• Title/Summary/Keyword: expansion behavior

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Synthesis and Sintering Behavior of Zr2WP2O12 Ceramics (Zr2WP2O12 세라믹스의 합성과 소결거동 연구)

  • Kim, Yong-Hyeon;Kim, Nam-Ok;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.586-591
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    • 2012
  • $Zr_2WP_2O_{12}$ powder, which has a negative thermal expansion coefficient, was synthesized by a solid-state reaction with $ZrO_2$, $WO_3$ and $NH_4H_2PO_4$ as the starting materials. The synthesis behavior was dependent on the solvent media used in the wet mixing process. The $Zr_2WP_2O_{12}$ powder prepared with a solvent consisting of D. I. water was fully crystallized at $1200^{\circ}C$, showing a sub-micron particle size. According to the results obtained from a thermal analysis, a $ZrP_2O_7$ was synthesized at a low temperature of $310^{\circ}C$, after which it was reacted with $WO_3$ at $1200^{\circ}C$. A new sintering additive, $Al(OH)_3$, was applied for the densification of the $Zr_2WP_2O_{12}$ powders. The cold isostatically pressed samples were densified with 1 wt% $Al(OH)_3$ additive or more at $1200^{\circ}C$ for 4 h. The main densification mechanism was liquid-phase sintering due to the liquid which resulted from the reaction with amorphous or unstable $Al_2O_3$ and $WO_3$. The densified $Zr_2WP_2O_{12}$ ceramics showed a relative density of 90% and a negative thermal expansion coefficient of $-3.4{\times}10^{-6}/^{\circ}C$. When using ${\alpha}-Al_2O_3$ as the sintering agent, densification was not observed at $1200^{\circ}C$.

An Experimental Study on Charateristics of Autogenous Shrinkage of HPFRCC considering Early Age Coefficient of Thermal Expansion (초기재령에서 열팽창계수를 고려한 고성능 섬유보강 시멘트 복합체의 자기수축 특성에 관한 실험적 연구)

  • Park, Jung-Jun;Moon, Jae-Heum;Park, Gi-Joon;Lee, Jang-Hwa;Kim, Sung-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3602-3609
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    • 2015
  • HPFRCC is characterized by a very low water-to-binder ratio which induce extremely large autogenous shrinkage at early age. The restriction of such autogenous shrinkage through the use of forms and reinforcing bars will increase substantially the risk of excessive residual stresses and shrinkage cracking. The exact understanding of the shrinkage behavior and studies on solutions to reduce shrinkage should be imperatively undertaken for further application of HPFRCC to real structures. Therefore, this paper investigated the mechanical properties of HPFRCC with respect to the eventual introduction of expansive admixture(EA) and shrinkage reducing agent (SRA) in the mixture. Autogenous shrinkage test was conducted considering the coefficient of thermal expansion (CTE) measured at early age so as to examine the effects of EA and SRA on the autogenous shrinkage behavior of HPFRCC.

Analytical Study on Concrete Cover Thickness of Anisotropic FRP Bar (이방성 섬유강화폴리머 보강근의 콘크리트 피복두께에 대한 해석적 연구)

  • Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.58-66
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    • 2022
  • In this study, to examine the effect of the transverse thermal expansion behavior of FRP reinforcing bars and concrete on the concrete cover thickness, based on 20℃, when the temperature changes from -70℃ to 80℃, the behavior of concrete was studied theoretically and numerically. Theoretical elastic analysis and nonlinear finite element analysis were performed on FRP reinforced concrete with different diameters and cover thicknesses of FRP reinforcement. As a result, at a negative temperature difference, concrete was compressed, and the theoretical strain result and the finite element result were similar, but at a positive temperature difference, tensile stress and further cracks occurred in the concrete, which was 1.2 to 1.4 times larger than the theoretical result. The ratio of the diameter of the FRP reinforcing bar to the thickness of the concrete cover (c/db) is closely related to the occurrence of cracks. Since the transverse thermal expansion coefficient of FRP reinforcing bars is three times greater than that of concrete, it is necessary to consider this in design.

