• Corrosion Science and Technology
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• v.18 no.5
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• pp.155-167
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• 2019

In this study, two novel Schiff base compounds including (3-(4-Chlorophenyl isoxazole-5-yl) methanol and (3-(2,4 dichlorophenol isoxazole-5-yl) methanol as corrosion inhibitors for mild steel in 1 M hydrochloric acid solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and density functional theory (DFT) computations. The results showed that the corrosion inhibition efficiency (IE) is remarkably enhanced with the growing concentration of the Schiff base inhibitors. The results from Tafel polarization and EIS methods showed that IE decreases with gradual increments of temperature. This process can be attributed to the displacement of the adsorption/desorption balance and hence to the diminution of the level of a surface coating. Also, the adsorption of two inhibitors over mild steel followed the Langmuir adsorption isotherm. Too, the results of the scanning electron microscope (SEM) images showed that the Schiff base inhibitors form an excellent protective film over mild steel and verified the results by electrochemical techniques. Additionally, the results from the experimental and those from DFT computations are in excellent accordance.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.858-863
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• 2004

In the optimized design of an actual structure, the design variable should be selected among any certain values or corresponds to a discrete design variable that needs to handle the size of a pre-formatted part. Various algorithms have been developed for discrete design. As recently reported, the sequential algorithm with orthogonal arrays(SOA), which is a local minimum search algorithm in discrete space, has excellent local minimum search ability. It reduces the number of function evaluation using orthogonal arrays. However it only finds a local minimum and the final solution depends on the initial value. In this research, the genetic algorithm, which defines an initial population with the potential solution in a global space, is adopted in SOA. The new algorithm, sequential algorithm with orthogonal arrays and genetic algorithm(SOAGA), can find a global solution with the properties of genetic algorithm and the solution is found rapidly with the characteristics of SOA.

• Journal of Pharmaceutical Investigation
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• v.27 no.4
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• pp.279-286
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• 1997

In order to formulate 2% ibuprofen solution, the effects of various solublizing agents, such as cosolvents (propylene glycol, polyethylene glycol, glycerin), a complexing agent $(CELDEX{\circledR}\;CH20)$, surfactants $(Poloxamers\;and\;Cremophor{\circledR}\;RH40)$ on the solubility of ibuprofen in aqueous solution were evaluated. Among them, Poloxamer 407 and $Cremophor{\circledR}$ RH40 showed the excellent capacity on the solubilization of ibuprofen. After 2% ibuprofen solution of choice were administered orally to rats, in reference to a 2% ibuprofen syrup in the market, the pharmacokinetic parameters were determined. The absorption rate of ibuprofen from the solution was higher than that from the suspension.

• Corrosion Science and Technology
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• v.14 no.5
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• pp.207-212
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• 2015

The purpose of this research was to synthesize fluorine modified waterborne polyurethane dispersion (F-WPU) by soap-free (internal emulsifier) emulsion polymerization techniques, to prepare coating solution based on fluorine modified waterborne polyurethane dispersion (F-WPU) and to compare the chemical and thermo-mechanical properties on the electrogalvanized steel sheet. Environmentally friendly F-WPU was prepared with a fluorinated polyol containing 60 wt% of fluorine. There are various ways of combining a wide variety of fluorinated polyols and diisocyanate to exhibit novel properties of waterborne polyurethane dispersion. Components of coating solution were largely divided into 4 kinds i.e., F-WPU, acrylic emulsion, silane coupling agent, and colloidal silicate. F-WPU coating solution on the electro-galvanized steel sheet showed excellent properties of corrosion resistance, alkali resistance and heat resistance, as compared to other coating solutions using a general waterborne resin. The F-WPU coating solution's reliable effects are possibly due to the fluorine atoms incorporated even in a small amount of F-WPU.

