• 한국환경과학회지
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• 제15권8호
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• pp.737-744
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• 2006

Present study was designed to characterize the concentrations of major roadside air pollutants in Daegu and to compare with those of Seoul and Busan. Evaluated were the exceedance frequence of mean concentrations of target compounds(CO, NO$_2$, O$_3$, PM$_{10}$, SO$_2$) and the relationship for time variation. Two air pollution monitoring stations(one roadside station and one residential station) in Daegu were selected for this study. In addition, one roadside monitoring station from each of Seoul and Busan was chosen for the comparison of Daegu monitoring stations. The data analyzed in the current study were collected from 1998 to 2000 by Daegu Regional Environmental Management Office. The roadside concentrations of NO2 and PM to and the exceedance frequency of ambient air standard levels in Daegu were higher than those of Seoul and Busan. Except 03, the roadside concentrations of all target compounds showed following three distinguished patterns; first, possibly due to increased traffic density, the concentrations increased from 0500 to 0900(LST), second, the concentrations decreased from 0900 to 1700(LST) possibly due to the increased wind velocity and decreased traffic density, and finally, increased traffic density, the concentrations increased again from 1700 to 2100(LST). An implication was that major air pollution sources shifted from residential area to road-area during rush hours.

• 한국환경과학회지
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• 제25권2호
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• pp.191-216
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• 2016

Since prolonged exposure to elevated ozone ($O_3$) concentrations is known to be harmful to human health, appropriate control strategies for ozone are needed for the non-attainment area such as Seoul, Korea. The goal of this research is to assess factors linked with the 1-hour ozone exceedance through a decision tree model. Since ozone is a secondary pollutant, lag times between ozone and explanatory variables for ozone formation are taken into account in the model to improve the accuracy of the simulation. Results show that while ozone concentrations of the previous day and $NO_2$ concentrations in the morning are major drivers for ozone exceedances in the early afternoon, meteorology plays more important role for ozone exceedances in the late afternoon. Results also show that a selection of lag times between ozone and explanatory variables affect the accuracy of predicting 1-hour ozone exceedances. The result analyzed in this study can be used for developing control strategies of ozone in Seoul, Korea.

• 한국대기환경학회지
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• 제16권6호
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• pp.607-623
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• 2000

Major trends of ozone concentration variations in Korea were investigated by using observation data from around 100 stations for the period of 1991∼1997. In addition, important regulating those variations were inferred. Three measures such as the number of days exceeding 80ppb, the 95th percentile of daily maxima, and the annual average concentration were used for the analysis of multi-scale ozone concentration variations. Three areas in the southwest (Sosan, Mokpo, and Cheju) of which monitoring has been operated since 1995 showed the highest annual average concentrations over; this was noted because of the high annual average in the Yosu area in the early 1990s. Large increases in annual average concentrations were observed along the relatively cleaner areas connecting Kangnung and Kwangju(northeast to southwest), in contrast to polluted areas connecting Seoul and Pusan(northeast to southeast). Both the number of exceedance days and the daily maximum concentration were nearly constant in the Greater Seoul Area in spite of interannual flucturations associated with year-to-year changes in air temperature. Within the Greater Seoul Area, all three measures usually showed the same trend; they decreased in the middle and west and increased in the east and northeast. All three measures including the number of exceedance days increased largely at Sillim where the average concentration was high but no exceedance days were recorded in the early 1999s, Nationwide ozone concentration variations appear to be determined by the competitive influence of long-range transport and local urban emissions, Within the city including the Greater Seoul Area, changes in emission which accompany changes in population and in the number if vehicles ( in the process of urban development) were found to be important components of ozone concentration variations.

• 한국지구과학회지
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• 제24권3호
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• pp.190-204
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• 2003

