technology. Nevertheless, PLAN has strengthened its naval power through modernization sufficiently and it is highly likely to use force. Especially, it is more likely in the region where the naval power operation like the Taiwan Strait is possible with the almost equality to that of the United States. China will continue to use its naval forces to achieve a rapid and decisive victory over U.S in the close area from the land.

Temperature Dependence on Dry Etching of $ZrO_2$ Thin Films in $Cl_2/BCl_3$/Ar Inductively Coupled Plasma ($Cl_2/BCl_3$/Ar 유도 결합 플라즈마에서 온도에 따른 $ZrO_2$ 박막의 식각)

  • Yang, Xue;Kim, Dong-Pyo;Lee, Cheol-In;Um, Doo-Seung;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.145-145
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    • 2008
  • High-k materials have been paid much more attention for their characteristics with high permittivity to reduce the leakage current through the scaled gate oxide. Among the high-k materials, $ZrO_2$ is one of the most attractive ones combing such favorable properties as a high dielectric constant (k= 20 ~ 25), wide band gap (5 ~ 7 eV) as well as a close thermal expansion coefficient with Si that results in good thermal stability of the $ZrO_2$/Si structure. During the etching process, plasma etching has been widely used to define fine-line patterns, selectively remove materials over topography, planarize surfaces, and trip photoresist. About the high-k materials etching, the relation between the etch characteristics of high-k dielectric materials and plasma properties is required to be studied more to match standard processing procedure with low damaged removal process. Among several etching techniques, we chose the inductively coupled plasma (ICP) for high-density plasma, easy control of ion energy and flux, low ownership and simple structure. And the $BCl_3$ was included in the gas due to the effective extraction of oxygen in the form of $BCl_xO_y$ compounds. During the etching process, the wafer surface temperature is an important parameter, until now, there is less study on temperature parameter. In this study, the etch mechanism of $ZrO_2$ thin film was investigated in function of $Cl_2$ addition to $BCl_3$/Ar gas mixture ratio, RF power and DC-bias power based on substrate temperature increased from $10^{\circ}C$ to $80^{\circ}C$. The variations of relative volume densities for the particles were measured with optical emission spectroscopy (OES). The surface imagination was measured by scanning emission spectroscope (SEM). The chemical state of film was investigated using energy dispersive X-ray (EDX).

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Quality Characteristics of Jeungpyun Prepared by Rice Sourdough (Rice Sourdough를 첨가한 증편의 품질특성)

  • Oh, Chul-Hwan;Oh, Nam-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.9
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    • pp.1215-1221
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    • 2009
  • The purpose of this work was to improve the quality of Jeungpyun made with rice sourdough, which was prepared using a mixed culture of Saccharomyces cerevisiae (S. cerevisiae) and Leuconostoc mesenteroides (L. mesenteroides) strains, and to also develop a new process for Jeungpyun preparation using the rice sourdough. The Jeungpyun was manufactured through proofing for 3 hr at $30^{\circ}C$ and steaming steps after mixing the ingredients, including pre-fermented rice sourdough, rice powder and water. After proofing, the expansion ratio of the Jeungpyun dough ranged from 109 to 135% and the pH was decreased to pH 3.80$\sim$4.09. The volumes of the Jeungpyun samples prepared with rice sourdough were 18$\sim$45% greater than that of the control. In particular, the Jeungpyun made with rice sourdough containing 10% brown rice (CM-10) had a significantly greater volume (266 mL). Also the rice sourdough Jeungpyun samples had well developed dense porous structures compared to the control. According to sensory evaluations, the sample prepared with rice sourdough containing 10% brown rice was preferred. Finally, the physical quality (texture properties) and microbiological shelf-life of the Jeungpyun was improved by using the rice sourdough.

Evaluation on Reinforcing Effect of Inclined System Bolting by Model Tests and Numerical Analysis (모형시험 및 수치해석을 통한 경사 시스템 록볼트의 보강효과 분석)