Analytical and experimental exploration of sobol sequence based DoE for response estimation through hybrid simulation and polynomial chaos expansion

  • Rui Zhang;Chengyu Yang;Hetao Hou;Karlel Cornejo;Cheng Chen
    • Smart Structures and Systems
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    • v.31 no.2
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    • pp.113-130
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    • 2023
  • Hybrid simulation (HS) has attracted community attention in recent years as an efficient and effective experimental technique for structural performance evaluation in size-limited laboratories. Traditional hybrid simulations usually take deterministic properties for their numerical substructures therefore could not account for inherent uncertainties within the engineering structures to provide probabilistic performance assessment. Reliable structural performance evaluation, therefore, calls for stochastic hybrid simulation (SHS) to explicitly account for substructure uncertainties. The experimental design of SHS is explored in this study to account for uncertainties within analytical substructures. Both computational simulation and laboratory experiments are conducted to evaluate the pseudo-random Sobol sequence for the experimental design of SHS. Meta-modeling through polynomial chaos expansion (PCE) is established from a computational simulation of a nonlinear single-degree-of-freedom (SDOF) structure to evaluate the influence of nonlinear behavior and ground motions uncertainties. A series of hybrid simulations are further conducted in the laboratory to validate the findings from computational analysis. It is shown that the Sobol sequence provides a good starting point for the experimental design of stochastic hybrid simulation. However, nonlinear structural behavior involving stiffness and strength degradation could significantly increase the number of hybrid simulations to acquire accurate statistical estimation for the structural response of interests. Compared with the statistical moments calculated directly from hybrid simulations in the laboratory, the meta-model through PCE gives more accurate estimation, therefore, providing a more effective way for uncertainty quantification.

Control of Crowning Using Residual Stress induced by the Difference of Tehermal Expansion Between Ceramic and Carbon Steel in Ceramic Cam Follower (열팽창계수차에 기인된 잔류응력을 이용한 세라믹 캠 팔로우어의 크라우닝 제어)

  • Choe, Yeong-Min;Lee, Jae-Do;No, Gwang-Su
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.703-708
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    • 2000
  • As the engine design changes to get high efficiency and performance of commercial diesel engine, surface w wear of the earn follower becomes an important issue as applied load increasing at the contact face between cam follower and cam. We developed the ceramic cam follower made of sili$\infty$n nitride ceramic which was more wear resistant than the cast iron or sintered metal cam follower. Ceramic cam follower was made by direct brazing of thin ceramic disk to steel body using an active brazing alloy without the interlayer. In-situ crowning(R), resulted from the difference of thermal expansion coefficient between ceramic and carbon steel after direct brazing without any stress-relieving inter]ayer, could be controlled. When a earbon steel was heated above $A_{c1}$ point and then c$\infty$led, the expansion curve represented a hysteresis. Appropriate crowning was achieved below the $A_{c1}$ point(about $723^{\circ}C$) and crowning increased with brazing temperature exponentially above the $A_{c1}$ point. Optimum brazing temperature range was from 700 to $720^{\circ}C$. We developed successfully the ceramic cam follower having appropriate crowning and being inexpensive. Also we could successfully control the crowning of ceramic earn follower by hysteresis behavior of thermal expansion of earbon steel during direct brazing process.

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Numerical Analysis and Laboratory Experiment of Rapid Restoration of Underground Cavity Using Expansive Material without Excavation (팽창재료를 이용한 지하공동의 비개착식 긴급복구 공법에 대한 실내실험 및 수치해석)

  • Lee, Kicheol;Choi, Byeon-Ghyun;Park, Jongho;Kim, Dongwook
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.1
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    • pp.55-64
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    • 2018
  • The purpose of this study is to evaluate the suitability of emergency underground cavity restoration method filling cavity with expansive material based on numerical analysis. For the numerical analysis, experiments were conducted to evaluate properties of expansive material. Based on the measured expansion pressure of the expansive material from the experiment, behavior of underground cavity restoration with various cavity dimensions (variation of height and width of rectangular-shape cavity) was numerically assessed. As a result of analysis, the vertical displacements of the top and bottom of cavity were significantly influenced by the cavity width and lateral displacements of cavity sides were highly dependent on cavity height. These vertical and lateral displacements were increased with increasing expansion pressure of expansive material. Also, when the expansion pressure was applied, the vertical displacement of the upper surface layer of the road was less dependent on cavity height, and was greatly influenced by cavity width.

Correlation Analysis between Damage of Expansion Joints and Response of Deck in RC Slab Bridges (RC 슬래브교의 신축이음 손상과 바닥판 응답과의 상관관계 분석)