본 연구에서는 서울시에 의해 운영되는 서울시내 31개 지역의 대기오염 자동측정망에서 1990년부터 2000년까지 11년 동안 측정한 자료 중, TSP와 PM$_{10}$에 대한 대기환경기준을 초과한 자료만을 선택적으로 분리한 후 여러 가지 통계적인 분석을 수행하였다. 이러한 연구목적에 맞추어, 각 토지 이용 상태별로 환경기준을 초과한 분진농도의 경향성을 비교해 본 결과, TSP의 경우 초과농도의 전반적인 발생분포가 녹지, 주거, 상업, 준공업지역 순서로 증가하는 양상을 보여주었다. 준공업 지역에서 351.0${\pm}$35.9${\mu}$g m$^3$로 가장 높은 초과농도를 보였다. PM$_{10}$의 초과농도는 주거지역에서 182.9${\pm}$42.4${\mu}$g m$^3$의 최고농도를 보이며, 초과농도분포는 준공업, 상업, 녹지, 주거지역 순서로 증가하는 양상을 보인다. 발생빈도수를 각 지점별 측정망수로 나누어 준 결과 주거지역에서 21회로 다른지역에 비해 높은 초과빈도수를 보였다. 이들 초과농도자료들만에 국한시켜 시간적 주기성을 분석한 결과에 따르면, 일반적으로 관측되는 부유분진 자료들과 차별화 된 경향성이 어느 정도 확인되었다. 특히 계절적인 주기로 구분하였을 때, 일반농도자료는 PM$_{10}$과 TSP 모두 겨울철에 가장 큰 농도를 보인데 반해, 초과농도는 다른 양상을 보여주었다. 이러한 연구결과, PM$_{10}$의 연도별 경향성에서 가장 주목할 점은 측정이 시작된 1995년 이후 초과농도의 크기가 지속적으로 감소함에도 불구하고, 그 발생빈도수는 최근에 들어 괄목할 만큼 증가하고 있다는 점을 들 수 있다.

• 한국환경과학회지
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• 제23권11호
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• pp.1889-1907
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• 2014

The characteristics of meteorological conditions related to changes in atmospheric environment on Jeju Island were investigated during recent years (2010-2012). This analysis was performed using the hourly observed data of meteorological variables (air temperature, wind speed and direction) and air pollutants ($O_3$, $PM_{10}$, $SO_2$, $NO_2$, and CO). Out of 5 pollutants, $O_3$ and $PM_{10}$ concentrations have frequently exceeded national environmental standards in the study area during the study period, with relatively higher concentrations than the others. The concentrations of $O_3$ and $PM_{10}$ in 2010 and 2011 were somewhat higher than those in 2012, and their highest concentrations were mostly observed in spring followed by fall. Nighttime $O_3$ concentrations (with relatively high concentration levels) were almost similar to its daytime concentrations, due to less $O_3$ titration by very low NO concentrations in the target area and in part to $O_3$ increase resulting from atmospheric transport processes. The transport effect related to the concentration variations of $O_3$ and $PM_{10}$ was also clarified in correlation between these pollutants and meteorological variables, e.g. the high exceedance frequency of concentration criteria with strong wind speed and the high concentrations with the westerly/northwesterly winds (e.g., transport from the polluted regions of China). The overall results of this study suggest that the changes in atmospheric environment in the study area were likely to be caused by the transport effect (horizontal and vertical) due to the meteorological conditions rather than the contribution of local emission sources.

• 한국대기환경학회지
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• 제30권5호
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• pp.504-509
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• 2014

Twenty-five stations of the urban monitoring network in Seoul were assessed with a focus on surveillance function of the exceedances of 8-hour ozone and 24-hour $PM_{10}$ standards. The two standards were selected because their attainment rates were particularly low. Two hierarchical cluster analyses were performed to group stations with similar atmospheric environments-one using daily highest 8-hour [$O_3+NO_2$], 8-hour $O_3$ concentrations plus corresponding 8-hour $NO_2$ concentrations considering the interconversion of $O_3$ and $NO_2$, and the other using 24-hour $PM_{10}$ concentrations. An index to measure higher concentration and exceedances of the standards was introduced. Within a cluster, sufficiently high score was assigned to the trends station or the station with higher index. Scores for $O_3+NO_2$ and $PM_{10}$ of a given station were added and ranked in the descending order to determine the relative importance.

• 한국대기환경학회지
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• 제29권5호
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• pp.545-552
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• 2013

While attainment rates for $SO_2$ and CO approached 100%, those for $PM_{10}$, $NO_2$, and $O_3$ have been low during the past decade. The attainment rates for 24-h $PM_{10}$ and 8-h $O_3$ have been only 1~3% and 5~12%, respectively, since the standards were strengthened in 2007. Variations in the 99th percentiles of 24-h $PM_{10}$, 8-h $O_3$, and 24-h $NO_2$, which are used as criteria for determining exceedance of standards, were examined by region. Because the analysis was based on short-term high-concentrations, the effects of Asian dust were observed for $PM_{10}$. Accordingly, it is necessary to specify whether exceptional events such as Asian dust will be included or not in determining the exceedances of standards. While variations in $NO_2$ were not large, there was an increasing trend in $O_3$. In the Yeongnam region, the increasing rate of $O_3$ concentrations was small although the decreasing rate of $NO_2$ was the greatest. In the Gangwon region, $NO_2$ concentrations were almost unchanged, but $O_3$ concentrations experienced a significant increase. Regional management strategies targeting short-term high concentrations of criteria pollutants analogous to the Special Act for the greater Seoul area will aid in improving attainment rates.