• Structural Engineering and Mechanics
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• v.38 no.5
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• pp.549-571
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• 2011

This paper presents analytical solutions for skewed thick plates under transverse loading that have previously been unreported in the literature. The thick plate solution is obtained in a framework of an oblique coordinate system. The governing equation is first derived in the oblique coordinate system, and the solution is obtained using deflection and rotation as partial derivatives of a potential function developed in this research. The solution technique is applied to three illustrative application examples, and the results are compared with numerical solutions in the literature and those derived from the commercial finite element analysis package ANSYS 11. These results are in excellent agreement. The present solution may also be used to model skewed structures such as skewed bridges, to facilitate efficient routine design or evaluation analyses, and to form special elements for finite element analysis. At the same time, the analytical solution developed in this research could be used to develop methods to address post-buckling and dynamic problems.

• Journal of the Korean Ceramic Society
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• v.29 no.11
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• pp.863-869
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• 1992

A SOG(spin glass) solution with excellent wetting to Si wafers was prepared by acid-hydrolysis of Si(OEt)4 and Me2Si(OEt)2. The solution was spin coated on Si wafers, and effects of heat treatment of the film were characterized by TG/DTA, FTIR and Ellipsometry. Silica film was obtained by heat treatment at $600^{\circ}C$ within one hour, but heat treatment at 80$0^{\circ}C$ caused interfacial oxidation of the silicon substrate. Unexpectedly silica films with much better adhesion were obtained by curing at $600^{\circ}C$ for over 30 min. than those obtained by thermal oxidation.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.31A no.10
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• pp.48-53
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• 1994

The problem of a plane wave impinging upon a semi-infinite paralle-plate waveguide is investigated. The interior fields can be analyzed by converting the initial field into vaveguide modes. Kirchhoff approximation is usually made at the waveguide aperture in the literature. In this paper, a modified approximation is made using the Uniform Gemetrical Theory of Diffraction(UTD). Numerical results show excellent agreement between UTD-supplemented mode-matching solution and UTD solution.

• Bulletin of the Korean Chemical Society
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• v.10 no.1
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• pp.80-84
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• 1989

Two properties of sodium naphthalenide (2), i.e. a strong base and a good electron donor were utilized for one pot synthesis: 2-alkylthiobenzimidazoles were synthesized in excellent yields from the reactions of benzimidazoline-2-thione (1) with an equimolar amount of alkyl halides in the presence of 2. Continuous addition of a different alkyl halide without the isolation of 2-alkylthiobenzimidazoles afforded 1-alkyl-2-alkylthiobenzimidazoles having different alkyl groups at N and S atoms in excellent yields. Further addition of 2 to 1-alkyl-2-alkylthiobenzimidazoles gave excellent yields of 1-alkylbenzimidazoline-2-thiones. When 2 in THF was added to a suspension of 1-alkyl-2-alkylthiobenzimidazoles in THF, a bond cleavage between N and C of alkyl group as well as S and C of alkyl group occurred. This is in contrast to the observation in which only cleavage between S and C of alkyl group takes place in the homogeneous solution.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2000.10a
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• pp.143-150
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• 2000

A physical lumped parameter model is proposed for the time domain analysis of dam-reservoir system. The exact solution of transmitting boundary is derived for a semi-infinite 2-D reservoir of constant depth. The characteristics of the solution are examined in both frequency and the domains. Mass and damping coefficient are obtained from asymptotic behavior of the frequency domain solution. Further refinement to the lumped model is made by approximating the kernel function of the convolution integral in the exact solution. Finally a new physical lumped parameter model is proposed that consists of two masses, a spring and two dampers for each mode. It is demonstrated that new lumped parameter model of transmitting boundary can give excellent results.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.2
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• pp.396-403
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• 1991

A solution is presented for the computation of the elastic-creep stresses in a hollow cylinder subjected to nonaxisymmetric temperature distribution. The creep problem is treated by the Maxwell creep model. Laplace transformation is used for reformation of the governing equation of elastic problem and Hooke's law in a function of .gamma. , .theta. , and creep constant. The governing equation is set up using the Airy stress function which leads to the biharmonic equation. The solution is obtained by using Fourer series method and Laplace inverse method used to obtain the stress components which include the variation of time. This solution shows excellent agreement with Lamkin's and Boley & Weiner's solution. The viscoelastic stresses are also obtained for the fuel rob tube subjecting nonaxisymmetric thermal load.