• Title/Summary/Keyword: ex-situ

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Physical Property Change of the Gapless Semiconductor $PbPdO_2$ Thin Film by Ex-situ Annealing

  • Choo, S.M.;Park, S.M.;Lee, K.J.;Jo, Y.H.;Park, G.S.;Jung, M.H.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.371-372
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    • 2012
  • We have studied lead-based gapless semiconductors, $PbPdO_2$, which is very sensitive to external parameters such as temperature, pressure, electric field, etc[1]. We have fabricated pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films using the pulsed laser deposition. Because of the volatile element of Pb, it is very difficult to grow the films. Note that in case of $MgB_2$, Mg is also volatile element. So in order to enhance the quality of $MgB_2$, some experiments are carried out in annealing with Mg-rich atmosphere [2]. This annealing process with volatile element plays an important role in making smooth surface. Thus, we applied such process to our studies of $PbPdO_2$ thin films. As a result, we found the optimal condition of ex-situ annealing temperature ${\sim}650^{\circ}C$ and time ~12 hrs. The ex-situ annealing brought the extreme change of surface morphology of thin films. After ex-situ annealing with PbO-rich atmosphere, the grain size of thin film was almost 100 times enlarged for all the thin films and also the PbO impurity phase was smeared out. And from X-ray diffraction measurements, we determined highly crystallized phases after annealing. So, we measured electrical and magnetic properties. Because of reduced grain boundary, the resistivity of ex-situ annealed samples changed smaller than no ex-situ sample. And the carrier densities of thin films were decreased with ex-situ annealing time. In this case, oxygen vacancies were removed by ex-situ annealing. Furthermore, we will discuss the transport and magnetic properties in pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films in detail.

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Brief Review on Microbial Enhanced Oil Recovery (미생물을 이용한 원유 회수증진법에 대한 동향연구)

  • Oh, Kyeongseok
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.4
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    • pp.1010-1019
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    • 2021
  • Petroleum oil in reservoir has been acquired by primary, secondary and tertiary oil recoveries. Microbial enhanced oil recovery (MEOR) classified to tertiary oil recovery has been evaluated in two ways of in-situ and ex-situ options. In-situ MEOR injects microbes into a depleted oil reservoir and stimulates those to generate metabolites. Among metabolites, biosurfactants play an important role to make heavy residues flow. Ex-situ MEOR injects microbial metabolites instead of microbes into a reservoir to recover oil. Even though both in-situ MEOR and ex-situ MEOR are eco-friend processes, in-situ MEOR can be preferred because it is more economic. Even though MEOR have been evaluated for a long time, it is still in the state of evaluating in a pilot-scale. Among microbes, bacteria have been widely evaluated in MEOR purpose. In this paper, bacteria for MEOR were summarized and their metabolites were qualitatively evaluated.

Mechanical Alloying and Combined Process of in-situ and ex-situ to Fabricate the ex-situ C-doped $MgB_2$ Wire (기계적 합금화 및 in-situ와 ex-situ의 혼합공정을 통한 C 도핑된 ex-situ $MgB_2$ 선재 제조)

  • Hwang, Soo-Min;Lee, Chang-Min;Lim, Jun-Hyung;Choi, Jun-Hyuk;Park, Jin-Hyun;Joo, Jin-Ho;Jun, Byung-Hyuk;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.79-86
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    • 2009
  • We successfully fabricated C-doped ex-situ $MgB_2$ wires using two different methods such as mechanical alloying(MA) and combined process(CP) of in-situ and ex-situ. In the MA, the precursor powder was prepared with a mixture of $MgB_2$ and 1 at% C powders by planetary ball milling for 0-100 h. In the CP, on the other hand, C-doped $MgB_2$ powder was prepared with Mg, B, and C powders by in-situ process via compaction, sintering, and crushing. The powders prepared by two methods were loaded into Fe tube and then the assemblages were drawn by a conventional powder-in-tube technique. The MA treatment of C-added $MgB_2$ decreased the particles/grains size and resulted in C-doping into $MgB_2$ after sintering, improving the critical current density($J_c$) in high external magnetic field. For the C-doped $MgB_2$ wire by MA for 25 h, the $J_c$ was $4.1{\times}10^3A/cm^2$ at 5 K and 6.4 T, which was 5.9 times higher than that of pure and untreated $MgB_2$ wire. The CP also provided C-doping into $MgB_2$ and improved the $J_c$ in high magnetic field; the C-doped $MgB_2$ wire fabricated by CP exhibited a $J_c$ being 2.3 times higher than that of the ex-situ wire used commercial $MgB_2$ powder at 5 K and 6.0 T($2.7{\times}10^3A/cm^2\;vs.\;1.2{\times}10^3A/cm^2$).