  • Lee, Jea-Dug;Kim, Byoung-Il;Yoo, Wan-Kyu;Han, Jin-Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.4
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    • pp.1529-1539
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    • 2013
  • Recent case studies in Japan have shown that rockbolts are commonly installed at an oblique angle to the excavation direction of the tunnel, instead of at a right angle, due to restriction of the working space. In particular, in the case of expansion in an existing tunnel, the working space can be very small, due to the large protective structures necessary to operate within an existing tunnel. In this case, where both the current use of the existing tunnel, and the reinforcement of the ground around the tunnel are required, the effects of installation angles and patterns of rockbolts are important factors in the design process. Therefore, in this study, a total number of 24 model tests are performed, to investigate the reinforcing effects of system bolting installed obliquely from the excavation direction of the tunnel, by changing the installation angle of bolts, longitudinal distance, and bonded length of bolts. The model test results indicate that the relaxed load ratio decreases, with the increase of both the bonded lengths and the number of the installed bolts, resulting in the decrease of the supported area by one bolt. Two-dimensional numerical analysis, which considered the reinforcement effect of inclined system bolting as the change of engineering properties near the tunnel, demonstrated that the deflection patterns at the tunnel crown in the numerical simulations, show a similar tendency to those measured in the model tests.

Effects of Extrusion-Texturization on Defatted Soy Flour for Soy Sauce Fermentation (압출성형기에 의한 전처리가 탈지대두분의 장유 제조특성에 미치는 영향)

  • Oh, Kyeong-Keun;Jung, Heon-Woong;Park, Ji-Yong;Lim, Jae-Kag;Kim, Jae-Cherl
    • Korean Journal of Food Science and Technology
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    • v.25 no.1
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    • pp.1-8
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    • 1993
  • Extruded defatted soy flour (DSF) with twin screw extruder was compared with steam treated DSF for soy sauce fermentation. Independent variables of response surface methodology (RSM) for extrusion were barrel temperature $(145{\sim}165^{\circ}C)$, feed moisture content $(25{\sim}35%)$, and feed rate $(20{\sim}30\;kg/hr)$. Extrusion conditions for production of the extrudates having highest water absorption capacity, lowest bulk density and highest expansion ratio were obtained by regression analysis of each dependent variable. Electron photomicrographs revealed significant increase of porosity inside the koji made from extruded DSF. Therefore, growth of fungi inside the koji made from extrudates of DSF was accelerated to achieve higher activities of protease, ${\alpha}-amylase$, and glucoamylase compared to the koji made from steamed DSF. Although amino acid composition of soy sauces prepared from two different DSF did not show any significant difference, the content of free amino acids in soluble nitrogen compounds was higher $(13%{\pm}2)$ in soy sauce made from extruded SDF. During the whole period of fermentation color of soy sauce made from extrudates of DSF was darker. Sensory evaluation did not reveal any serious off-odor and off-taste in the soy sauce fermented from extruded DSF.

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The Effect of Mandatory Diagnosis-Related Groups Payment System (포괄수가제도 당연적용 효과평가)

  • Choi, Jae-Woo;Jang, Sung-In;Jang, Suk-Yong;Kim, Seung-Ju;Park, Hye-Ki;Kim, Tae Hyun;Park, Eun-Cheol
    • Health Policy and Management
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    • v.26 no.2
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    • pp.135-147
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    • 2016
  • Background: The voluntary diagnosis-related groups (DRG)-based payment system was introduced in 2002 and the government mandated participation in the DRG for all hospitals from July 2013. The main purpose of this study is to examine the independent effect of mandatory participation in DRG on various outcomes of patients. Methods: This study collected 1,809,948 inpatient DRG data from the Health Insurance Review and Assessment database which contains medical information for all patients for the period 2007 to 2014 and examined patient outcomes such as length of stay (LOS), total medical cost, spillover, and readmission rate according to hospital size. Results: LOS of patients decreased after DRGs (large hospitals: adjusted odds ratio [aOR], 0.87; 95% confidence interval [CI], 0.78-0.97; small hospitals: aOR, 0.91; 95% CI, 0.91-0.92). The total medical cost of patients increased after DRGs (large hospitals: aOR, 1.22; 95% CI, 1.14-1.30; small hospitals: aOR, 1.22; 95% CI, 1.21-1.23). The results reveals that spillover of patients increased after DRGs (large hospitals: aOR, 1.27; 95% CI, 0.70-2.33; small hospitals: aOR, 1.18; 95% CI, 1.16-1.20). Finally, we found that readmission rates of patients decreased significantly after DRGs (large hospitals: aOR, 0.28; 95% CI, 0.26-0.29; small hospitals: aOR, 0.59; 95% CI, 0.56-0.63). Conclusion: The DRG payment system compared to fee-for-service payment in South Korea may be an alternative medical price policy which can reduce the LOS. However, government need to monitor inappropriate changes such as spillover increase. Since this study also is the results based on relatively simple surgery, insurer needs to compare or review bundled payment like new DRG for expansion of various inpatient-related diseases including internal medicine.