  • Jung, Hyun-Jin;An, Hyo-Joon;Park, Ki-Tae;Jung, Kyu-San;Kim, Yu-Hee;Lee, Jong-Han
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.245-253
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    • 2021
  • RC slab bridges account for the largest portion of deteriorated bridges in Korea. However, most RC slabs are not included in the first and second classes of bridges, which are subject to bridge safety management and maintenance. The highest damaged components in highway bridges are the subsidiary facilities including expansion joints and bearings. In particular, leakage through expansion joints causes deterioration and cracks of concrete and exposure of reinforced bars. Therefore, this study analyzed the effect of adhesion damage at expansion joints on the response of the deck in RC slab bridges. When the spacing between the expansion joints at both ends was closely adhered, cracks occurred in the concrete at both ends of the deck due to the resistance rigidity at the expansion joints. Based on the response results, the correlation analysis between displacements in the longitudinal direction of the expansion joint and concrete stress at both ends of the deck for each damage scenario was performed to investigate the effect of the occurrence of damage on the bridge behavior. When expansion joint devices at both sides were damaged, the correlation between displacement and stress showed a low correlation of 0.18 when the vehicles proceeded along all the lanes. Compared with those in the intact state, the deflections of the deck in the damaged case at both sides showed a low correlation of 0.34 to 0.53 while the vehicle passed and 0.17 to 0.43 after the vehicle passed. This means that the occurrence of cracks in the ends of concrete changed the behavior of the deck. Therefore, data-deriven damage detection could be developed to manage the damage to expansion joints that cause damage and deterioration of the deck.

Time-Dependent Characteristics of the Nonequilibrium Condensation in Subsonic Flows

  • Baek, Seung-Cheol;Kwon, Soon-Bum;Toshiaki Setoguchi;Kim, Heuy-Dong
    • Journal of Mechanical Science and Technology
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    • v.16 no.11
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    • pp.1511-1521
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    • 2002
  • High-speed moist air or steam flow has long been of important subject in engineering and industrial applications. Of many complicated gas dynamics problems involved in moist air flows, the most challenging task is to understand the nonequilibrium condensation phenomenon when the moist air rapidly expands through a flow device. Many theoretical and experimental studies using supersonic wind tunnels have devoted to the understanding of the nonequilibrium condensation flow physics so far. However, the nonequilibrium condensation can be also generated in the subsonic flows induced by the unsteady expansion waves in shock tube. The major flow physics of the nonequilibrium condensation in this application may be different from those obtained in the supersonic wind tunnels. In the current study, the nonequilibrium condensation phenomenon caused by the unsteady expansion waves in a shock tube is analyzed by using the two-dimensional, unsteady, Navier-Stokes equations, which are fully coupled with a droplet growth equation. The third-order TVD MUSCL scheme is applied to solve the governing equation systems. The computational results are compared with the previous experimental data. The time-dependent behavior of nonequilibrium condensation of moist air in shock tube is investigated in details. The results show that the major characteristics of the nonequilibrium condensation phenomenon in shock tube are very different from those in the supersonic wind tunnels.

Influence of High Temperature Deformation Process Variables on the Microstructure and Thermo-physical Properties of a Ni-Fe-Co Alloy (Fe-Ni-Co 합금의 고온 변형 공정 변수와 미세조직 및 열물리적 특성의 상관 관계)

  • Yoon, D.H.;Jung, J.E.;Chang, Y.W.;Lee, J.H.;Lee, K.S.
    • Transactions of Materials Processing
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    • v.21 no.3
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    • pp.207-214
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    • 2012
  • High temperature deformation behavior of a $Ni_{30}Fe_{53}Co_{17}$ alloy, with its extraordinary low coefficient of thermal expansion less than $10{\times}10^{-6}K^{-1}$ at temperatures ranging from room temperature to 673K, was investigated by conducting a series of compression tests. From an empirical processing map, the appropriate working temperature-strain rate combination for optimum forming was deduced to be in the ~1373K, $10^{-2}s^{-1}$ region. This region has a relatively high power dissipation efficiency, greater than 0.36. Furthermore, open die forging of a 100mm diameter billets was performed to confirm the variation of thermo-physical properties in relation to microstructure. The coefficient of thermal expansion was found to increase considerably with increasing the open die forging temperature and decreasing the cooling rate, which in turn provides a drastic increase in the average grain size.

A Experimental Study on the Performance Test of Water Leakage Repair Materials for Water Expansion Acrylic Resin (아크릴 수지계 수팽창성 누수보수재의 재료적 성능평가에 관한 실험적 연구)

  • Hong Chae Han;Kim Su-Ryon;Kwak Kyu-Sung;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.51-56
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    • 2005
  • It does not find for solution by limitation of technological mechanism of existent of leakage maintenance material. So, it is paid for huge expense because continuous repeat maintenance work is consisting. Furthermore, it is indicated by big problem in construction work that is constructed by field experience that thing by definite and systematic theory is not with proper performance test and analysis up to now. Therefore, wish to measure physical performance change by various environment condition maintenance of structure and performance construction work aspect in that apply to water leakage maintenance material using of acrylic resin system water expansion, leakage maintenance material in this research, and present suitable form of construction work under these environment. also, wish to ready diversified remedy by oversea market opening.

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