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Ex-situ Reductive Dechlorination of Carbon Tetrachloride by Iron Sulfide in Batch Reactor

  • Choi, Kyung-Hoon;Lee, Woo-Jin
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.177-183
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    • 2008
  • Ex-situ reductive dechlorination of carbon tetrachloride (CT) by iron sulfide in a batch reactor was characterized in this study. Reactor scaled-up by 3.5 L was used to investigate the effect of reductant concentration on removal efficiency and process optimization for ex-situ degradation. The experiment was conducted by using both liquid-phase and gas-phase volume at pH 8.5 in anaerobic condition. For 1 mM of initial CT concentration, the removal of the target compound was 98.9% at 6.0 g/L iron sulfide. Process optimization for ex-situ treatment was performed by checking the effect of transition metal and mixing time on synthesizing iron sulfide solution, and by determining of the regeneration time. The effect of Co(II) as transition metal was shown that the reaction rate was slightly improved but the improvement was not that outstanding. The result of determination on the regeneration time indicated that regenerating reductant capacity after $1^{st}$ treatment of target compound was needed. Due to the high removal rates of CT, ex-situ reductive dechlorination in batch reactor can be used for basic treatment for the chlorinated compounds.

Ex-situ Stabilization and Utility Prospects of 'Jata' Ecorace of Tropical Tasar Silkworm Antheraea mylitta Drury

  • Hansda, G.;Reddy, R. Manohar;Sinha, M. K.;Ojha, N. G.;Prakash, N. B. Vijaya
    • International Journal of Industrial Entomology and Biomaterials
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    • v.17 no.2
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    • pp.169-172
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    • 2008
  • Indian tropical tasar silkworm, Antheraea mylitta D is reported to have forty four ecoraces by way of their adoption to different topographical and vegetational conditions. Of late, another ecorace 'JATA' - univoltine under in-situ condition has been explored which is localized in Thakurmunda area of the foot hills of Simlipal biosphere (Mayurbhanj district) of Orissa, India. The ecorace 'Jata' exhibits superior economic characters over widely commercialized ecoraces of Daba and Sukinda. The cocoon production of localized 'Jata' ecorace is depleting day by day in in-situ condition. In the present study, efforts were made to stabilize the ecorace 'Jata' under ex-situ condition at Ranchi (Jharkhand), where the 'Jata' ecorace silkworms were reared on Terminalia tomentosa for four successive generations during 2006 and 2007 and the cocoons were preserved in grainage house under prevailing climatic conditions. The results indicated change in voltinism behaviour of the 'Jata' ecorace from univoltine to bivoltine. The rearing performance and grainage efficiencies indicate the tendency of 'Jata' ecorace towards acclimatization and stabilization under Ranchi climatic conditions. The 'Jata' ecorace manifests the prospects for acclimatization, stabilization and commercial exploitation.

Determination of the minimum population size for ex situ conservation of water-shield (Brasenia schreberi J.F. Gmelin) inferred from AFLP analysis

  • Kim, Changkyun;Na, Hye Ryun;Jung, Jongduk;Kim, Hojoon;Hyun, Jin-Oh;Shin, Hyunchur;Choi, Hong-Keun
    • Journal of Ecology and Environment
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    • v.35 no.4
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    • pp.301-306
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    • 2012
  • Determination of the minimum population size is an important component for the ex situ conservation of an endangered species. Here, we present the identification of collection strategies that most efficiently captured the genetic diversity of Brasenia schreberi J.F. Gmelin (water-shield) in natural populations from the mainland (MGC) and Jeju Island (JNS) of South Korea, using amplified fragment length polymorphism (AFLP) markers. A total of 313 and 383 polymorphic bands were detected in the MGC and JNS populations, respectively. All of the 140 sampled ramets were distinguishable by the presence of distinct AFLP phenotypes. According to the simulation of the individual sampling by maximization sampling, 25 and 28 individuals captured all of the genetic diversity in the MGC population (mainland of South Korea) and the JNS population (Jeju Island), respectively. The level of genetic diversity of the core collections was similar to the entire collection, indicating that the core collections very well represent the diversity of the entire collection. We therefore suggest a management unit of B. schreberi based on the genetic information for assessing the minimum population size for its ex situ conservation.

A Study on Public Perception of the Ex-suit Conservation Institution for Conserving Marine Animals: Case of the Korea National Maritime Museum (해양동물 보전을 위한 서식지외 보전기관에 대한 대중의 인식조사에 관한 연구 - 국립해양박물관사례를 중심으로)

  • Lee, Bomsok;Kwon, Suk-jae;Kim, Tae-goun
    • Journal of Navigation and Port Research
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    • v.43 no.6
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    • pp.475-482
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    • 2019
  • The increase in human use and activity in the oceans is leading to marine pollution and habitat destruction. As a result, in particular, marine animals with a long life cycle and small population are threatened with extinction. Thus, the Korean government designated 11 artificial habitats, such as aquariums and marine museums, as Ex-situ conservation institutions to preserve endangered marine life in 2010. However, studies on the significance and economic value of Ex-situ conservation institutions providing marine life conservation services have not been conducted. Thus, the purpose of this study was to estimate the public's quantitative support for the operation policy of Ex-situ conservation institutions, which is a management method for the protection and propagation of marine animals in Korea. To achieve this, the economic value of the marine animal conservation role of the National Maritime Museum was estimated, operated as an Ex-situ conservation institution for the preservation of green turtles in Korea. By using the representative non-market valuation method for public goods known as the contingent valuation method (CVM), the economic value of the Ex-situ conservation institution (National Maritime Museum) was estimated at approximately 41.8 billion won to a maximum of 78.1 billion won. The results of this study can be applied as basic data for marine animal management policymakers in establishing efficient management plans for endangered marine animals in Korea's coastal waters.