• 한국대기환경학회지
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• 제34권5호
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• pp.708-726
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• 2018

In this study, we examined the contribution of nitrogen oxides and volatile organic compounds emitted from China and Japan to ozone concentrations over Gwangyang-bay, South Korea. We used a chemical transport model, Community Multi-scale Air Quality model, and its instrumented sensitivity tool, High-order Decoupled Direct Method. Intercontinental Chemical Transport Experiment-Phase B 2006 for East Asia and Clean Air Policy Support System 2007 emissions inventories for South Korea were used for the ozone simulation. During the study period, May 2007, the modeled maximum daily 8-hr average ozone concentration among seven air quality monitors in Gwangyang-bay was 68.8 ppb. The contribution of $NO_x$ emissions from China was 19.5 ppb (28%). The highest modeled ozone concentrations and Chinese contributions appeared when air parcels were originated from Shanghai area. The observed 8-hr average ozone concentrations in Gwangyang Bay exceeded the national ambient air quality standard (60 ppb) 203 times by daytime and 56 times by nighttime during the period. It was noticed that many exeedances happened when contribution of Chinese emissions to ozone concentrations over the area increased. Sensitivity analysis shows that a reduction in Chinese $NO_x$ and VOC emissions by 15% could lessen the total exceedance hours by 24%. This result indicates that high ozone concentrations over Gwangyang-bay are strongly enhanced by Chinese emissions.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2019년도 학술발표회
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• pp.412-412
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• 2019

Nature-based solutions (NBS) offer a wide variety of techniques that promote cost-efficient stormwater management practices. In particular, low impact development facilities utilize NBS principles to restore the ecosystem services in a highly-urbanized area. Despite the advancements in these technologies, several considerations should still be addressed to ensure optimum functionality and attainment of desired pollutant removal efficiency a LID facility. This study evaluated the mass flushing characteristics of pollutants in an urban catchment and the efficiency of a small constructed wetland (SCW) in treating urban stormwater runoff. 21 rainfall events from 2010 to 2018 were monitored to determine and quantify stormwater pollutants. The highest pollutant washoff was observed on rainfall depths ranging from 0.1mm to 10mm, whereas events with greater rainfall depths exhibited lower pollutant concentrations due to dilution effect. However, the SCW manifested lower pollutant-removal performance on rainfall depths exceeding 10mm due to the exceedance of the facility's design rainfall. This study is beneficial in assessing the dynamics of pollutant washoff and efficiency of LID facilities subjected under various external factors.

• Annals of Occupational and Environmental Medicine
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• 제35권
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• pp.3.1-3.11
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• 2023

Background: Studies on the risk of mercury (Hg) in Korean fishery products focus primarily on total Hg levels as opposed to methylmercury (MeHg) levels. None of the few studies on MeHg in tuna investigated tuna from Japanese restaurants. Few have evaluated lead (Pb), cadmium (Cd) and arsenic (As) in tuna. Thus, this study aimed to conduct a risk assessment by evaluating heavy metal concentrations in tuna from Japanese restaurants. Methods: Thirty-one tuna samples were collected from Japanese restaurants in the Republic of Korea. They were classified according to region and species. The concentration of heavy metals in the samples was analyzed using the Ministry of Food and Drug Safety Food Code method. The rate of exceedance of maximum residue levels (MRLs) and the risk compared to the provisional tolerable weekly intake (PTWI) set by the Joint Food and Agriculture Organization/World Health Organization Expert Committee on Food Additives (%PTWI) were evaluated for risk assessment. Results: The mean of MeHg, Pb, Cd and As concentrations were 0.56 ± 1.47 mg/kg, 33.95 ± 3.74 ㎍/kg, 14.25 ± 2.19 ㎍/kg and 1.46 ± 1.89 mg/kg, respectively. No sample exceeded the MRLs of Pb and Cd, but 9.7% of the samples exceeded the MRL of MeHg. The %PTWIs of MeHg, Pb, Cd and As were 4.2037, 0.0162, 0.0244 and 1.1627, respectively. The %PTWI of MeHg by age group and sex was highest among men aged 19-29 years (10.6494), followed by men aged 30-49 years (7.2458) and women aged 19-29 years (4.8307). Conclusions: We found that 3 out of 31 samples exceeded the MRL of MeHg. The %PTWI of MeHg showed significant differences based on age and sex, and the value was likely to exceed a safe level depending on individuals' eating behaviors. Therefore, improved risk management for MeHg is required.